Porous assembly of metallo‐supramolecule and polyoxometalate via ionic complexation with vapor sorption properties

Author(s):  
Yaping Xu ◽  
Hao Yu ◽  
Xin Jiang ◽  
Junjuan Shi ◽  
Bao Li ◽  
...  
2017 ◽  
Vol 75 (6) ◽  
pp. 919-926 ◽  
Author(s):  
Cristina Simón ◽  
Francisco García Fernández ◽  
Luis García Esteban ◽  
Paloma de Palacios ◽  
Reza Hosseinpourpia ◽  
...  

2021 ◽  
Author(s):  
MATHILDE SIMON ◽  
RENE FULCHIRON ◽  
FABRICE GOUANVE

Abstract The objective of this study was to understand the chemical modification impact on interactions between water and cellulosic fiber. In that respect, cotton (C), flax (F), viscose (V) and cellulose acetate (CA) were analyzed by using a dynamic vapor sorption analysis. The sorption and desorption isotherms and kinetic curves were modelled using the Park model and the “Parallel Exponential Kinetics” (PEK) model-which allowed an accurate fitting on the whole range of water activity. The obtained sorption properties were correlated to the accessibility and the amount of sorption sites and also to the crystallinity level of the fibers. It was found that V exhibited the highest water sorption capacity due to a higher hydroxyl groups accessibility and a high amorphous fraction, followed up by F, C and CA. In contrast, higher kinetic sorption rate was obtained for CA due to a decrease of the hydroxyl groups within the fibers. Regardless the fiber, the determination of characteristic times showed that the kinetic rate was higher for sorption than desorption.


1968 ◽  
Vol 51 (9) ◽  
pp. 1339-1344 ◽  
Author(s):  
E. Berlin ◽  
B.A. Anderson ◽  
M.J. Pallansch

RSC Advances ◽  
2017 ◽  
Vol 7 (2) ◽  
pp. 975-984 ◽  
Author(s):  
Ling Li ◽  
Lei Lv ◽  
Ru-Dan Huang

Six new coordination polymers have been synthesized based on terphenyl tetracarboxylates (H4L1, H4L2) and bis-pyridyl ligands (bpfp, bpe and bpmp).


2005 ◽  
Vol 10 (2) ◽  
pp. 249-259 ◽  
Author(s):  
Paul Young ◽  
Stephen Edge ◽  
John Staniforth ◽  
D. Fraser Steele ◽  
Robert Price

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