Desulfurization of phosphorothioate oligonucleotides via the sulfur-by-oxygen replacement induced by the hydroxyl radical during negative electrospray ionization mass spectrometry

2012 ◽  
Vol 47 (7) ◽  
pp. 836-844 ◽  
Author(s):  
Lianming Wu ◽  
David E. White ◽  
Connie Ye ◽  
Frederick G. Vogt ◽  
Gerald J. Terfloth ◽  
...  







RSC Advances ◽  
2017 ◽  
Vol 7 (69) ◽  
pp. 43540-43545 ◽  
Author(s):  
Jiying Pei ◽  
Cheng-Chih Hsu ◽  
Yinghui Wang ◽  
Kefu Yu

Quinone reduction during negative ESI MS was illustrated to be closely related to corona discharge (CD).



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