Spark discharges in liquid heptane in contact with silver nitrate solution: Investigation of the synthesized particles

We report on the green synthesis of silver nanoparticles utilizing theP.purpureumleaf extract. Controlling the surface plasmon absorption of silver nanoparticles was achieved by regulating the amount of extract concentration and the molarity of silver nitrate solution. The surface plasmon absorption peak is found at around 430nm. The surface plasmon absorption peak have shifted to lower wavelength as the amount of extract is increased, while plasmon absorption peak shifts on a higher wavelength as the concentration of silver nitrate is increased before it stabilized at 430nm. This can be explained in terms of the available nucleation sites promoted by the plant extract as well as the available silver ions present in silver nitrate solution.

Download Full-text

The Action of Silver Salts on Solution of Ammonium Persulphate

Proceedings of the Royal Society of Edinburgh ◽

10.1017/s0370164600010373 ◽

1902 ◽

Vol 23 ◽

pp. 163-168 ◽

Cited By ~ 9

Author(s):

Hugh Marshall

Keyword(s):

Silver Nitrate ◽

Ammonium Salt ◽

Potassium Salt ◽

Nitrate Solution ◽

Silver Nitrate Solution ◽

General Description ◽

Potassium Persulphate ◽

Ammonium Persulphate ◽

Silver Salts

Although the action of potassium persulphate on silver nitrate solution was one of the first persulphate reactions observed (vol. xviii. p. 64), I had not until lately paid any special attention to the behaviour of the ammonium salt in this respect. It appears, however, that in the latter case there are additional actions of great interest, not possible with the potassium salt. A general description of these will be given now, but there are still some points deserving of further investigation.

Download Full-text

The New Complexes of Tris(2-Methoxy-5-Bromophenyl)Stibine with Silver Nitrate

Bulletin of the South Ural State University series Chemistry ◽

10.14529/chem210102 ◽

2021 ◽

Vol 13 (1) ◽

pp. 21-30

Author(s):

O.K. Sharutina ◽

Keyword(s):

Diffraction Analysis ◽

Silver Nitrate ◽

Silver Atom ◽

Nitrate Solution ◽

Silver Nitrate Solution ◽

X Ray Diffraction ◽

Space Group ◽

X Ray ◽

Crystallographic Characteristics ◽

Group A

By mixing solutions of tris(2-methoxy-5-bromophenyl)antimony and silver nitrate in a methanol : acetonitrile mixture (1:1 vol.), nitrato-O,O'-(acetonitrile)[tris(2-methoxy-5-bromophenyl)antimony]silver complex with the general formula [(C6H3ОMe-2-Br-5)3SbAg(μ2-NO3)(Ме3CN)]2•2[(C6H3ОMe-2-Br-5)3SbAgNO3(Ме3CN)] (1) has been obtained. An addition of silver nitrate solution in the methanol : acetonitrile mixture to the tris(2-methoxy-5-bromophenyl)antimony dioxane solution has led to the formation of a small amount of dark crystals of the ionic complex [(2-MeО-5-Br-C6H3)3SbAg(H2O)Sb(C6H3Br-5-OMe-2)3]+[(2-MeО-5-Br-C6H3)3SbAg(m-NO3)3 AgSb(C6H3Br-5-OMe-2)3]-×3C4H8O2 (2). Complexes 1 and 2 have been characterized by IR spectroscopy, and their structures have been determined by X-ray diffraction analysis. The IR spectra of complexes 1 and 2 contain the bands characterizing the Sb-O, Sb-C, С≡N-, and NO3-group band vibrations. X-ray diffraction analysis of the complexes has been carried out on an automatic four-circle D8 Quest Bruker diffractometer (МоКα radiation, λ = 0.71073 Å, graphite monochromator) at 293 K. Crystallographic characteristics of 1: triclinic, P-1 space group, a = 9.32(3), b = 17.50(7), c = 17.97(5) Å, a = 97.56(14), β = 92.90(19), g = 99.45(19) grad., V = 2859(16) Å3, Z = 2, rcalc = 2.069 g/cm3, 2: monoclinic, С2/с space group, a = 17.417(14), b = 21.041(15), c = 32.01(2) Å, a = 90, β = 97.79(3), g = 90 grad., V = 11624(15) Å3, Z = 4, rcalc = 2.006 g/cm3. In the monomeric and dimeric molecules of crystal 1, nitrate ligands are chelating and bridging, respectively. In the cation of complex 2, the silver atom is bonded to two antimony ligands, the third coordination site is occupied by a water molecule. In the dimeric anion there are one antimony ligand and three bridging nitrate groups surrounding each silver atom.

