The influence of neutral salts on acid-salt equilibria: III. The second dissociation constant of carbonic acid and the influence of salts on the activity of the hydrogen ions in a bicarbonate-carbonate mixture

2010 ◽  
Vol 47 (10) ◽  
pp. 819-825 ◽  
Author(s):  
I. M. Kolthoff ◽  
Wouter Bosch
Keyword(s):  
Dissociation Constant ◽  
Carbonic Acid ◽  
Hydrogen Ions ◽  
Acid Salt ◽  
Second Dissociation Constant

The second dissociation constant of carbonic acid in ethanol–water mixture from 5°C to 45°C

1999 ◽  
Vol 332 (1) ◽  
pp. 83-88 ◽  
Author(s):  
Jia-Zhen Yang ◽  
Dian-Zhen Lu ◽  
Chao-Jun Hou ◽  
Jie Wang
Keyword(s):  
Dissociation Constant ◽  
Carbonic Acid ◽  
Water Mixture ◽  
Second Dissociation Constant

Second dissociation constant of 3-(N-morpholino)-2-hydroxypropanesulfonic acid and pH of its buffer solutions

1993 ◽  
Vol 65 (8) ◽  
pp. 1084-1087 ◽  
Author(s):  
Y. C. Wu ◽  
P. A. Berezansky ◽  
Daming. Feng ◽  
W. F. Koch
Keyword(s):  
Dissociation Constant ◽  
Buffer Solutions ◽  
Second Dissociation Constant

The Physiology of Carbon Dioxide Transport in Insect Blood

1950 ◽  
Vol 27 (2) ◽  
pp. 158-174 ◽  
Author(s):  
L. LEVENBOOK
Keyword(s):  
Carbon Dioxide ◽  
Dissociation Constant ◽  
Temperature Coefficient ◽  
Carbonic Acid ◽  
Apparent Dissociation Constant ◽  
Carbon Dioxide Transport ◽  
High Co2 ◽  
The Third ◽  
A Value ◽  
Dissociation Curves

1. The pH of the blood of the third instar Gastrophilus larva is 6.64 at 38° C. with a pH-temperature coefficient of -0.007 Per 1° C. rise in temperature. 2. The total CO2 content of the blood varies from 40.6 to 131.4 vol. % with an average of 72.4 vol. %. The CO2 content of the tissues minus the cuticle is very close to, and follows the variations in, the CO2 content of the blood. 3. The CO2 tension in the blood is from 300 to 500 mm. Hg. From 30 to 50% of the CO2 is in solution, the rest in the form of bicarbonate. Carbamate formation does not occur in the blood. 4. The ‘apparent’ dissociation constant for carbonic acid, (pK'1), has a value of 6.08 (S.D. ±0.06) at 38° C. and 6.19 (s.d. ±0.13) at 16° C. 5. CO2 dissociation curves have been drawn for 38 and 16° C. The slope of the curves indicates that the whole of the CO2 is given off at zero CO2 tension, and that the blood is adapted for functioning at high CO2 tensions.

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