Effect of a Constant Drift in the Reptation Dynamics of Entangled Polymers

2019 ◽  
pp. 159-162
Author(s):  
Andrés R. Tejedor ◽  
Jorge Ramírez
Keyword(s):  
Entangled Polymers

Flow-Induced Orientation and Stretching of Entangled Polymers in the Framework of Nonequilibrium Thermodynamics

2016 ◽  
Vol 49 (8) ◽  
pp. 3161-3173 ◽  
Author(s):  
Pavlos S. Stephanou ◽  
Ioanna Ch. Tsimouri ◽  
Vlasis G. Mavrantzas
Keyword(s):  
Nonequilibrium Thermodynamics ◽  
Entangled Polymers

Rational Design of Novel Materials From Polymer Microrheology

2010 ◽  
Author(s):  
Rodrigo E. Teixeira ◽  
Richard S. Graham
Keyword(s):  
Rational Design ◽  
Molecular Level ◽  
Pressure Vessels ◽  
Novel Materials ◽  
Entangled Polymers ◽  
Stochastic Fluctuations ◽  
Safety Margins ◽  
Polymer Liquids ◽  
Entangled Polymer ◽  
High Degree

The visco-elastic properties of entangled polymer liquids arise from molecular-scale topological interactions and stochastic fluctuations under flow. Here, the evolutions of individual entangled polymers were observed in rheologically relevant shear flow histories. We uncover a high degree of molecular individualism and broad conformational distributions resulting from incessant stretch-collapse cycles. The data and insights of the present study may lead to improved molecular-level models and constitutive equations. These tools, in turn, may enable the rational design of novel materials with properties tailored to accomplish specific tasks such as high-pressure vessels and piping with greater safety margins and cost-effectiveness.

scholarly journals FIELD THEORY OF N ENTANGLED POLYMERS

2000 ◽  
Vol 14 (32) ◽  
pp. 3881-3895 ◽  
Author(s):  
FRANCO FERRARI ◽  
HAGEN KLEINERT ◽  
IGNAZIO LAZZIZZERA
Keyword(s):  
Field Theory ◽  
Canonical Ensemble ◽  
Feynman Diagrams ◽  
Linking Number ◽  
Entangled Polymers

We formulate a field theory capable of describing a canonical ensemble of N polymers subjected to linking number constraints in terms of Feynman diagrams.

Self-oscillations in capillary flow of entangled polymers

1999 ◽  
Vol 43 (2) ◽  
pp. 453-460 ◽  
Author(s):  
Shi-Qing Wang ◽  
N. Plucktaveesak
Keyword(s):  
Capillary Flow ◽  
Entangled Polymers

scholarly journals Effect of Chain Length Dispersity on the Mobility of Entangled Polymers

2018 ◽  
Vol 121 (5) ◽  
Author(s):  
Brandon L. Peters ◽  
K. Michael Salerno ◽  
Ting Ge ◽  
Dvora Perahia ◽  
Gary S. Grest
Keyword(s):  
Chain Length ◽  
Entangled Polymers

scholarly journals Contraction of Entangled Polymers After Large Step Shear Deformations in Slip-Link Simulations

Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 370 ◽  
Author(s):  
Yuichi Masubuchi
Keyword(s):  
Dynamics Simulation ◽  
Uniaxial Deformation ◽  
Single Chain ◽  
Orientational Relaxation ◽  
Entangled Polymers ◽  
Constraint Release ◽  
Large Step ◽  
Entangled Polymer ◽  
Convective Constraint Release ◽  
Chain Contraction

Although the tube framework has achieved remarkable success to describe entangled polymer dynamics, the chain motion assumed in tube theories is still a matter of discussion. Recently, Xu et al. [ACS Macro Lett. 2018, 7, 190–195] performed a molecular dynamics simulation for entangled bead-spring chains under a step uniaxial deformation and reported that the relaxation of gyration radii cannot be reproduced by the elaborated single-chain tube model called GLaMM. On the basis of this result, they criticized the tube framework, in which it is assumed that the chain contraction occurs after the deformation before the orientational relaxation. In the present study, as a test of their argument, two different slip-link simulations developed by Doi and Takimoto and by Masubuchi et al. were performed and compared to the results of Xu et al. In spite of the modeling being based on the tube framework, the slip-link simulations excellently reproduced the bead-spring simulation result. Besides, the chain contraction was observed in the simulations as with the tube picture. The obtained results imply that the bead-spring results are within the scope of the tube framework whereas the failure of the GLaMM model is possibly due to the homogeneous assumption along the chain for the fluctuations induced by convective constraint release.

Sign in / Sign up

Export Citation Format

Share Document