Gold(I) Complexes in Ionic Liquids: An Efficient Catalytic System for the C-H Functionalization of Arenes and Heteroarenes under Mild Conditions

2019 ◽  
Vol 2019 (22) ◽  
pp. 3687-3693 ◽  
Author(s):  
Marco Baron ◽  
Andrea Biffis
Keyword(s):  
Ionic Liquids ◽  
Catalytic System ◽  
Mild Conditions

Eco-friendly acetylcholine-carboxylate bio-ionic liquids for controllable N-methylation and N-formylation using ambient CO2 at low temperatures

2019 ◽  
Vol 21 (3) ◽  
pp. 567-577 ◽  
Author(s):  
Wenfeng Zhao ◽  
Xiaoping Chi ◽  
Hu Li ◽  
Jian He ◽  
Jingxuan Long ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Catalytic System ◽  
Low Temperatures ◽  
Mild Conditions ◽  
Ambient Co2

A sustainable and recyclable ionic liquid catalytic system is developed to be efficient in N-methylation or N-formylation of amines with CO2 under mild conditions.

Practical allylation with unactivated allylic alcohols under mild conditions

2021 ◽  
Author(s):  
Shuangshuang Li ◽  
Ju Qiu ◽  
Bowen Li ◽  
Zuolian Sun ◽  
Peizhong Xie ◽  
...  
Keyword(s):  
Proton Transfer ◽  
Catalytic System ◽  
Allylic Alcohols ◽  
Mild Conditions ◽  
Accelerate Proton

A practical palladium/calcium catalytic system was developed for dehydrative allylation concerning unactivated allylic alcohols. EtOH solvent with H2O additive was identified as powerful media to accelerate proton transfer. That catalytic...

A Pd-Catalyzed in situ domino process for mild and quantitative production of 2,5-dimethylfuran directly from carbohydrates

2017 ◽  
Vol 19 (9) ◽  
pp. 2101-2106 ◽  
Author(s):  
Hu Li ◽  
Wenfeng Zhao ◽  
Anders Riisager ◽  
Shunmugavel Saravanamurugan ◽  
Zhongwei Wang ◽  
...  
Keyword(s):  
Catalytic System ◽  
Mild Conditions

A sustainable catalytic system is developed to be efficient for producing the biofuel 2,5-dimethylfuran directly from carbohydrate biomass via an in situ domino process under mild conditions.

scholarly journals Efficient transformation of CO2 to cyclic carbonates using bifunctional protic ionic liquids under mild conditions

2019 ◽  
Vol 21 (12) ◽  
pp. 3456-3463 ◽  
Author(s):  
Xianglei Meng ◽  
Zhaoyang Ju ◽  
Suojiang Zhang ◽  
Xiaodong Liang ◽  
Nicolas von Solms ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
High Activity ◽  
Cyclic Carbonates ◽  
Protic Ionic Liquids ◽  
Mild Conditions ◽  
Efficient Transformation ◽  
Mild Temperature

Bifunctional protic ionic liquids were prepared and they showed high activity for conversion of CO2 with epoxides at mild temperature (30–50 °C) and 1 bar CO2.

A cobalt-substituted Keggin-type polyoxometalate for catalysis of oxidative aromatic cracking reactions in water

2020 ◽  
Vol 10 (23) ◽  
pp. 8042-8048
Author(s):  
Yoshihiro Shimoyama ◽  
Satoru Tamura ◽  
Yasutaka Kitagawa ◽  
Dachao Hong ◽  
Yoshihiro Kon
Keyword(s):  
Sodium Bicarbonate ◽  
Catalytic System ◽  
Mild Conditions ◽  
Keggin Type

Oxidative aromatic cracking reactions in water were achieved using a catalytic system with a cobalt-substituted Keggin-type polyoxometalate as a catalyst, an Oxone® as a sacrificial oxidant and sodium bicarbonate as an additive under mild conditions.

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