Adsorption on heterogeneous surfaces: Numerical analysis of models for the Dubinin-Radushkevich equation

1981 ◽  
Vol 46 (8) ◽  
pp. 1709-1721 ◽  
Author(s):  
Miloš Smutek ◽  
Arnošt Zukal

A numerical method, based on the integral equation of the adsorption on energy heterogeneous surfaces, is suggested for the evaluation of overall isotherm. It is shown that for the distribution of adsorption energies given by Eq. (1.11) and different models of the adsorption behaviour, the overall isotherms obey approximately the Dubinin-Radushkevich equation. The strong energy heterogeneity smears effectively the differences between the localized and mobile adsorption and leads to the same character of the overall isotherm with only a slightly changed heterogeneity parameter.

1958 ◽  
Vol 36 (12) ◽  
pp. 1624-1633 ◽  
Author(s):  
W. R. Dixon ◽  
J. H. Aitken

The problem of making resolution corrections in the scintillation spectrometry of continuous X rays is discussed. Analytical solutions are given to the integral equation which describes the effect of the statistical spread in pulse height. The practical necessity of making some kind of numerical analysis is pointed out. Difficulties with numerical methods arise from the fact that the observed pulse-height distribution cannot be defined precisely. As a result it is possible in practice only to find smooth "solutions". Additional difficulties arise if the numerical method is based on an invalid analytical procedure. For example matrix inversion is of doubtful value in making the resolution correction because there does not appear to be an inverse kernel for the integral equation in question.


Author(s):  
Muhammad Hassan ◽  
Benjamin Stamm

In this article, we analyse an integral equation of the second kind that represents the solution of N interacting dielectric spherical particles undergoing mutual polarisation. A traditional analysis can not quantify the scaling of the stability constants- and thus the approximation error- with respect to the number N of involved dielectric spheres. We develop a new a priori error analysis that demonstrates N-independent stability of the continuous and discrete formulations of the integral equation. Consequently, we obtain convergence rates that are independent of N.


2019 ◽  
Vol 21 (2) ◽  
pp. 1-5
Author(s):  
Marcin Nabrdalik ◽  
Michał Sobociński

Abstract The paper presents analysis of stress distribution in the friction node of knee joint endoprosthesis where sleds are made of various titanium alloys and CoCrMo cooperate with spherical polyethylene inserts. Currently used titanium alloys consists of Nb, Ta, Zr or Mo and with lesser value of Young’s modulus than Ti6Al4V alloy, or steel CoCrMo, which significantly varies from other metal materials. The obtained results make it possible to indicate the “weak points” of the accepted solution, and thus counteract the subsequent effects resulting from premature wear of endoprosthesis elements. The analysis was conducted with numerical method of ADINA System 8.6. The Finite Elements Method allowed to compute and present stress distribution quickly in all elements of the model.


2008 ◽  
Vol 580-582 ◽  
pp. 213-216
Author(s):  
Seong Hyuk Lee ◽  
Jung Hee Lee ◽  
Jin Woon Lee ◽  
Jong Min Kim

A new hybrid soldering and conductive adhesive joining technology using a fusible lowmelting- point alloy (LMPA) have been developed. A numerical method for numerical analysis of fusible particles behavior is proposed to investigate coalescence characteristics of fusible particles in solderable isotropic conductive adhesives (ICAs). For finding out suitable conditions to obtain reliable conduction paths, the present study examines the influence of process-related parameters such as volume fraction and viscosity on coalescence characteristics of fusible particles.


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