Download Full-text

The Synthesis and Stability Study of Silver Nanoparticles Prepared by Using p-Aminobenzoic Acid as Reducing and Stabilizing Agent

Indonesian Journal of Chemistry ◽

10.22146/ijc.29312 ◽

2018 ◽

Vol 18 (3) ◽

pp. 421 ◽

Cited By ~ 2

Author(s):

Dian Susanthy ◽

Sri Juari Santosa ◽

Eko Sri Kunarti

Keyword(s):

Silver Nanoparticles ◽

Reaction Time ◽

Silver Nitrate ◽

Tap Water ◽

Nitrate Solution ◽

Silver Nitrate Solution ◽

Stability Study ◽

Synthesis Process ◽

Aminobenzoic Acid ◽

Stabilizing Agent

A study to examine the performance of p-aminobenzoic acid as both reducing agent for silver nitrate to silver nanoparticles (AgNPs) and stabilizing agent for the formed AgNPs has been done. The synthesis of AgNPs was performed by mixing silver nitrate solution as precursor with p-aminobenzoic acid solution and heating it in a boiling water bath. After the solution turned to yellow, the reaction stopped by cooling it in tap water. The formed AgNPs were analyzed by using UV-Vis spectrophotometry to evaluate their SPR absorption in wavelength range of 400–500 nm. The synthesis process was highly depend on the pH, reaction time, and mole ratios of the reactants. The synthesis only occur in pH 11 and at reaction time 30 min, the particle size of the formed AgNPs was 12 ± 7 nm. Longer reaction time increased the reducing performance of p-aminobenzoic acid in AgNPs synthesis but decreased its stabilizing performance. The increase of silver nitrate amount relative to p-aminobenzoic acid in the synthesis increased the reducing and stabilizing performance of p-aminobenzoic acid and the optimum mole ratio between AgNO3 and p-aminobenzoic acid was 5:100 (AgNO3 to p-aminobenzoic acid).

Download Full-text

Pretreated Lignocellulosic Waste Mediated Biosynthesis of Silver Nanoparticles Under Room Temperature

International Journal of Nanoscience ◽

10.1142/s0219581x16600012 ◽

2016 ◽

Vol 15 (05n06) ◽

pp. 1660001 ◽

Cited By ~ 1

Author(s):

V. P. Manjamadha ◽

Karuppan Muthukumar

Keyword(s):

Silver Nanoparticles ◽

Silver Nitrate ◽

Room Temperature ◽

Nitrate Solution ◽

Silver Ions ◽

Silver Nitrate Solution ◽

Morphological Characterization ◽

Alternative Source ◽

X Ray ◽

Antibacterial Performance

The current work elucidates the utilization of biowaste as a valuable reducing agent for the synthesis of silver nanoparticles. In this study, the wastewater generated during the alkaline pretreatment of lignocellulosic wastes (APLW) was used as a bioreductant to reduce silver nitrate under room temperature. Synthesis of stable silver nanoparticles (AgNPs) was achieved rapidly on addition of APLW into the silver nitrate solution (1[Formula: see text]mM). The morphological characterization of AgNPs was performed using field emission scanning electron microscopy (FESEM). The micrograph clearly depicted the presence of spherical AgNPs. The presence of elemental silver along with biomoilties was determined using energy dispersive X-ray spectroscopy (EDAX) analysis. The X-ray diffraction (XRD) study proved the crystalline form of stable AgNPs. The AgNPs exhibited excellent antibacterial performance against Gram negative organism. The immediate bioreduction of silver ions using APLW was well illustrated in the present study. Thus, APLW serve as an alternative source for reducing agents instead of utilizing valuable medicinal plants for nanoparticles synthesis.

Download Full-text

Mafenide acetate (sulfamylon) and silver sulphadiazine creams for local treatment of burns

Drug and Therapeutics Bulletin ◽

10.1136/dtb.9.10.39 ◽

1971 ◽

Vol 9 (10) ◽

pp. 39-40

Keyword(s):

Silver Nitrate ◽

Antimicrobial Prophylaxis ◽

Nitrate Solution ◽

Local Treatment ◽

Silver Nitrate Solution ◽

Gram Negative ◽

Long Run ◽

Resistant Strains ◽

Prophylactic Use ◽

Silver Sulphadiazine

Infection, especially with Pseudomonas aeruginosa and some other Gram-negative bacilli, is a major cause of death in severely burned patients. In attempts to combat such infection classical asepsis and systemic chemotherapy have been less successful than local chemoprophylaxis. Creams containing polymyxin, neomycin and some other antibiotics help, but compresses of 0.5% silver nitrate solution,1 2 and gentamicin cream3 4 appear to be better. Unfortunately silver nitrate gives little or no protection against Klebsiella and some other Gram-negative bacilli and is relatively ineffective against established infection: prophylactic use of gentamicin is likely in the long run to select out resistant strains of Ps. aeruginosa, and is therefore better reserved for the treatment of systemic pseudomonas sepsis. Two newer agents for local antimicrobial prophylaxis and treatment are mafenide acetate cream5 and silver sulphadiazine cream which is not yet marketed.6

Download Full-text