Determination of rice husk activated Carbon capacity in adsorption of Cu Metal from Sasirangan liquid waste based on isotherm model

The process of manufacturing Sasirangan - a traditional fabric of South Kalimantan - has an impact that affects environmental pollution, namely the dyeing process of the fabric. The synthetic dyes used contain heavy metals and one of those toxic metals is copper (Cu). This study aims to determine the adsorption capacity of rice husk activated carbon adsorbent by adjusting the adsorption pattern based on isotherm models as the treatment to sasirangan liquid waste. The method consists of three stages: preparation of adsorbent by carbonization process, chemical and physical activation, then continued by adsorption process of Cu metal with carbon from rice husks with variations of adsorbent dose (2, 4, and 6 grams). This treatment was conducted by batch process. In this reseach, the adsorption capacity of rice husk adsorbent towards heavy metal Cu in sasirangan liquid waste was determined from the equilibrium state with the Langmuir isotherm equation and Freundlich isotherm equation. Based on isothermal studies of adsorption data, the correlation coefficient values obtained from the isotherm model approaches are: for dose of 2 grams adsorbent, Langmuir R2 = 0.9991 and Freundlich R2 = 0.9981; for dose of 4 grams adsorbent, Langmuir R2 = 0.9992 and Freundlich R2 = 0.9989; for dose of 6 grams adsorbent, Langmuir R2 = 0.9990 and Freundlich R2 = 0.9986. The results of investigation indicate that adsorption data correlated well with Langmuir isotherm model.

Preparation and Characterization of a Novel Activated Carbon@Polyindole Composite for the Effective Removal of Ionic Dye from Water

The present study is aimed at the synthesis and exploring the efficiency of a novel activated carbon incorporated polyindole (AC@PIN) composite for adsorptive removal of Malachite Green (MG) dye from aqueous solution. An AC@PIN hybrid material was prepared by in situ chemical oxidative polymerization. The physico-chemical characteristics of the AC@PIN composite were assessed using Fourier-transform infrared spectrometer, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, ultraviolet visible spectroscopy, and determination of point of zero charge (pHPZC). A series of adsorption studies was conducted to evaluate the influence of operational parameters such as pH, contact time, initial dye concentration, AC@PIN dosage, and temperature on dye adsorption behavior of developed composite. A maximum dye removal percentage (97.3%) was achieved at the pH = 10, AC@PIN dosage = 6.0 mg, initial dye concentration 150 mg L−1, and temperature = 20 °C. The kinetic studies demonstrated that the adsorption of MG on AC@PIN followed pseudo-second-order model (R2 ≥ 0.99). Meanwhile, Langmuir isotherm model was founded to be the best isotherm model to describe the adsorption process. Finally, the recyclability test revealed that the composite exhibits good recycle efficiency and is stable after 5 cycles. The obtained results suggest that AC@PIN composite could be a potential candidate for the removal of MG from wastewater.

Adsorption Study of Soluos Dumpsite Leachate Treatment Using Musa sapientum Peels as Biosorbent

Dumpsite leachate has the potential to pollute ground and surface water as well as vegetation within the vicinity of the dumpsite. Its treatment therefore needs adequate attention. The aim of this work is to study the adsorption of Soluos dumpsite leachate treatment using Musa sapientum peel as biosorbent with a view of establishing the adsorption isotherm model. Musa sapientum peels sourced from Ayetoro market in Epe area of Lagos State, Nigeria were used to prepare the adsorbent. Batch adsorption was carried out with various dosage of the prepared absorbent in leachate collected from Soluos dumpsite in Lagos. The adsorption data obtained were fitted into Linear, Freundlich, Langmuir, Temkin and Hasley isotherm models. The results showed that the concentration of total dissolved solids (TDS) in the dumpsite leachate decreased as the adsorbent dosage increased. At adsorbent dosage of 10 g/L, the concentration of TDS in the leachate was 485.7 mg/L which was less than the 500 mg/L stipulated by National Environmental Standard and Regulatory Agency (NAESRA) for the discharge of wastewater. The coefficient of determination (R2) values for Linear, Freundlich and Hasley, Langmuir and Temkin isotherm models were 0.9944, 0.9936, 0.8562 and 0.9723 respectively. Linear isotherm model was jettisoned because the plot did not pass through the origin and Freundlich isotherm model was ignored as a result of N value which was less than unity hence Hasley isotherm model was adopted in this work. A good correlation existed between the experimental and predicted values, having a R2 value of 0.9965 which further validated the Hasley isotherm model as the best adsorption model for the treatment of Soluos dumpsite leachate using Musa sapientum peel as biosorbent. It was concluded that Musa sapientum peel as biosorbent can be used for treatment of Soluos dumpsite leachate.

