Toward Metal-Organic-Framework-Based Supercapacitors: Room-Temperature Synthesis of Electrically Conducting MOF-Based Nanocomposites Decorated with Redox-Active Manganese

2019 ◽  
Vol 2019 (26) ◽  
pp. 3034-3034
Author(s):  
Yi-Sen Wang ◽  
Yu-Chuan Chen ◽  
Jun-Hong Li ◽  
Chung-Wei Kung
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Temperature Synthesis ◽  
Room Temperature Synthesis ◽  
Electrically Conducting ◽  
Redox Active ◽  
Metal Organic ◽  
Organic Framework

Room Temperature Synthesis of an 8-Connected Zr-Based Metal–Organic Framework for Top-Down Nanoparticle Encapsulation

2018 ◽  
Vol 30 (7) ◽  
pp. 2193-2197 ◽  
Author(s):  
Hyunho Noh ◽  
Chung-Wei Kung ◽  
Timur Islamoglu ◽  
Aaron W. Peters ◽  
Yijun Liao ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Top Down ◽  
Temperature Synthesis ◽  
Room Temperature Synthesis ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Room temperature synthesis of metal organic framework MOF-2

2014 ◽  
Vol 21 (5) ◽  
pp. 769-773 ◽  
Author(s):  
Negash Getachew ◽  
Yonas Chebude ◽  
Isabel Diaz ◽  
Manuel Sanchez-Sanchez
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Temperature Synthesis ◽  
Room Temperature Synthesis ◽  
Metal Organic ◽  
Organic Framework

scholarly journals A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands

2021 ◽  
Vol 9 ◽  
Author(s):  
Monica A. Gordillo ◽  
Paola A. Benavides ◽  
Kaybriana Spalding ◽  
Sourav Saha
Keyword(s):  
Metal Organic Framework ◽  
Charge Carrier Concentration ◽  
Charge Movement ◽  
Transport Pathways ◽  
Electrically Conducting ◽  
Redox Active ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Bond Charge ◽  
Organic Framework

A new electrically conducting 3D metal-organic framework (MOF) with a unique architecture was synthesized using 1,2,4,5-tetrakis-(4-carboxyphenyl)benzene (TCPB) a redox-active cis-dipyridyl-tetrathiafulvalene (Z-DPTTF) ligand. While TCPB formed Zn2(COO)4 secondary building units (SBUs), instead of connecting the Zn2-paddlewheel SBUs located in different planes and forming a traditional pillared paddlewheel MOF, the U-shaped Z-DPTTF ligands bridged the neighboring SBUs formed by the same TCPB ligand like a sine-curve along the b axis that created a new sine-MOF architecture. The pristine sine-MOF displayed an intrinsic electrical conductivity of 1 × 10−8 S/m, which surged to 5 × 10−7 S/m after I2 doping due to partial oxidation of electron rich Z-DPTTF ligands that raised the charge-carrier concentration inside the framework. However, the conductivities of the pristine and I2-treated sine-MOFs were modest possibly because of large spatial distances between the ligands that prevented π-donor/acceptor charge-transfer interactions needed for effective through-space charge movement in 3D MOFs that lack through coordination-bond charge transport pathways.

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