A kinetic study of free-radical copolymerization of butyl acrylate with methyl methacrylate in solution

1996 ◽  
Vol 197 (11) ◽  
pp. 3743-3755 ◽  
Author(s):  
Enrique López Madruga ◽  
Marta Fernández-García
1995 ◽  
Vol 16 (7) ◽  
pp. 503-512 ◽  
Author(s):  
Rocío Cuervo-Rodríguez ◽  
M Carmen Fernández-Monreal ◽  
Marta Fernández-García ◽  
Enrique L. Madruga

Author(s):  
Marta Fernández-García ◽  
Marina Fernández-Sanz ◽  
Enrique López Madruga ◽  
Carmen Fernández-Monreal

2012 ◽  
Vol 602-604 ◽  
pp. 781-784 ◽  
Author(s):  
Da Ping Wu ◽  
Li Na Zhu ◽  
Yan Lin Sun

The hydrophobically modified polyacrylamides (PAM) were synthesized using butyl acrylate (BA) and methyl methacrylate (MMA) as hydrophobic monomers, via water solution free radical copolymerization. The influences of hydrophobic monomer content on the molecular weight, insoluble fraction and dissolution rate of PAM were investigated. The flocculation effects of PAMs for two kinds of tailing slurry with difficult sedimentation feature were also evaluated. The results show that different flocculation effects of hydrophobically modified PAMs can be obtained according to different kinds of tailing slurry.


Processes ◽  
2019 ◽  
Vol 7 (7) ◽  
pp. 395 ◽  
Author(s):  
Javier A. Gómez-Reguera ◽  
Eduardo Vivaldo-Lima ◽  
Vida A. Gabriel ◽  
Marc A. Dubé

Kinetic modeling of the bulk free radical copolymerizations of n-butyl acrylate (BA) and 2-ethylhexyl acrylate (EHA); methyl methacrylate (MMA) and EHA; as well as BA, MMA and EHA was performed using the software PREDICI®. Predicted results of conversion versus time, composition versus conversion, and molecular weight development are compared against experimental data at different feed compositions. Diffusion-controlled effects and backbiting for BA were incorporated into the model as they proved to be significant in these polymerizations. The set of estimated global parameters allows one to assess the performance of these copolymerization systems over a wide range of monomer compositions.


1993 ◽  
Vol 26 (25) ◽  
pp. 6766-6770 ◽  
Author(s):  
Yung Dae Ma ◽  
You Chan Won ◽  
Keiji Kubo ◽  
Takeshi Fukuda

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