S‐Trifluoroethyl Benzenesulfonothioate: A Bench‐Stable Reagent for Electrophilic Trifluoroethylthiolation †

2020 ◽  
Vol 38 (12) ◽  
pp. 1625-1628 ◽  
Author(s):  
Shuai Huang ◽  
Ziheng Xia ◽  
Kui Lu ◽  
Haifeng Lu ◽  
Chen‐Ho Tung ◽  
...  
Keyword(s):  
2002 ◽  
Author(s):  
G. K. Prakash ◽  
Markus Etzkorn ◽  
George A. Olah ◽  
Karl O. Christe ◽  
Stefan Schneider
Keyword(s):  

ChemInform ◽  
2010 ◽  
Vol 41 (38) ◽  
pp. no-no
Author(s):  
Sandeep V. Khansole ◽  
Shivaji B. Patwari ◽  
Yeshwant B. Vibhute

Synlett ◽  
2018 ◽  
Vol 30 (07) ◽  
pp. 777-782 ◽  
Author(s):  
Clément Ghiazza ◽  
Cyrille Monnereau ◽  
Lhoussain Khrouz ◽  
Maurice Médebielle ◽  
Thierry Billard ◽  
...  

We demonstrated that the shelf-stable reagent trifluoromethyl tolueneselenosulfonate can be involved in radical trifluoromethylselenylation. Upon visible-light irradiation, the homolysis of the reagent could take place at room temperature. This finding is explored for unprecedented C(sp2)–SeCF3 and C(sp3)–SeCF3 processes under transition-metal-free conditions. Mechanistic investigations, including cyclic voltammetry, luminescence measurement, and EPR studies, allowed the proposal of plausible mechanisms.1 Introduction.2 Reactivity of Reagent I with Diazonium Salts3 Reactivity of Reagent I with Alkenes and Alkynes4 Conclusion


1972 ◽  
Vol 23 (4) ◽  
pp. 721-724 ◽  
Author(s):  
James H. Rust ◽  
Sanford Berman ◽  
William H. Habig ◽  
John D. Marshall ◽  
Dan C. Cavanaugh

2003 ◽  
Vol 10 (4) ◽  
pp. 292-296 ◽  
Author(s):  
Yun-yan Wang ◽  
Li-yuan Chai ◽  
Xiao-bo Min ◽  
De-wen He ◽  
Bing Peng

1971 ◽  
Vol 17 (6) ◽  
pp. 548-550 ◽  
Author(s):  
Charles Bishop ◽  
T M Chu ◽  
Z K Shihabi

Abstract A single stable reagent for spectrophotometric assay of creatine kinase in one step is described. Reagent cost has been decreased by running the reaction at Km conditions for creatine phosphate and relating the activity to maximum velocity.


2018 ◽  
Vol 20 (3) ◽  
pp. 812-815 ◽  
Author(s):  
Hua Zhou ◽  
Paramita Mukherjee ◽  
Rongqiang Liu ◽  
Edelweiss Evrard ◽  
Dianpeng Wang ◽  
...  
Keyword(s):  

Synthesis ◽  
1987 ◽  
Vol 1987 (02) ◽  
pp. 166-167 ◽  
Author(s):  
Peter Henklein ◽  
Hans-Ulrich Heyne ◽  
Wolf-Rainer Halatsch ◽  
Hartmut Niedrich

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