A Novel Characterization Method for Graft-Polymer Structures Chemically Attached on Thermally Stable Polymer Films

2011 ◽  
Vol 213 (1) ◽  
pp. 72-78 ◽  
Author(s):  
Kazuyuki Enomoto ◽  
Shuichi Takahashi ◽  
Yasunari Maekawa
2012 ◽  
Vol 445 ◽  
pp. 797-802 ◽  
Author(s):  
Alice Mesnage ◽  
Pardis Simon ◽  
Guy Deniau ◽  
Nathalie Herlin-Boime ◽  
Serge Palacin

This document aims at presenting and explaining the mechanism of a simple green process, called Graftfast©, recently developed in order to graft polymer films onto any type of materials. This process is of great interest as it works in a short one step reaction at room temperature, atmospheric pressure in water. Particularly since this method is a redoxinduced process consisting in the reduction of diazonium salts into aryl radicals in presence of vinylic monomer, the involvement of such radicals was investigated. Moreover, this work demonstrates the efficiency of such process for the preparation of functionalized TiO2 nanoparticles. The composition and the grafted polymer quantities were investigated showing the successful grafting of the polymer onto the nanoparticles while conserving their morphology.


1995 ◽  
Vol 33 (4) ◽  
pp. 577-580 ◽  
Author(s):  
Michael F. Roberts ◽  
Samson A. Jenekhe

2012 ◽  
Vol 22 (10) ◽  
pp. 2187-2193 ◽  
Author(s):  
Xiangyue Meng ◽  
Wenqing Zhang ◽  
Zhan'ao Tan ◽  
Yongfang Li ◽  
Yihan Ma ◽  
...  

ACS Nano ◽  
2011 ◽  
Vol 5 (11) ◽  
pp. 9017-9027 ◽  
Author(s):  
Dong Jin Kang ◽  
Taegyun Kwon ◽  
Minsoo P. Kim ◽  
Chul-Hee Cho ◽  
Hyunjung Jung ◽  
...  

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