A Sustainable Palladium‐Intercalated Montmorillonite Clay Catalytic System for Imine Hydrogenation under Mild Conditions

A practical palladium/calcium catalytic system was developed for dehydrative allylation concerning unactivated allylic alcohols. EtOH solvent with H2O additive was identified as powerful media to accelerate proton transfer. That catalytic...

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4-OH-TEMPO/TCQ/TBN/HCl: A Metal-Free Catalytic System for Aerobic Oxidation of Alcohols under Mild Conditions

Chinese Journal of Chemistry ◽

10.1002/cjoc.201500357 ◽

2015 ◽

Vol 33 (9) ◽

pp. 1019-1023 ◽

Cited By ~ 4

Author(s):

Yanli Dong ◽

Xiaomei Zhao ◽

Renhua Liu

Keyword(s):

Catalytic System ◽

Aerobic Oxidation ◽

Metal Free ◽

Mild Conditions ◽

Oxidation Of Alcohols

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Eu-Ti-Pt-Catalytic system for direct hydroxylation of benzene by O2 and H2 under mild conditions

Studies in Surface Science and Catalysis - 12th International Congress on Catalysis, Proceedings of the 12th ICC ◽

10.1016/s0167-2991(00)81059-9 ◽

2000 ◽

pp. 815-820 ◽

Cited By ~ 10

Author(s):

I. Yamanaka ◽

T. Nabeta ◽

S. Takenaka ◽

K. Otsuka

Keyword(s):

Catalytic System ◽

Mild Conditions ◽

Hydroxylation Of Benzene ◽

Direct Hydroxylation

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A Pd-Catalyzed in situ domino process for mild and quantitative production of 2,5-dimethylfuran directly from carbohydrates

Green Chemistry ◽

10.1039/c7gc00580f ◽

2017 ◽

Vol 19 (9) ◽

pp. 2101-2106 ◽

Cited By ~ 34

Author(s):

Hu Li ◽

Wenfeng Zhao ◽

Anders Riisager ◽

Shunmugavel Saravanamurugan ◽

Zhongwei Wang ◽

...

Keyword(s):

Catalytic System ◽

Mild Conditions

A sustainable catalytic system is developed to be efficient for producing the biofuel 2,5-dimethylfuran directly from carbohydrate biomass via an in situ domino process under mild conditions.

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A cobalt-substituted Keggin-type polyoxometalate for catalysis of oxidative aromatic cracking reactions in water

Catalysis Science & Technology ◽

10.1039/d0cy01758b ◽

2020 ◽

Vol 10 (23) ◽

pp. 8042-8048

Author(s):

Yoshihiro Shimoyama ◽

Satoru Tamura ◽

Yasutaka Kitagawa ◽

Dachao Hong ◽

Yoshihiro Kon

Keyword(s):

Sodium Bicarbonate ◽

Catalytic System ◽

Mild Conditions ◽

Keggin Type

Oxidative aromatic cracking reactions in water were achieved using a catalytic system with a cobalt-substituted Keggin-type polyoxometalate as a catalyst, an Oxone® as a sacrificial oxidant and sodium bicarbonate as an additive under mild conditions.

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Modified Montmorillonite Clay Stabilized Silver Nanoparticles: An Active Heterogeneous Catalytic System for the Synthesis of Propargylamines

Catalysis Letters ◽

10.1007/s10562-015-1679-0 ◽

2016 ◽

Vol 146 (3) ◽

pp. 656-665 ◽

Cited By ~ 12

Author(s):

Subrat Jyoti Borah ◽

Diganta Kumar Das

Keyword(s):

Silver Nanoparticles ◽

Catalytic System ◽

Montmorillonite Clay ◽

Heterogeneous Catalytic ◽

Modified Montmorillonite ◽

Heterogeneous Catalytic System

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Pd(CH3CN)2Cl2/Pipecolinic Acid as a Highly Efficient Catalytic System for Suzuki-Miyaura Cross-coupling Reaction of Bromoaryl Carboxylic Acids in Water

Catalysts ◽

10.3390/catal9010086 ◽

2019 ◽

Vol 9 (1) ◽

pp. 86 ◽

Cited By ~ 1

Author(s):

Xiaogang Li ◽

Wenbin Zhang ◽

Leiqing Fu ◽

Mengping Guo

Keyword(s):

Catalytic System ◽

Coupling Reaction ◽

Cross Coupling ◽

Catalytic Performance ◽

High Turnover ◽

Mild Conditions ◽

Highly Efficient ◽

Cross Coupling Reaction ◽

Pipecolinic Acid ◽

Excellent Catalytic Performance

In this study, a convenient and highly efficient catalytic system for the Suzuki-Miyaura coupling reaction was investigated under mild conditions. A combination of Pd(CH3CN)2Cl2 and pipecolinic acid showed excellent catalytic performance and afforded high turnover numbers; turnover numbers were up to 4.9 × 105 for the coupling reaction of 4-bromobenzoic acid and tetraphenylboron sodium. The catalytic system was also effective for the indexes of 4-bromobenzoic acid, and high turnover numbers were obtained.

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Dawson-type polyoxometalate-based vacancies g-C3N4 composite-nanomaterials for efficient photocatalytic nitrogen fixation

Inorganic Chemistry Frontiers ◽

10.1039/c9qi01093a ◽

2019 ◽

Vol 6 (11) ◽

pp. 3315-3326 ◽

Cited By ~ 6

Author(s):

Xiao-Hong Li ◽

Wei-Lin Chen ◽

Peng He ◽

Ting Wang ◽

Ding Liu ◽

...

Keyword(s):

Nitrogen Fixation ◽

Catalytic System ◽

Defect Structure ◽

Composite Nanomaterials ◽

Self Healing ◽

Mild Conditions ◽

System P

POM@V-g-C3N4 show outstanding photocatalytic N2 fixation activities at mild conditions under illumination due to the excellent POM properties and rich defect structure. The reaction can form a self-healing, recyclable N2-fixing catalytic system.

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Direct Dehydrogenative Coupling of Alcohols with Hydrosilanes Promoted by Sodium tri(sec-butyl)borohydride

Catalysts ◽

10.3390/catal8120618 ◽

2018 ◽

Vol 8 (12) ◽

pp. 618 ◽

Cited By ~ 2

Author(s):

Maciej Skrodzki ◽

Maciej Zaranek ◽

Samanta Witomska ◽

Piotr Pawluc

Keyword(s):

Organic Synthesis ◽

Catalytic System ◽

Mild Conditions ◽

Dehydrogenative Coupling ◽

Stoichiometric Reaction ◽

Work Up

Alkoxysilanes find application in many areas of chemistry ranging from research-scale organic synthesis to multi-ton production of materials. Classically, they are obtained in stoichiometric reaction of alcoholysis of chlorosilanes, however, recent years brought development in the field of direct dehydrogenative coupling of hydrosilanes with alcohols, which is a more atom-economic and benign alternative to the former process. In this paper, we report the use of sodium tri(sec-butyl)borohydride as a convenient promoter of this reaction. Exemplary syntheses carried out under mild conditions and without additional solvents, followed by very easy work-up procedure, show excellent potential for application of so devised catalytic system.

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