ChemInform Abstract: Metal Free Visible Light Photoredox Activation of PhI(OAc)2for the Conversion of Arylboronic Acids to Phenols.

ChemInform ◽  
2015 ◽  
Vol 46 (33) ◽  
pp. no-no
Author(s):  
Abhijit Paul ◽  
Debnath Chatterjee ◽  
Rajkamal Rajkamal ◽  
Tanmoy Halder ◽  
Srirupa Banerjee ◽  
...  
Keyword(s):  
Visible Light ◽  
Metal Free ◽  
Arylboronic Acids

Metal free visible light photoredox activation of PhI(OAc)2 for the conversion of arylboronic acids to phenols

2015 ◽  
Vol 56 (19) ◽  
pp. 2496-2499 ◽  
Author(s):  
Abhijit Paul ◽  
Debnath Chatterjee ◽  
Rajkamal ◽  
Tanmoy Halder ◽  
Srirupa Banerjee ◽  
...  
Keyword(s):  
Visible Light ◽  
Metal Free ◽  
Arylboronic Acids

Porous conjugated polymer via metal-free synthesis for visible light-promoted oxidative hydroxylation of arylboronic acids

Polymer ◽  
2017 ◽  
Vol 126 ◽  
pp. 291-295 ◽  
Author(s):  
Zi Jun Wang ◽  
Run Li ◽  
Katharina Landfester ◽  
Kai A.I. Zhang
Keyword(s):  
Visible Light ◽  
Conjugated Polymer ◽  
Metal Free ◽  
Arylboronic Acids

Regioselective C3-H Trifluoromethylation of 2H-Indazole Under Transition-Metal-Free Photoredox Catalysis

2019 ◽  
Author(s):  
Arumugavel Murugan ◽  
Venkata Nagarjuna Babu ◽  
Nagaraj Sabarinathan ◽  
Sharada Duddu. S
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Practical Approach ◽  
Hypervalent Iodine ◽  
Radical Mechanism ◽  
Photoredox Catalysis ◽  
Metal Free

Here we report a visible-light-promoted metal-free regioselective C3-H trifluoromehtylation reaction that proceeds via radical mechanism and which supported by control experiments. The combination of photoredox catalysis and hypervalent iodine reagent provides a practical approach for the present trifluoromethylation reaction and synthesis of a library of trifluoromethylated indazoles.

Metal‐Free and Heterogeneous Photocatalytic Reduction of 4‐Nitroaniline by a Poly(Ethylene Glycol)‐Supported Eosin Dye under Visible‐Light Exposure

ChemCatChem ◽  
2019 ◽  
Vol 11 (14) ◽  
pp. 3307-3317
Author(s):  
Andreea L. Chibac ◽  
Violeta Melinte ◽  
Vlasta Brezová ◽  
Estelle Renard ◽  
Arnaud Brosseau ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Visible Light ◽  
Light Exposure ◽  
Photocatalytic Reduction ◽  
Poly Ethylene Glycol ◽  
Metal Free ◽  
Poly Ethylene

Highly chemoselective deoxygenation of N-heterocyclic N-oxides under transition metal-free conditions

2021 ◽  
Vol 19 (16) ◽  
pp. 3735-3742
Author(s):  
Se Hyun Kim ◽  
Ju Hyeon An ◽  
Jun Hee Lee
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Eosin Y ◽  
Metal Free ◽  
Simple Protocol

Here, we provide an operationally simple protocol for the highly chemoselective deoxygenation of various functionalized N-heterocyclic N-oxides under visible light-mediated photoredox conditions with Na2-eosin Y as an organophotocatalyst.

Metal-free visible-light-induced aerobic oxidation of α-diazoesters leading to α-ketoesters in air

2021 ◽  
Author(s):  
Ruisheng Liu ◽  
Qishun Liu ◽  
Haoran Meng ◽  
Hongyu Ding ◽  
Jindong Hao ◽  
...  
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Aerobic Oxidation ◽  
Metal Free

A metal-free and visible-light-induced strategy has been established for the construction of α-ketoesters via aerobic oxidation of α-diazoesters with dioxygen in air at room temperature.

Visible-Light-Mediated Organoboron-Catalysed Metal-Free Dehydrogenation of N-Heterocycles Using Molecular Oxygen

2021 ◽  
Author(s):  
Lanfeng Wei ◽  
Yu Wei ◽  
Jinli Zhang ◽  
Liang Xu
Keyword(s):  
Visible Light ◽  
Molecular Oxygen ◽  
The Other ◽  
Metal Free ◽  
Other Hand

The surge of photocatalytic transformation not only provides unprecedented synthetical methods, but also triggers the enthusiasm for more sustainable photocatalysts. On the other hand, oxygen is an ideal oxidant in...

Visible-Light-Induced Palladium-Catalyzed Selective Defluoroarylation of Trifluoromethylarenes with Arylboronic Acids

2021 ◽  
Author(s):  
Yun-Cheng Luo ◽  
Fei-Fei Tong ◽  
Yanxia Zhang ◽  
Chun-Yang He ◽  
Xingang Zhang
Keyword(s):  
Visible Light ◽  
Arylboronic Acids ◽  
Palladium Catalyzed
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