Angle-Resolved NMR: A Theory of the 1/T $$_1$$ Relaxation Rate in Magnetic Systems

2013 ◽  
pp. 49-57
Author(s):  
Andrew Smerald
Keyword(s):  
Relaxation Rate ◽  
Magnetic Systems

Analysis of the backbone dynamics of capsicein using 15N NMR relaxation rate measurements

1994 ◽  
Vol 91 ◽  
pp. 776-784
Author(s):  
C van Heijenoort ◽  
S Bouaziz ◽  
E Guittet
Keyword(s):  
Relaxation Rate ◽  
Nmr Relaxation ◽  
Backbone Dynamics ◽  
15N Nmr ◽  
15N Nmr Relaxation

Hedgehog structure in nematic and magnetic systems

1988 ◽  
Vol 49 (7) ◽  
pp. 1097-1101 ◽  
Author(s):  
N. Schopohl ◽  
T.J. Sluckin
Keyword(s):  
Magnetic Systems

SURFACE MAGNETISM OF NEARLY MAGNETIC SYSTEMS AND RELATED PROPERTIES

1984 ◽  
Vol 45 (C5) ◽  
pp. C5-339-C5-347
Author(s):  
M. T. Beal-Monod
Keyword(s):  
Surface Magnetism ◽  
Magnetic Systems

Dynamical chaos in magnetic systems

1992 ◽  
Vol 162 (7) ◽  
pp. 81 ◽  
Author(s):  
K.N. Alekseev ◽  
G.P. Berman ◽  
V.I. Tsifrinovich ◽  
A.M. Frishman
Keyword(s):  
Dynamical Chaos ◽  
Magnetic Systems

Magnetic resonance image attributes of the bovine ovarian follicle antrum during development and regression

Reproduction ◽  
2000 ◽  
pp. 311-323 ◽  
Author(s):  
JL Hilton ◽  
GE Sarty ◽  
GP Adams ◽  
RA Pierson
Keyword(s):  
Magnetic Resonance ◽  
Relaxation Rate ◽  
Follicular Fluid ◽  
Magnetic Resonance Image ◽  
Follicular Development ◽  
Physiological Status ◽  
Proton Density ◽  
Dominant Follicle ◽  
Rate Heterogeneity ◽  
Pixel Value

The magnetic resonance images and maps of bovine ovaries acquired at defined phases of follicular development and regression were studied to determine whether magnetic resonance image attributes of the follicular antrum reflect the physiological status of dominant and subordinate ovarian follicles. Ovariectomies were performed at day 3 of wave one, day 6 of wave one, day 1 of wave two and at >/= day 17 after ovulation. The timings of ovariectomies were selected to acquire growing, early static, late static and regressing follicles of the first wave and preovulatory follicles of the ovulatory wave. Pre-selection and subordinate follicles were also available for analysis. Serum samples were taken on the day of ovariectomy and follicular fluid samples were taken after imaging. Numerical pixel value and pixel heterogeneity in a spot representing approximately 95% of the follicular antrum were quantified in T(1)- and T(2)-weighted images. T(1) and T(2) relaxation rates (T(1) and T(2)), proton density, apparent diffusion coefficients and their heterogeneities were determined from the computed magnetic resonance maps. The antra of early atretic dominant follicles showed higher T(2)-weighted mean pixel value (P < 0.008) and heterogeneity (P < 0. 01) and lower T(2) heterogeneity (P < 0.008) than growing follicles. Subordinate follicles in the presence of a preovulatory dominant follicle had higher T(1), T(1) heterogeneity, proton density, proton density heterogeneity, and lower mean pixel value in T(1)-weighted images than subordinate follicles of the anovulatory wave (P < 0.04). T(1) relaxation rate heterogeneity and proton density heterogeneity were positively correlated with follicular fluid oestradiol concentration (r = 0.4 and 0.3; P < 0.04). T(2) relaxation rate heterogeneity was positively correlated with follicular fluid progesterone concentration (r = 0.4; P < 0.008). Quantitative differences in magnetic resonance image attributes of the antrum observed among phases of follicular development and regression coincided with changes in the ability of the dominant follicle to produce steroid hormones and ovulate, and thus were indicative of physiological status and follicular health.

