Synthesis and Characterization of Zn–Organic Frameworks Containing Chitosan as a Low-Cost Inhibitor for Sulfuric-Acid-Induced Steel Corrosion: Practical and Computational Exploration

In this work, a Zn–benzenetricarboxylic acid (Zn@H3BTC) organic framework coated with a dispersed layer of chitosan (CH/Zn@H3BTC) was synthesized using a solvothermal approach. The synthesized CH/Zn@H3BTC was characterized by Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscope (FESEM), thermal gravimetric analysis (TGA), and Brunauer, Emmett, and Teller (BET) surface area. The microscopic observation and the analysis of the BET surface area of CH/Zn@H3BTC nanocomposites indicated that chitosan plays an important role in controlling the surface morphology and surface properties of the Zn@H3BTC. The obtained findings showed that the surface area and particle size diameter were in the range of 80 m2 g−1 and 800 nm, respectively. The corrosion protection characteristics of the CH/Zn@H3BTC composite in comparison to pristine chitosan on duplex steel in 2.0 M H2SO4 medium determined by electrochemical (E vs. time, PDP, and EIS) approaches exhibited that the entire charge transfer resistance of the chitosan- and CH/Zn@H3BTC-composite-protected films on the duplex steel substrate was comparatively large, at 252.4 and 364.8 Ω cm2 with protection capacities of 94.1% and 97.8%, respectively, in comparison to the unprotected metal surface (Rp = 20.6 Ω cm2), indicating the films efficiently protected the metal from corrosion. After dipping the uninhabited and protected systems, the surface topographies of the duplex steel were inspected by FESEM. We found the adsorption of the CH/Zn@H3BTC composite on the metal interface obeys the model of the Langmuir isotherm. The CH/Zn@H3BTC composite revealed outstanding adsorption on the metal interface as established by MD simulations and DFT calculations. Consequently, we found that the designed CH/Zn@H3BTC composite shows potential as an applicant inhibitor for steel protection.

Enhancing the polymer electrolyte – Li metal interface on high-voltage solid-state batteries with Li-based additives inspired by the surface chemistry of Li7La3Zr2012

High-voltage Li metal solid-state batteries are in the spotlight of high energy and power density devices for the next generation of batteries. However, the lack of robust solid-electrolyte interfaces (SEI)...

Application of digital image processing technique in the microstructure analysis and the machinability investigation

Introduction. The world is at the stage of creating an interdisciplinary approach that will be implemented in metallurgical research. The paper formulates the technique of image analysis in the study of processing at different depths from the mold-metal interface. The purpose of the work. Processing of a cast-iron workpiece within the first 3.5 mm of thickness from the mold-metal interface is a serious problem of solid processing. The study of machinability at different depths is a key requirement of the industry for ease of processing. Machinability will determine a number of factors, including tool consumption, workpiece surface quality, energy consumption, etc. The method of investigation. Image analysis is performed to determine the percentage of graphite in etched and non-etched samples. K-means clustering allows to create a new image from a given one with a clear separation of white and black areas by converting a digital image into a binary image using a threshold value for segmentation. The volume fraction of perlite, the volume fraction of graphite and the average size of graphite flakes in microns are used as input variables for the machinability of cast iron. Results and discussion. The output, that is, the segmented image, will be the input function for calculating the workability index using formulas. Thus, microstructural analysis will help predict the workability index of grey cast iron ASTM A48 Class 20. Using this method and the program, based on the microstructure, it is possible to predict in advance the characteristics of the machining of the part, taking into account possible changes in the casting process itself.

Identification of the position of piezoelectric polarization at the MoS2/metal interface

Transition-metal dichalcogenides, such as MoS2, lack their inversion center in monolayers, exhibiting in-plane piezoelectricity at a nanoscale thickness. In conventional piezoceramics devices, the operating mechanism has been well established that piezocharges appear at crystal edges and how these charges act in capacitor structures. Although TMDC monolayers are expected to possess a unique system due to their semiconductor nature, a strong interaction with contact metals alters physical properties predominantly. In this study, we identify the position of piezocharges in MoS2 generators based on the displacement current under dynamic strain. The present results provide new insights for the future device engineering.