Sustainability of active bulk plasma with high electronegativity incapacitive high frequency plasma

In a high-frequency capacitively coupled plasma (HF-CCP), few studies have been carried out for the transport of charged particles in the active bulk plasma with high electronegativity. The electric field E(t), specifically, time-varying reduced field E(t)/Ng provides key knowledge about the characteristics of collisional bulk plasma. Numerical modeling is the only method for estimating E(t)/Ng, while a limited number of collision cross sections and related transport parameters are available. Under these circumstances, we discuss how to estimate the reduced field E(t)/Ng, i.e., E(t) in active bulk plasma with high electronegativity in HF-CCP through investigation of the correlation between the DC-critical reduced field (E/Ng)Crit: and the HF-effective reduced field (E(t)/Ng)eff . Our previous discussion on the correlation is validated by increasing the number of results of (E(t)/Ng)eff . The relation between the electronegativity and the ionization degree is derived from the sustainable condition in the bulk plasma.

Effects of Electronegativity and Hydration Energy on the Selective Adsorption of Heavy Metal Ions by Synthetic NaX Zeolite

The adsorption capacity of synthetic NaX zeolite for Pb2+, Cd2+, Cu2+ and Zn2+ in single and multi-component systems were investigated. The effects of electronegativity and hydration energy on the selective adsorption, as well as potential selective adsorption mechanism of the NaX zeolite for Pb2+, Cd2+, Cu2+ and Zn2+ were also discussed. The maximum adsorption capacity order of the heavy metals in the single system was Pb2+ > Cd2+ > Cu2+ > Zn2+, and this could be related to their hydration energy and electronegativity. The values of the separation factors (α) and affinity constant (KEL) in different binary systems indicated that Pb2+ was preferentially adsorbed, and Zn2+ presented the lowest affinity for NaX zeolite. The selective adsorption capacities of the metals were in the order, Pb2+ > Cd2+ ≈ Cu2+ > Zn2+. The trend for the selective adsorption of NaX zeolite in ternary and quaternary systems was consistent with that in the binary systems. Pb2+ and Cu2+ reduced the stability of the Si-O-Al bonds and the double six-membered rings in the NaX framework, due to the high electronegativity of Pb2+ and Cu2+ than that of Al3+. The selective adsorption mechanism of NaX zeolite for the high electronegative metal ions could mainly result from the negatively charged O in the Si-O-Al structure of the NaX zeolite, hence heavy metal ions with high electronegativity display a strong affinity for the electron cloud of the oxygen atoms in the Si-O-Al. This study could evaluate the application and efficiency of zeolite in separating and recovering certain metal ions from industrial wastewater.

Exploring the binding mechanism of positive allosteric modulators in human metabotropic glutamate receptor 2 using molecular dynamics simulations

Based on the binding mode and electrostatics, the features of high affinity PAMs were the reduced hydrophobicity with low electronegativity of R1, increased hydrophobicity with low electronegativity of R2 and with high electronegativity of linker.

High-performance PDMS‐based triboelectric nanogenerator fabricated using surface-modified carbon nanotubes via pulsed laser ablation

Poly-(dimethylsiloxane) (PDMS) has been used as a negative friction layer in triboelectric nanogenerator (TENG) owing to its high electronegativity and flexibility. With advantage of the PDMS, various materials design to...

Determination of solute-solute and solute-solvent interaction of pyrimidine5-carbonitrile in aqueous DMSO at 298.15 K.

Introduction: In this reported work, we have used 80 % aqueous dimethyl sulphoxide (DMSO) for density and viscosity measurement of pyrimidine-5-carbonitrile at 298.15 K. The obtained experimental results shows that as concentration increases density and viscosity increases. From the results of density and viscosity, we have found apparent molar volume, limiting apparent molar volume, semi-empirical parameters, Falkenhagen coefficients and Jones Dole coefficients. Method: The apparent molar volume and limiting apparent molar volume having negative values indicated electostrictive solvation of ions and weak or absence of ion solvent interactions respectively. Result & Discussion : Falkenhagen coefficients is independent of concentration having positive value has shown strong solute-solute interactions and Jones-Dole coefficients having negative value has shown weak solute-solvent interactions. The strong solute-solute interactions were presents in A-1 as compared to A-2 compound because high electronegativity of oxygen atom. These parameters had given idea about molecular interactions such as solute-solute, solute-solvent and solvent-solvent. Conclusion: We have reported density and viscosity study of 4-amino-2-hydroxy-6-phenylpyrimidine-5-carbonitrile and 4- amino-2-mercapto-6-phenylpyrimidine-5-carbonitrile in 80 % aqueous DMSO solution at 298.15 K temperature. It has been observed that Strong molecular association in A-2 as compared to A-1 due to negative values of Øv.

STUDY OF PHASES IN CRYSTALLINE SENTENCES

The objective of the study was to study the phases in the crystalline sentence of calcium molybdate with sodium metafanadat on the basis of phase equilibrium in binary sentence. For this sutyd, different mixtures are prepared based on different molar ratios and investigation is made about these different mixture physical properties. Finally, the study also draw a phase balanced chart for the studied substances. For methodology adopted, nine samples were prepared. The results shows that to form a solid solution as dissolving sodium metafandate in calcium molybdate up to 40% of sodium metafanadate and form a solid solution in this sentence confirms that the necessary conditions to form a soid solution. It is concluded that for difference less than 15%, unlimited solid solution is formed; whereas, for difference above 15%, limited solid solution is formed. Our conclusion also shows that these two elements solubility is limited where one possesses the characteristic of high electronegativity, while, the other possess the characteristic of low electro negativity.

Improvement of Bromide Ion Conduction in Lanthanum Oxybromide Based Solids by Doping Divalent Zinc Ion with High Electronegativity

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