Composite PEDOT/Au Nanoparticles Modified Electrodes for Determination of Mercury at Trace Levels by Anodic Stripping Voltammetry

2010 ◽  
Vol 23 (2) ◽  
pp. 456-462 ◽  
Author(s):  
Marco Giannetto ◽  
Giovanni Mori ◽  
Fabio Terzi ◽  
Chiara Zanardi ◽  
Renato Seeber
e-Polymers ◽  
2016 ◽  
Vol 16 (2) ◽  
pp. 117-123 ◽  
Author(s):  
Shirley T. Palisoc ◽  
Michelle T. Natividad ◽  
Nicole Mae D.C. Martinez ◽  
Rochelle Marie A. Ramos ◽  
Kevin Anthony Y. Kaw

Abstract[Ru(NH3)6]3+/Nafion modified indium tin oxide (ITO) electrodes were fabricated via the drop coating technique and were used for the simultaneous determination of lead (Pb2+), cadmium (Cd2+), and zinc (Zn2+) in trace amounts using anodic stripping voltammetry (ASV). The amount of [Ru(NH3)6]3+ in the coating solution was varied at 5 mg, 10 mg, and 15 mg. The fabricated electrodes were used to detect varying concentrations of Pb, Cd and Zn. ASV results showed that as the amount of [Ru(NH3)6]3+ was increased, the reduction current of the heavy metals increased as well. The Pearson correlation values obtained for Pb and Cd were close to 1.0, indicating a strong positive linear relationship between the variables. The minimum heavy metal concentration that can be simultaneously detected by the fabricated electrodes is 0.5 ppm.


2014 ◽  
Vol 17 (4) ◽  
pp. 205-208 ◽  
Author(s):  
Shirley Tiong Palisoc ◽  
Michelle Tiamzon Natividad ◽  
Patricia Denise DeVera ◽  
Benjamin Simone B. Tuason

Chemically modified [Ru(NH3)6]3+ doped Nafion® thin film was fabricated on indium tin oxide (ITO) coated glass electrodes by using the drop-coating method to detect heavy metal ions of Pb(II) in de-ionized water analyte solution via anodic stripping voltammetry (ASV). This study also determined the effect of varying the concentration of the mediator ([Ru(NH3)6]3+) on the detection of the said heavy metals. The redox mediator Ru(NH3)6]3+ used in the study was effectively incorporated and immobilized within the Nafion modified electrodes. Lead concentration in the electrolyte solution and the concentration of the redox mediator was varied to control the properties of the fabricated electrodes which utilized for heavy metal detection through ASV. The conducting properties of ITO electrodes were enhanced with the deposition of Nafion® attaining minimal interference. The stripping current peaks increased with the concentration of the heavy metal present in the solution as well as with the mediator concentration.


2016 ◽  
Vol 8 (8) ◽  
pp. 1935-1941 ◽  
Author(s):  
Yangjuan Wang ◽  
Yuanping Peng ◽  
Yifu Chen ◽  
Kejing Du ◽  
Yijun Li ◽  
...  

A silver-based coordination complex was synthesized from melamine (MA), terephthalic acid (TPA) and silver nitrate for the determination of Pb2+ at the trace level by differential pulse anodic stripping voltammetry (DPASV).


Author(s):  
Larissa Pinto Silva ◽  
Náira Da Silva Campos ◽  
Thalles Pedrosa Lisboa ◽  
Lucas Vinícius de Faria ◽  
Maria Auxiliadora Costa Matos ◽  
...  

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