Detection of Chemical Exchange in Methyl Groups of Macromolecules

2019 ◽  
Author(s):  
Michelle Gill ◽  
Andrew Hsu ◽  
Arthur G. Palmer, III
Keyword(s):  
Relaxation Rate ◽  
Chemical Exchange ◽  
Double Quantum ◽  
Methyl Groups ◽  
Multiple Quantum ◽  
Relaxation Data ◽  
E Coli ◽  
Methyl Trosy ◽  
Dynamics Simulations ◽  
Exchange Broadening

<div> <div> <div> <p>The zero- and double-quantum methyl TROSY Hahn-echo and the methyl <sup>1</sup>H-<sup>1</sup>H dipole- dipole cross-correlation nuclear magnetic resonance experiments enable estimation of multiple quantum chemical exchange broadening in methyl groups in proteins. The two relaxation rate constants are established to be linearly dependent using molecular dynamics simulations and empirical analysis of experimental data. This relationship allows chemical exchange broadening to be recognized as an increase in the Hahn-echo relaxation rate constant. The approach is illustrated by analyzing relaxation data collected at three temperatures for <i>E. coli </i>ribonuclease HI and by analyzing relaxation data collected for different cofactor and substrate complexes of <i>E. coli </i>AlkB. </p> </div> </div> </div>

The localized electron: magnetic properties

2018 ◽  
Author(s):  
Jean-Pierre Launay ◽  
Michel Verdaguer
Keyword(s):  
Single Molecule ◽  
Model Systems ◽  
Ferromagnetic Coupling ◽  
Single Chain ◽  
Single Molecule Magnets ◽  
Magnetic Systems ◽  
Orbital Interactions ◽  
Prussian Blue Analogues ◽  
Mononuclear Complexes

After preliminaries about electron properties, and definitions in magnetism, one treats the magnetism of mononuclear complexes, in particular spin cross-over, showing the role of cooperativity and the sensitivity to external perturbations. Orbital interactions and exchange interaction are explained in binuclear model systems, using orbital overlap and orthogonality concepts to explain antiferromagnetic or ferromagnetic coupling. The phenomenologically useful Spin Hamiltonian is defined. The concepts are then applied to extended molecular magnetic systems, leading to molecular magnetic materials of various dimensionalities exhibiting bulk ferro- or ferrimagnetism. An illustration is provided by Prussian Blue analogues. Magnetic anisotropy is introduced. It is shown that in some cases, a slow relaxation of magnetization arises and gives rise to appealing single-ion magnets, single-molecule magnets or single-chain magnets, a route to store information at the molecular level.

Description and symmetry of aperiodic crystals

2018 ◽  
Author(s):  
Ted Janssen ◽  
Gervais Chapuis ◽  
Marc de Boissieu
Keyword(s):  
Time Reversal ◽  
Mathematical Concept ◽  
New Materials ◽  
Magnetic Systems ◽  
Atomic Structures ◽  
Modulated Phases ◽  
Quasiperiodic Functions ◽  
Aperiodic Crystals ◽  
Superspace Description

This chapter first introduces the mathematical concept of aperiodic and quasiperiodic functions, which will form the theoretical basis of the superspace description of the new recently discovered forms of matter. They are divided in three groups, namely modulated phases, composites, and quasicrystals. It is shown how the atomic structures and their symmetry can be characterized and described by the new concept. The classification of superspace groups is introduced along with some examples. For quasicrystals, the notion of approximants is also introduced for a better understanding of their structures. Finally, alternatives for the descriptions of the new materials are presented along with scaling symmetries. Magnetic systems and time-reversal symmetry are also introduced.

Sign in / Sign up

Export Citation Format

Share Document