Kinetics of High Pressure Phase Transitions in the Diamond Anvil Cell

Author(s):  
Bernd Lorenz ◽  
Ingo Orgzall
1999 ◽  
Vol 11 (34) ◽  
pp. 6515-6520 ◽  
Author(s):  
Jagannadham Akella ◽  
Samuel T Weir ◽  
Yogesh K Vohra ◽  
Heather Prokop ◽  
Shane A Catledge ◽  
...  

2007 ◽  
Vol 102 (10) ◽  
pp. 106104 ◽  
Author(s):  
N. Nissim ◽  
S. Eliezer ◽  
L. Bakshi ◽  
L. Perelmutter ◽  
D. Moreno ◽  
...  

2019 ◽  
Vol 116 (39) ◽  
pp. 19324-19329 ◽  
Author(s):  
Rajkrishna Dutta ◽  
Eran Greenberg ◽  
Vitali B. Prakapenka ◽  
Thomas S. Duffy

Neighborite, NaMgF3, is used as a model system for understanding phase transitions in ABX3 systems (e.g., MgSiO3) at high pressures. Here we report diamond anvil cell experiments that identify the following phases in NaMgF3 with compression to 162 GPa: NaMgF3 (perovskite) → NaMgF3 (post-perovskite) → NaMgF3 (Sb2S3-type) → NaF (B2-type) + NaMg2F5 (P21/c) → NaF (B2) + MgF2 (cotunnite-type). Our results demonstrate the existence of an Sb2S3-type post-post-perovskite ABX3 phase. We also experimentally demonstrate the formation of the P21/c AB2X5 phase which has been proposed theoretically to be a common high-pressure phase in ABX3 systems. Our study provides an experimental observation of the full sequence of phase transitions from perovskite to post-perovskite to post-post-perovskite followed by 2-stage breakdown to binary compounds. Notably, a similar sequence of transitions is predicted to occur in MgSiO3 at ultrahigh pressures, where it has implications for the mineralogy and dynamics in the deep interior of large, rocky extrasolar planets.


2001 ◽  
Vol 62 (5) ◽  
pp. 941-949 ◽  
Author(s):  
H. Hirano ◽  
S. Uehara ◽  
A. Mori ◽  
A. Onodera ◽  
K. Takemura ◽  
...  

1986 ◽  
Vol 33 (6) ◽  
pp. 4221-4226 ◽  
Author(s):  
Samuel T. Weir ◽  
Yogesh K. Vohra ◽  
Arthur L. Ruoff

2022 ◽  
pp. 122904
Author(s):  
Zhenghao Zhao ◽  
Hiroyuki Kagi ◽  
Kazuki Komatsu ◽  
Keishiro Yamashita ◽  
Satoshi Nakano

2019 ◽  
Vol 48 (1) ◽  
pp. 242-252 ◽  
Author(s):  
Maciej Ptak ◽  
Bartosz Zarychta ◽  
Dagmara Stefańska ◽  
Aneta Ciupa ◽  
Waldeci Paraguassu

We report the synthesis, high-pressure phase transitions and optical properties of novel bimetallic perovskite-type MOFs with imidazolium ions.


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