2016 ◽  
Vol 14 (5) ◽  
pp. 1680-1693 ◽  
Author(s):  
Akinari Sumita ◽  
Yuko Otani ◽  
Tomohiko Ohwada

The unmasking reaction rates and the time of generation of highly reactive electrophiles can be controlled. This reaction system demonstrates the conceptual validity of one-pot build-up of a complex aromatic molecule from multiple starting components.


1986 ◽  
Vol 34 (6) ◽  
pp. 3988-3991 ◽  
Author(s):  
M. N. Piancastelli ◽  
M. K. Kelly ◽  
G. Margaritondo ◽  
D. J. Frankel ◽  
G. J. Lapeyre

2016 ◽  
Vol 16 (6) ◽  
pp. 3465-3472 ◽  
Author(s):  
Lilian M. Hayes ◽  
Caroline E. Knapp ◽  
Karina Y. Nathoo ◽  
Neil J. Press ◽  
Derek A. Tocher ◽  
...  

1991 ◽  
Vol 95 (5) ◽  
pp. 3147-3166 ◽  
Author(s):  
Eli Shalev ◽  
Narda Ben‐Horin ◽  
Uzi Even ◽  
Joshua Jortner

The first study of an aromatic molecule by neutron diffraction, leading to a Fourier projection of the neutron scattering density in the unit cell, gives a value of 1·08 ± 0·04 Å for the length of the C—H bonds which link hydrogen atoms to the benzene ring. The spirals of hydrogen bonds which bind together neighbouring molecules are found to consist of typical ‘long bonds’, with the proton much closer to one oxygen atom than to the other. The O—H distance is 1·02 Å, and it appears that the O, H, O atoms are not collinear.


2015 ◽  
Vol 17 (47) ◽  
pp. 32000-32008 ◽  
Author(s):  
Dorian S. N. Parker ◽  
Ralf I. Kaiser ◽  
Oleg Kostko ◽  
Tyler P. Troy ◽  
Musahid Ahmed ◽  
...  

The nitrogen bearing aromatic molecule pyridine (C5H5N) is revealed to form in high temperature environments simulating conditions in carbon-rich circumstellar envelopes via the reaction of the cyano vinyl radical with vinyl cyanide.


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