Complete Relaxation and Conformational Exchange Matrix (CORCEMA) Analysis of NOESY Spectra of Interacting Systems; Two-Dimensional Transferred NOESY

1995 ◽  
Vol 108 (3) ◽  
pp. 243-261 ◽  
Author(s):  
H.N.B. Moseley ◽  
E.V. Curto ◽  
N.R. Krishna
1996 ◽  
Vol 61 (3) ◽  
pp. 389-403 ◽  
Author(s):  
Luboš Arnold ◽  
Martina Pressová ◽  
David Šaman ◽  
Martin Vogtherr ◽  
Stefan Limmer

1'-C Deuterated H-phosphonate synthons were prepared via a 12-step procedure starting from [1'-2H]ribose. The procedure included nucleosidation of 1'-O-acetyl-2',3',5'-O-tribenzoyl[1'-2H]ribose with appropriately protected nucleobases and preparation of nucleoside-H-phosphonates by slightly modified described procedures. The automated RNA synthesis of 5'-G*C*U*A*U*UUAU-3' and 3'-AC*G*A*U*A*AAGU-5' was performed on a Gene Assembler Plus DNA-synthesizer. These specifically deuterated oligoribonucleotides were subsequently compared with the corresponding non-deuterated sequences using 2D-NMR NOESY spectra. Specific deuterium incorporation resulted in the expected simplification of spectral pattern.


Science ◽  
2019 ◽  
Vol 364 (6447) ◽  
pp. 1267-1271 ◽  
Author(s):  
Shaun P. Johnstone ◽  
Andrew J. Groszek ◽  
Philip T. Starkey ◽  
Christopher J. Billington ◽  
Tapio P. Simula ◽  
...  

Nonequilibrium interacting systems can evolve to exhibit large-scale structure and order. In two-dimensional turbulent flow, the seemingly random swirling motion of a fluid can evolve toward persistent large-scale vortices. To explain such behavior, Lars Onsager proposed a statistical hydrodynamic model based on quantized vortices. Here, we report on the experimental confirmation of Onsager’s model. We dragged a grid barrier through an oblate superfluid Bose–Einstein condensate to generate nonequilibrium distributions of vortices. We observed signatures of an inverse energy cascade driven by the evaporative heating of vortices, leading to steady-state configurations characterized by negative absolute temperatures. Our results open a pathway for quantitative studies of emergent structures in interacting quantum systems driven far from equilibrium.


1991 ◽  
Vol 24 (26) ◽  
pp. 6874-6876 ◽  
Author(s):  
K. Zemke ◽  
B. F. Chmelka ◽  
K. Schmidt-Rohr ◽  
H. W. Spiess

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