Characterization by Temperature-Programmed Reduction and by Temperature-Programmed Oxidation (TPR-TPO) of Chromium(III) Oxide-Based Catalysts: Correlation with the Catalytic Activity for Hydrofluoroalkane Synthesis

1995 ◽  
Vol 152 (1) ◽  
pp. 70-74 ◽  
Author(s):  
S. Brunet ◽  
B. Requieme ◽  
E. Matouba ◽  
J. Barrault ◽  
M. Blanchard
Keyword(s):  
Catalytic Activity ◽  
Temperature Programmed Reduction ◽  
Temperature Programmed Oxidation ◽  
Temperature Programmed

Oxygen Radicals Occlusion/Release Behavior of Nanoporous Aluminosilicate, Ca12Al14-XSiXO33+0.5X (0≦X≦4)

2006 ◽  
Vol 45 ◽  
pp. 2105-2109
Author(s):  
Makoto Nagashima ◽  
Daisuke Hirabayashi ◽  
Kenzi Suzuki
Keyword(s):  
Catalytic Activity ◽  
Oxygen Content ◽  
Oxygen Radicals ◽  
Catalytic Performance ◽  
Oxygen Release ◽  
Release Behavior ◽  
Temperature Programmed Reduction ◽  
Temperature Programmed Oxidation ◽  
Temperature Range ◽  
Temperature Programmed

Oxygen radicals occlusion / release behavior of nanoporous aluminosilicate, Ca12Al14-XSiXO33+0.5X (0≦X≦4), synthesized under different condition was examined by the temperature programmed reduction (TPR) in an atmosphere of hydrogen in the temperature range of 200-1000°C and temperature programmed oxidation (TPO) measurement at 800°C. From the TPR results of Ca12Al14O33 (X=0) and Ca12Al10Si4O35 (X=4), it was found that there were three oxygen release peaks, denoted as α, β and γ, on each sample and the peaks appeared in the temperature range 300-420°C, 420-600°C, and 600-750°C, respectively. The oxygen contents of α and γ of samples were almost the same. However, the oxygen content of β in the sample with x = 4 was much larger, almost double, compared to that in x = 0. From the TPR, TPO results and catalytic performance, it was concluded that the oxygen content of β peak strongly influenced the catalytic activity of the nanoporous aluminosilicate in the propylene combustion.

scholarly journals Precipitated K-Promoted Co–Mn–Al Mixed Oxides for Direct NO Decomposition: Preparation and Properties

Catalysts ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 592 ◽  
Author(s):  
Květa Jirátová ◽  
Kateřina Pacultová ◽  
Jana Balabánová ◽  
Kateřina Karásková ◽  
Anna Klegová ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Mixed Oxides ◽  
No Decomposition ◽  
Temperature Programmed Reduction ◽  
X Ray ◽  
Co2 Desorption ◽  
Metal Nitrates ◽  
Temperature Programmed ◽  
Desorption Method ◽  
Al Oxide

Direct decomposition of nitric oxide (NO) proceeds over Co–Mn–Al mixed oxides promoted by potassium. In this study, answers to the following questions have been searched: Do the properties of the K-promoted Co–Mn–Al catalysts prepared by different methods differ from each other? The K-precipitated Co–Mn–Al oxide catalysts were prepared by the precipitation of metal nitrates with a solution of K2CO3/KOH, followed by the washing of the precipitate to different degrees of residual K amounts, and by cthe alcination of the precursors at 500 °C. The properties of the prepared catalysts were compared with those of the best catalyst prepared by the K-impregnation of a wet cake of Co–Mn–Al oxide precursors. The solids were characterized by chemical analysis, DTG, XRD, N2 physisorption, FTIR, temperature programmed reduction (H2-TPR), temperature programmed CO2 desorption (CO2-TPD), X-ray photoelectron spectrometry (XPS), and the species-resolved thermal alkali desorption method (SR-TAD). The washing of the K-precipitated cake resulted in decreasing the K amount in the solid, which affected the basicity, reducibility, and non-linearly catalytic activity in NO decomposition. The highest activity was found at ca 8 wt.% of K, while that of the best K-impregnated wet cake catalyst was at about 2 wt.% of K. The optimization of the cake washing conditions led to a higher catalytic activity.

