Radical Additions of Alkyl 2-Haloalkanoates and 2-Haloalkanenitriles to Alkenes Initiated by Electron Transfer from Copper in Solvent-Free Systems

1997 ◽  
Vol 1997 (11) ◽  
pp. 2303-2313 ◽  
Author(s):  
Jürgen O. Metzger ◽  
Ralf Mahler ◽  
Gerald Francke
Keyword(s):  
Electron Transfer ◽  
Solvent Free

Cycloaddition of CO2 with epoxides and esterification reactions using the porous redox catalyst Co-POM@MIL-101(Cr)

2019 ◽  
Vol 43 (39) ◽  
pp. 15585-15595 ◽  
Author(s):  
Afsaneh Marandi ◽  
Mehrnaz Bahadori ◽  
Shahram Tangestaninejad ◽  
Majid Moghadam ◽  
Valiollah Mirkhani ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Acetic Acid ◽  
Catalytic Activity ◽  
Outer Sphere ◽  
Transfer Mechanism ◽  
Solvent Free ◽  
Electron Transfer Mechanism ◽  
Redox Catalyst ◽  
Redox Pair ◽  
Esterification Reactions

The catalytic activity of the Co-POM@MIL-101(Cr) composite in solvent-free cycloaddition of CO2 to epoxides and esterification of acetic acid with alcohols is due to an outer-sphere electron transfer mechanism using the Co(iii)/Co(ii) redox pair.

scholarly journals Quinone Redox-active Ionic Liquids

2017 ◽  
Vol 59 (4) ◽  
Author(s):  
Andrew Patrick Doherty ◽  
Sean Patterson ◽  
Laura Diaconu Diaconu ◽  
Louise Graham ◽  
Rachid Barhdadi ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Solvent Free ◽  
Large Array ◽  
Transfer Processes ◽  
Redox Active ◽  
Electron Transfer Processes ◽  
Physical And Chemical

<p>Simple ionic liquids exhibit unique physical and chemical<br />properties that make them very useful for deployment in electrochemical<br />devices such as solvent-free electrolytes in capacitors and batteries.<br />However, incorporating redox functionality into ionic liquid<br />structures opens up in situ faradaic electrochemistry which allows access<br />to a large array of new electrochemical applications reliant upon<br />heterogeneous or homogenous electron-transfer processes. This paper<br />presents and discusses the opportunities and challenges for these types<br />of electro-materials across a myriad of applications by considering<br />exemplar quinone-functionalised ionic liquids.</p>

Long-range electron transfer in solvent-free supermolecules

1992 ◽  
Vol 197 (1-2) ◽  
pp. 131-135 ◽  
Author(s):  
Joshua Jortner ◽  
M. Bixon ◽  
H. Heitele ◽  
M.E. Michel-Beyerle
Keyword(s):  
Electron Transfer ◽  
Long Range ◽  
Solvent Free
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