Sorption of Monothioarsenate to the Natural Sediments and Its Competition with Arsenite and Arsenate

Monothioarsenate (MTAsV) is one of the major arsenic species in sulfur- or iron-rich groundwater, and the sediment adsorption of MTAsV plays an important role in arsenic cycling in the subsurface environment. In this study, batch experiments and characterization are conducted to investigate the sorption characteristic and mechanism of MTAsV on natural sediments and the influences of arsenite and arsenate. Results show that MTAsV adsorption on natural sediments is similar to arsenate and arsenite, manifested by a rapid early increasing stage, a slowly increasing stage at an intermediate time until 8 h, before finally approaching an asymptote. The sediment sorption for MTAsV mainly occurs on localized sites with high contents of Fe and Al, where MTAsV forms a monolayer on the surface of natural sediments via a chemisorption mechanism and meanwhile the adsorbed MTAsV mainly transforms into other As species, such as AlAs, Al-As-O, and Fe-As-O compounds. At low concentration, MTAsV sorption isotherm by natural sediments becomes the Freundlich isotherm model, while at high concentration of MTAsV, its sorption isotherm becomes the Langmuir isotherm model. The best-fitted maximum adsorption capacity for MTAsV adsorption is about 362.22 μg/g. Furthermore, there is a competitive effect between MTAsV and arsenate adsorption, and MTAsV and arsenite adsorption on natural sediments. More specifically, the presence of arsenite greatly decreases MTAsV sorption, while the presence of MTAsV causes a certain degree of reduction of arsenite adsorption on the sediments before 4 h, and this effect becomes weaker when approaching the equilibrium state. The presence of arsenate greatly decreases MTAsV sorption and the presence of MTAsV also greatly decreases arsenate sorption. These competitive effects may greatly affect MTAsV transport in groundwater systems and need more attention in the future.

Study on Optimum IUPAC Adsorption Isotherm Models Employing Sensitivity of Parameters for Rigorous Adsorption System Performance Evaluation

Adsorption cooling technologies driven by low-grade thermal or solar power are used as an energy-efficient alternative to conventional refrigeration and air conditioning systems. Explicit understanding of the adsorption cycles requires precise determination of the performance parameters, replication of the experimental data, and the rigorous study of the adsorption heat transformation method. Hence, the optimum adsorption isotherms model must be identified. Scientists often face difficulties in selecting the suitable isotherm model as there are many models for a particular form of adsorption isotherm. The present study introduces a novel approach for choosing the optimal models for each type of International Union of Pure and Applied Chemistry (IUPAC) classified adsorption isotherm using robust statistical methods. First, the box-and-whisker plots of error identification are employed. Tóth for Type-I(a) and Type-I(b), modified BET for Type-II, GAB for Type-III, Universal for Type-IV(a), and Type-IV(b), Sun Chakrabarty for Type-V, and Yahia et al. for Type-VI were found lower than the other candidate models in box-and-whisker plot. The optimality of our selected models was further verified using analysis of variance (ANOVA), pairwise Tukey honest significant difference (HSD) test, Kruskal–Wallis rank-sum test, and pairwise Wilcoxon rank-sum test. In short, rigorous statistical analysis was performed to identify the best model for each type of isotherm by minimizing error. Moreover, specific cooling effect (SCE) of Maxsorb III/ethanol and silica gel/water pairs were determined. Results showed that Tóth is the optimal isotherm model for the studied pairs, and the SCE values obtained from the model agree well with experimental data. The optimum isotherm model is indispensable for the precise designing of the next generation adsorption cooling cycles.

