Ethylene polymerization catalysts from supported organotransition metal complexes. II. Chromium alkyls

1990 ◽  
Vol 28 (13) ◽  
pp. 3587-3601 ◽  
Author(s):  
P. D. Smith ◽  
M. P. Mcdaniel
Author(s):  
Qiuyue Zhang ◽  
Wenhong Yang ◽  
Zheng Wang ◽  
Gregory A. Solan ◽  
Tongling Liang ◽  
...  

Access to six examples of α,α’-bis(imino)-2,3:5,6-bis(pentamethylene)pyridine-iron(II) chloride complex, [2,3:5,6-{C4H8C(N(2-R1-4-R3-6-R2C6H2)}2C5HN] (R1 = Me, R2 = R3 = CH(p-FPh)2 Fe1; R1 = Et, R2 = R3 = CH(p-FPh)2 Fe2; R1 = iPr,...


1996 ◽  
Vol 107 (1-3) ◽  
pp. 113-121 ◽  
Author(s):  
Giuseppe Braca ◽  
Glauco Sbrana ◽  
Anna Maria Raspolli-Galletti ◽  
Angelina Altomare ◽  
Guillermo Arribas ◽  
...  

2007 ◽  
Vol 72 (11) ◽  
pp. 1155-1169 ◽  
Author(s):  
Dragoslav Stoiljkovic ◽  
Branka Pilic ◽  
Misa Bulajic ◽  
Nebojsa Djurasovic ◽  
Nikolaj Ostrovski

Despite intensive research over the last 50 years, many questions concerning ethylene polymerization by supported chromium oxide are still unanswered. Hence, the very fundamental issues of this polymerization are discussed in this paper. It is shown that a charge percolation mechanism (CPM) of olefin polymerization by Ziegler-Natta transition metal complexes, recently proposed by us, can give the answers in this case, too.


Polymer ◽  
2019 ◽  
Vol 171 ◽  
pp. 87-95 ◽  
Author(s):  
Chantsalnyam Bariashir ◽  
Zheng Wang ◽  
Gregory A. Solan ◽  
Chuanbing Huang ◽  
Xiang Hao ◽  
...  

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