Reaction kinetics of graft copolymerization and thermochemical studies of the degradation of poly(vinyl alcohol) graft copolymer

2001 ◽  
Vol 50 (3) ◽  
pp. 347-353 ◽  
Author(s):  
Yassin A Aggour
2016 ◽  
Vol 852 ◽  
pp. 979-983
Author(s):  
Ping Rui Meng ◽  
Liang Bo Li

Sodium acrylate (NaAA) and acrylamide (AM) were grafted onto poly (vinyl alcohol) (PVA) using potassium persulfate as an initiator, Graft copolymerization namely poly (vinyl alcohol)-g-poly (acrylamide/sodium acrylate) (PVA-g-PAM/SAC). The poly (vinyl alcohol)-g-poly (vinylamine/sodium acrylate) (PVAMC) was prepraed by Hofmann rearrangement.The PVAMC homogeneous membrane was characterized by fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM).The water resistance of the PVAMC membranes is the best when pH of the PVAMC solutions was 4, at that time the numbers of-NH3+ and-COO- groups trended to be equal, so the isoelectric point was pH=4. At 90 °C the pervaporation of PVAMC composite membrane was tested and showed that the separation factor and the permeate flux were about 1001 and 1341 g/(m2·h) for 90wt% ethanol aqueous solution, and they were about 1297 and 1040 g/(m2·h) for 90wt% isopropanol aqueous solution.


1982 ◽  
Vol 27 (12) ◽  
pp. 4787-4797 ◽  
Author(s):  
Nikolaos A. Peppas ◽  
Paula J. Hansen

2009 ◽  
Vol 4 (5-6) ◽  
pp. 331-339 ◽  
Author(s):  
A. N. Ozerin ◽  
N. S. Perov ◽  
A. N. Zelenetskii ◽  
T. A. Akopova ◽  
L. A. Ozerina ◽  
...  

1996 ◽  
Vol 105 (10) ◽  
pp. 4350-4357 ◽  
Author(s):  
Mitsuhiro Shibayama ◽  
Masao Uesaka ◽  
Yasuhiro Shiwa

2010 ◽  
Vol 58 (7) ◽  
pp. 4470-4476 ◽  
Author(s):  
Magdy M. Senna ◽  
Stephane Salmieri ◽  
Abdel-Wahab El-naggar ◽  
Agnes Safrany ◽  
Monique Lacroix

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