Aplikasi Zeolit Alam Aktif Wonosari Sebagai Adsorben Zat Warna Remazol Yellow Fg

Zeolite as an adsorbent has been widely used. Zeolite activation was carried out to increase the absorption. This study aimed to determine the characteristics of the active zeolite and apply it as an adsorbent. The activation process was carried out by adding acid and calcining at 4500C for 6 hours. Remazol Yellow FG is a dye that is widely used in the textile industry. In this study, the adsorption process was carried out on the Remazol Yellow FG solution, then analyzed the effect of changes in pH (5, 6, 7, 8, 9), contact time (30, 60, 90, 120, 150 minutes) and the concentration of Remazol Yellow FG solution ( 50, 100, 150, 200, 250 ppm) on the adsorption of Remazol Yellow FG dye. From the analysis of the sample solution of Remazol Yellow, the values of Ce and qe can be calculated. These values were then used to calculate KL and KF in the Langmuir adsorption isotherm and Freundlich adsorption isotherm models. From the experimental results, it could be seen that as the contact time increased, the adsorption capacity would be greater. However, when the zeolite was already in the saturated phase, the adsorption capacity would tend to decrease. In the Langmuir adsorption isotherm, the KL value was 0.0274 L/mg and in the Freundlich adsorption isotherm model, the KF value was 29.25 L/mg. Remazol Yellow FG adsorption tended to follow the Langmuir adsorption isotherm model with an R2 value of 0.998.

Treatment of Bilge Water by Fenton Oxidation Followed by Granular Activated Carbon Adsorption

Due to its high oil content, the discharge of bilge water from ships is one of the most important pollutants in marine ecosystem. In this research, we investigated the treatment of bilge water for Haydarpasa Waste Collection Plant by Fenton oxidation followed by granular activated carbon (GAC) adsorption. We applied the following optimum operational conditions for Fenton oxidation: [Fe2+]: 6 mM; [H2O2]: 30 mM; and the ratio of [Fe2+]/[H2O2]: 1/5. Adsorption was performed in the effluent sample of Fenton oxidation. The effects of different adsorption periods, adsorbent concentrations, temperature, and pH were examined. Additionally, Freundlich and Langmuir isotherm models were applied. We obtained the following optimum operational conditions: 24 h, 2 g of GAC L−1, 20 °C, and pH = 6. We observed an 89.5 ± 1.9% of Chemical Oxygen Demand (COD) removal efficiency under these conditions. Data generated from the experiments fit both isotherm models well, though we preferred the Langmuir isotherm model to the Freundlich isotherm model because the former’s regression coefficient (0.90) was larger than that reported for the Freundlich isotherm model (0.78). The potential to treat bilge water by Fenton oxidation followed by granular activated carbon is promising for the Haydarpasa Waste Collection Plant.

A Simple One-Step Modification of Shrimp Shell for the Efficient Adsorption and Desorption of Copper Ions

Removing toxic heavy metal species from aqueous solutions is a point of concern in our society. In this paper, a promising biomass adsorbent, the modified waste shrimp shell (MS), for Cu (II) removal was successfully prepared using a facile and simple one-step modification, making it possible to achieve high-efficiency recycling of the waste NaOH solution as the modification agent. The outcome shows that with the continuous increase in pH, temperature and ion concentration, the adsorption effect of MS on Cu (II) can also be continuously improved. Adsorption isotherm and adsorption kinetics were fitted with the Langmuir isotherm model and the pseudo-second-order model, respectively, and the maximum adsorption capacity of Cu (II) as obtained from the Langmuir isotherm model fitting reached 1.04 mmol/g. The systematic desorption results indicated that the desorption rate of Cu (II) in the MS could reach 100% within 6 min, where HNO3 is used as the desorption agent. Moreover, experiments have proven that after five successive recycles of NaOH as a modifier, the adsorption capacity of MS on Cu (II) was efficient and stable, maintaining tendency in 0.83–0.85 mmol/g, which shows that waste NaOH solution can be used as a modification agent in the preparation of waste shrimp shell adsorbent, such as waste NaOH solution produced in industrial production, thereby making it possible to turn waste into renewable resources and providing a new way to recycle resources.