Investigation on the mechanical properties and oil resistance of sulfur cured nitrile rubber/hydrogenated nitrile butadiene rubber blends

Author(s):  
Huimin Zou ◽  
Yuanrong Jing ◽  
Jieyun Tu ◽  
Xinghui Shi ◽  
Jakub Kadlcak ◽  
...  
2021 ◽  
pp. 096739112110313
Author(s):  
Ahmed Abdel-Hakim ◽  
Soma A el-Mogy ◽  
Ahmed I Abou-Kandil

Blending of rubber is an important route to modify properties of individual elastomeric components in order to obtain optimum chemical, physical, and mechanical properties. In this study, a novel modification of styrene butadiene rubber (SBR) is made by employing acrylic rubber (ACM) to obtain blends of outstanding mechanical, dynamic, and oil resistance properties. In order to achieve those properties, we used a unique vulcanizing system that improves the crosslink density between both polymers and enhances the dynamic mechanical properties as well as its resistance to both motor and break oils. Static mechanical measurements, tensile strength, elongation at break, and hardness are improved together with dynamic mechanical properties investigated using dynamic mechanical analyses. We also proposed a mechanism for the improvement of crosslink density and consequently oil resistance properties. This opens new opportunities for using SBR/ACM blends in oil sealing applications that requires rigorous mechanical and dynamic mechanical properties.


2015 ◽  
Vol 133 (4) ◽  
pp. n/a-n/a ◽  
Author(s):  
Peng Yu ◽  
Hui He ◽  
Can Jiang ◽  
Yunchao Jia ◽  
Dongqing Wang ◽  
...  

2013 ◽  
Vol 750-752 ◽  
pp. 816-819 ◽  
Author(s):  
Teng Teng Wang ◽  
Guo Lun Zhong ◽  
Li Ling Zhou

The mechanical properties, compatibility, flame retardancy property, hot-air ageing resistance of hydrogenated nitrile-butadiene rubber (HNBR) / chloroprene rubber (CR) blends were investigated. With increasing CR, stress at 100% elongation, shore A hardness, limited oxygen index of HNBR/CR blends increased, while the tensile strength, hot-air aging resistance of the blends decreased. Differential scanning calorimeter (DSC) revealed that it’s incompatible with both HNBR and CR before vulcanization, however they became compatible completely after vulcanization as indicated by Dynamic Mechanical Analysis (DMA).


2019 ◽  
pp. 089270571986648
Author(s):  
Kerui Liao ◽  
Feifei Liu ◽  
Zhaobo Wang

Thermoplastic vulcanizates (TPVs) based on ethylene-methacrylic acid (EMA) copolymer/nitrile butadiene rubber (NBR) blends were prepared by dynamic vulcanization where the NBR phase was reinforced by zinc dimethacrylate (ZDMA). The effect of ZDMA dosage on the mechanical properties, Mullins effect, and morphology of the TPVs was investigated systematically. Experimental results indicated that the mechanical properties of EMA/NBR TPVs were enhanced remarkably with the incorporation of ZDMA. Morphology study showed that the NBR particles with diameters of about 1–5 μm were dispersed evenly in the etched surface of EMA/NBR/ZDMA TPV. The Mullins effect could be observed in the stress–strain curves of EMA/NBR TPV and EMA/NBR/ZDMA TPV during the uniaxial loading–unloading cycles. Compared with those of EMA/NBR TPV, EMA/NBR/ZDMA TPV had the higher stress, residual deformation, and internal friction loss.


2019 ◽  
pp. 135-142
Author(s):  
N. V. Shadrinov ◽  
U. V. Evseeva

The results of study of the influence of hollow corundum microspheres HCM-S (5–100 µm) and HCM-L (70–180 µm) on the properties of nitrile butadiene rubber BNKS-18 are presented. The dependence of elastomer resistance to abrasion impact and physic and mechanical properties on the dispersion and concentration of hollow corundum microspheres is shown. The process of hollow corundum microspheres exfoliation of the elastomeric matrix, which largely determines the change of physic and mechanical properties, has been studied by specially developed stretching device compatible with an atomic force microscope. The paper describes microspheres exfoliation which is conventionally divided into 3 stages.


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