A Study of Thin Liquid Films as Related to the Stability of Crude Oil Emulsions

2001 ◽  
Vol 238 (1) ◽  
pp. 177-182 ◽  
Author(s):  
Hongbo Fang ◽  
Lu Zhang ◽  
Lan Luo ◽  
Sui Zhao ◽  
Jingyi An ◽  
...  
2017 ◽  
Vol 744 ◽  
pp. 346-349
Author(s):  
Xiu Juan Li ◽  
Rui Song Guo ◽  
Min Zhao

The structure of the thin liquid films determines the stability of foams and emulsions. In this work the bubbles stretched length with different hollow SiO2 particles concentration is measured when the foam has been stilled for different time. The results show that the bubbles stretched length is longer than that of bubbles when the foam is free of hollow SiO2 particles even when the foam has been stilled for 500mins. The bubbles stretched length increases with increasing the concentration of hollow SiO2 particles. A strong hydration effect leaves a large volume of hydration layers on the solid particles surfaces in aqueous solutions. The water in hydration layers can help the film keep a certain thickness. The existence of hydration forces leads that two particles cannot be too close each other. The high concentration surfactant limited in the fixed area helps the film keep good elasticity. Therefore the film has a long life time with compatible thickness and elasticity and the three-phrase foam is upper stable.


2011 ◽  
Vol 382 (1-3) ◽  
pp. 174-180 ◽  
Author(s):  
Theodor D. Gurkov ◽  
Jana K. Angarska ◽  
Krassimir D. Tachev ◽  
Wolfgang Gaschler

2008 ◽  
Vol 5 (2) ◽  
pp. 159-162 ◽  
Author(s):  
Meiqin Lin ◽  
Chunling Zhang ◽  
Hua Zong ◽  
Mingyuan Li ◽  
Hongbo Fang ◽  
...  

2018 ◽  
Vol 2 (2) ◽  
Author(s):  
Stoyan I. Karakashev

This review article reports on the effect of the counter-ions on the ionic surfactant adsorption layer and its relation to the stability of foams and emulsions. The adsorption theory of Davies about the ionic surfactant monolayer was revisited and it is shown how to account for the type of the counter-ions. The experimental validation of this theory on thin liquid films was shown as well, thus explaining the effect of Hofmeister. However their effect on foams and emulsions is more complex. Furthermore, it is shown how the counter-ions affect in complex way the stability of foams and emulsions via the surfactant adsorption layer in the light of the newest theory. To elucidate the nature of this effect further investigation is called for. 


1998 ◽  
Vol 198 (2) ◽  
pp. 224-240 ◽  
Author(s):  
Theodor Gurkov ◽  
Krassimir Danov ◽  
Norbert Alleborn ◽  
Hans Raszillier ◽  
Franz Durst

REAKTOR ◽  
2017 ◽  
Vol 6 (1) ◽  
pp. 29
Author(s):  
B. Pramudono ◽  
H. B. Mat

The stability of water-in-oil emulsion of some Malaysian crude oils was studied with particular emphasis on effect of interfacial active components existed in the crude oil, i.e. asphaltene, resin and wax. The emulsion stability was studied by measuring the volume of water or oil phase separated in variation with time, water hold up, and the heights of the sedimenting/coalescing interfaces during the separation at various temperatures. The study investigated the influence of asphaltene, resin and wax on emultion stability if it`s present in the crude oil alone, together or combination one of the others. The result show that the interfacial active component that stabilize emulsion is asphaltene. The resin and wax  do not form stale emulsion either aloneor together. There is a correlation between emulsion stability and physicochemical properties of crude oil which showed that higher asphaltene content in the crude oil would form more stable emultion. Increased temperature was found to cause instability of emultion. Keywords : emultion stability, crude oil, asphaltene, resin and wax


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