Experimental and Theoretical Study of Metal-Hydride Reactors

2006 ◽  
pp. 211-222
Author(s):  
Y. Kaplan ◽  
M. Demiralp ◽  
T. N. Veziroglu
Keyword(s):  
Metal Hydride ◽  
Theoretical Study

Metal−Hydride Bond Activation and Metal−Metal Interaction in Dinuclear Iron Complexes with Linking Dinitriles:  A Synthetic, Electrochemical, and Theoretical Study

2002 ◽  
Vol 41 (24) ◽  
pp. 6456-6467 ◽  
Author(s):  
Ana I. F. Venâncio ◽  
Maxim L. Kuznetsov ◽  
M. Fátima C. Guedes da Silva ◽  
Luísa M. D. R. S. Martins ◽  
João J. R. Fraústo da Silva ◽  
...  
Keyword(s):  
Metal Hydride ◽  
Bond Activation ◽  
Theoretical Study ◽  
Iron Complexes ◽  
Metal Interaction ◽  
Dinuclear Iron ◽  
Metal Metal

Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study

2017 ◽  
Vol 4 (11) ◽  
pp. 1813-1820 ◽  
Author(s):  
Dongdong Xu ◽  
Chunhui Shan ◽  
Yingzi Li ◽  
Xiaotian Qi ◽  
Xiaoling Luo ◽  
...  
Keyword(s):  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Metal Hydride ◽  
Bond Energy ◽  
Alkaline Earth ◽  
Theoretical Study ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Bond Dissociation

Alkaline-earth-metal could catalyse the dehydrocoupling procedure of N–H and B–H bond due to the low Ae–H bond energy. The direct σ-bond metathesis procedure is proved to be unfavourable.

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