Prediction of binary component isotherms for adsorption on heterogeneous surfaces

2007 ◽  
Vol 53 (4) ◽  
pp. 345-352 ◽  
Author(s):  
B. Al-Duri ◽  
Y. Khader ◽  
G. McKay
Keyword(s):  
Heterogeneous Surfaces ◽  
Binary Component ◽  
Adsorption On Heterogeneous Surfaces

Adsorption on heterogeneous surfaces: Numerical analysis of models for the Dubinin-Radushkevich equation

1981 ◽  
Vol 46 (8) ◽  
pp. 1709-1721 ◽  
Author(s):  
Miloš Smutek ◽  
Arnošt Zukal
Keyword(s):  
Integral Equation ◽  
Numerical Analysis ◽  
Numerical Method ◽  
Adsorption Behaviour ◽  
Heterogeneous Surfaces ◽  
Strong Energy ◽  
Adsorption On Heterogeneous Surfaces ◽  
Heterogeneity Parameter ◽  
Adsorption Energies ◽  
Mobile Adsorption

A numerical method, based on the integral equation of the adsorption on energy heterogeneous surfaces, is suggested for the evaluation of overall isotherm. It is shown that for the distribution of adsorption energies given by Eq. (1.11) and different models of the adsorption behaviour, the overall isotherms obey approximately the Dubinin-Radushkevich equation. The strong energy heterogeneity smears effectively the differences between the localized and mobile adsorption and leads to the same character of the overall isotherm with only a slightly changed heterogeneity parameter.

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