Determination of the electron affinities of ?- and ?-naphthyl radicals using the kinetic method with full entropy analysis. The C ? H bond dissociation energies of naphthalene

2001 ◽  
Vol 36 (6) ◽  
pp. 607-615 ◽  
Author(s):  
Harvey A. Lardin ◽  
Robert R. Squires ◽  
Paul G. Wenthold
Keyword(s):  
Kinetic Method ◽  
Bond Dissociation Energies ◽  
Electron Affinities ◽  
Entropy Analysis ◽  
Bond Dissociation ◽  
Dissociation Energies

Electron affinities of a homologous series of tertiary alkyl radicals and their C–H bond dissociation energies (BDEs)

Tetrahedron ◽  
2009 ◽  
Vol 65 (8) ◽  
pp. 1655-1659 ◽  
Author(s):  
Panayiotis S. Petrou ◽  
Athanassios V. Nicolaides
Keyword(s):  
Homologous Series ◽  
Bond Dissociation Energies ◽  
Electron Affinities ◽  
Alkyl Radicals ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Tertiary Alkyl

Experimental methods for measurement of bond dissociation energies and heats of formation of radicals

1951 ◽  
Vol 207 (1088) ◽  
pp. 5-13 ◽  
Keyword(s):  
Experimental Methods ◽  
Experimental Results ◽  
Heats Of Formation ◽  
Bond Dissociation Energies ◽  
Carrier Gas ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Kinetics Of

The paper describes a pyrolytic method of investigating the kinetics of gaseous reactions in which toluene is used as a carrier gas. It is shown that the method is particularly suitable for the determination of bond dissociation energies. The scope of the method is illustrated by various examples. A list of bond dissociation energies obtained is given. The manner in which the experimental results obtained can be cross-checked, is indicated and illustrated by examples. The effects of various constitutional factors on the bond dissociation energies are discussed.

Experimental and computational studies of deuterated ethanols: gas-phase acidities, electron affinities and bond dissociation energies

1993 ◽  
Vol 123 (3) ◽  
pp. 171-185 ◽  
Author(s):  
Thuy Thanh Dang ◽  
Edwin L. Motell ◽  
Michael J. Travers ◽  
Eileen P. Clifford ◽  
G. Barney Ellison ◽  
...  
Keyword(s):  
Gas Phase ◽  
Computational Studies ◽  
Bond Dissociation Energies ◽  
Electron Affinities ◽  
Bond Dissociation ◽  
Dissociation Energies

Structures and thermochemistry of ions formed by methane chemical ionization of Fe(CO)5. Site of protonation and determination of FeH and FeCO bond dissociation energies of HFe(CO)n+ ions

1993 ◽  
Vol 28 (12) ◽  
pp. 1547-1554 ◽  
Author(s):  
Dag Ekeberg ◽  
Solveig Isaksen Hagen ◽  
Georg Hvistendahl ◽  
Christian Schulze ◽  
Einar Uggerud ◽  
...  
Keyword(s):  
Chemical Ionization ◽  
Bond Dissociation Energies ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Methane Chemical Ionization
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