Effect of Ni Reducibility on Anisole Hydrodeoxygenation Activity in the La-Ni/γ-Al2O3 Catalytic System

2019 ◽  
Vol 18 (2) ◽  
Author(s):  
Brett Pomeroy ◽  
Teri Doxtator ◽  
Jose E. Herrera ◽  
Dominic Pjontek
Keyword(s):  
Catalytic Activity ◽  
Catalytic System ◽  
Catalyst Surface ◽  
Reaction Pathway ◽  
Catalyst Characterization ◽  
Temperature Programmed Reduction ◽  
Visible Spectroscopy ◽  
Uv Visible ◽  
Temperature Programmed

Abstract The effect of lanthanum addition on the activity of a series of Ni/γ-Al2O3 catalysts for anisole hydrodeoxygenation (HDO) was evaluated. Catalyst characterization using hydrogen temperature-programmed reduction (H2-TPR) and UV-visible spectroscopy suggests that lanthanum incorporation results in the formation of larger metallic Ni domains in the catalyst surface, which in turn favour the direct anisole hydrogenation pathway to methoxycyclohexane. Despite the improvements to reducibility that resulted from the incorporation of La, the catalysts displayed lower selectivity towards cyclohexane, independent of total nickel loading. The catalytic activity results were rationalized in terms of a proposed reaction pathway where anisole is initially hydrogenated followed by sequential deoxygenation steps.

ChemInform Abstract: Temperature-programmed Reduction and Catalytic Activity of Ni/Al2O3.

ChemInform ◽  
1987 ◽  
Vol 18 (38) ◽  
Author(s):  
HOANG DANG LANH HOANG DANG LANH ◽  
HO SI THOANG HO SI THOANG ◽  
NGUYEN KHOAI NGUYEN KHOAI ◽  
J. VOELTER
Keyword(s):  
Catalytic Activity ◽  
Temperature Programmed Reduction ◽  
Temperature Programmed

scholarly journals Novel Nickel- and Magnesium-Modified Cenospheres as Catalysts for Dry Reforming of Methane at Moderate Temperatures

Catalysts ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1066 ◽  
Author(s):  
Bogdan Samojeden ◽  
Marta Kamienowska ◽  
Armando Izquierdo Colorado ◽  
Maria Elena Galvez ◽  
Ilona Kolebuk ◽  
...  
Keyword(s):  
Supported Catalysts ◽  
Temperature Programmed Desorption ◽  
Catalytic Performance ◽  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Temperature Programmed Reduction ◽  
Fly Ashes ◽  
Coal Fly Ashes ◽  
Temperature Programmed ◽  
Mg Content

Cenospheres from coal fly ashes were used as support in the preparation of Ni–Mg catalysts for dry reforming of methane. These materials were characterized by means of XRD, H2-temperature-programmed reduction (H2-TPR), CO2-temperature-programmed desorption (CO2-TPD), and low-temperature nitrogen sorption techniques. The cenosphere-supported catalysts showed relatively high activity and good stability in the dry reforming of methane (DRM) at 700 °C. The catalytic performance of modified cenospheres was found to depend on both Ni and Mg content. The highest activity at 750 °C and 1 atm was observed for the catalyst containing 30 wt % Mg and 10, 20, and 30 wt % Ni, yielding to CO2 and CH4 conversions of around 95%.

scholarly journals Role of CO2 During Oxidative Dehydrogenation of Propane Over Bulk and Activated-Carbon Supported Cerium and Vanadium Based Catalysts

2021 ◽  
Author(s):  
Petar Djinović ◽  
Janez Zavašnik ◽  
Janvit Teržan ◽  
Ivan Jerman
Keyword(s):  
Catalytic Activity ◽  
Activated Carbon ◽  
Oxidative Dehydrogenation ◽  
Active Phase ◽  
Lattice Oxygen ◽  
Chemisorbed Oxygen ◽  
Catalytically Active ◽  
Temperature Programmed ◽  
Propane Cracking

AbstractCeO2, V2O5 and CeVO4 were synthesised as bulk oxides, or deposited over activated carbon, characterized by XRD, HRTEM, CO2-TPO, C3H8-TPR, DRIFTS and Raman techniques and tested in propane oxidative dehydrogenation using CO2. Complete oxidation of propane to CO and CO2 is favoured by lattice oxygen of CeO2. The temperature programmed experiments show the ~ 4 nm AC supported CeO2 crystallites become more susceptible to reduction by propane, but less prone to re-oxidation with CO2 compared to bulk CeO2. Catalytic activity of CeVO4/AC catalysts requires a 1–2 nm amorphous CeVO4 layer. During reaction, the amorphous CeVO4 layer crystallises and several atomic layers of carbon cover the CeVO4 surface, resulting in deactivation. During reaction, V2O5 is irreversibly reduced to V2O3. The lattice oxygen in bulk V2O5 favours catalytic activity and propene selectivity. Bulk V2O3 promotes only propane cracking with no propene selectivity. In VOx/AC materials, vanadium carbide is the catalytically active phase. Propane dehydrogenation over VC proceeds via chemisorbed oxygen species originating from the dissociated CO2. Graphic Abstract

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