Characterization of the Network Structure of Alkali-Activated Aluminosilicate Binders by Single- and Double-Resonance 29si {27al} Mas Nmr Experiments

Author(s):  
T. T. Tran ◽  
S. A. Bernal ◽  
D. Herfort ◽  
J. Skibsted
Author(s):  
Herve Goure Doubi ◽  
Valerie Montouillout ◽  
Gisele L Lecomte Nana ◽  
Benoit Nait Ali ◽  
Leon Koffi Konan ◽  
...  

2006 ◽  
Vol 90 (1-3) ◽  
pp. 246-250 ◽  
Author(s):  
Jian Jiao ◽  
Wei Wang ◽  
Bogdan Sulikowski ◽  
Jens Weitkamp ◽  
Michael Hunger

2009 ◽  
Vol 132 (1-2) ◽  
pp. 133-137
Author(s):  
David J. Aurentz ◽  
Anthony F. Tierno ◽  
Kevin J. Sutovich

1996 ◽  
Vol 6 (5-6) ◽  
pp. 331-340 ◽  
Author(s):  
C. Fernandez ◽  
J.P. Amoureux ◽  
J.M. Chezeau ◽  
L. Delmotte ◽  
H. Kessler

1991 ◽  
Vol 182 (2) ◽  
pp. 120-126 ◽  
Author(s):  
Lars Kellberg ◽  
Magnus Linsten ◽  
Hans J. Jakobsen

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2911
Author(s):  
Margarida Gonçalves ◽  
Inês Silveirinha Vilarinho ◽  
Marinélia Capela ◽  
Ana Caetano ◽  
Rui Miguel Novais ◽  
...  

Ordinary Portland Cement is the most widely used binder in the construction sector; however, a very high carbon footprint is associated with its production process. Consequently, more sustainable alternative construction materials are being investigated, namely, one-part alkali activated materials (AAMs). In this work, waste-based one-part AAMs binders were developed using only a blast furnace slag, as the solid precursor, and sodium metasilicate, as the solid activator. For the first time, mortars in which the commercial sand was replaced by two exhausted sands from biomass boilers (CA and CT) were developed. Firstly, the characterization of the slag and sands (aggregates) was performed. After, the AAMs fresh and hardened state properties were evaluated, being the characterization complemented by FTIR and microstructural analysis. The binder and the mortars prepared with commercial sand presented high compressive strength values after 28 days of curing-56 MPa and 79 MPa, respectively. The mortars developed with exhausted sands exhibit outstanding compressive strength values, 86 and 70 MPa for CT and CA, respectively, and the other material’s properties were not affected. Consequently, this work proved that high compressive strength waste-based one-part AAMs mortars can be produced and that it is feasible to use another waste as aggregate in the mortar’s formulations: the exhausted sands from biomass boilers.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1207
Author(s):  
Gabrielle Foran ◽  
Nina Verdier ◽  
David Lepage ◽  
Cédric Malveau ◽  
Nicolas Dupré ◽  
...  

Solid-state NMR spectroscopy is an established experimental technique which is used for the characterization of structural and dynamic properties of materials in their native state. Many types of solid-state NMR experiments have been used to characterize both lithium-based and sodium-based solid polymer and polymer–ceramic hybrid electrolyte materials. This review describes several solid-state NMR experiments that are commonly employed in the analysis of these systems: pulse field gradient NMR, electrophoretic NMR, variable temperature T1 relaxation, T2 relaxation and linewidth analysis, exchange spectroscopy, cross polarization, Rotational Echo Double Resonance, and isotope enrichment. In this review, each technique is introduced with a short description of the pulse sequence, and examples of experiments that have been performed in real solid-state polymer and/or hybrid electrolyte systems are provided. The results and conclusions of these experiments are discussed to inform readers of the strengths and weaknesses of each technique when applied to polymer and hybrid electrolyte systems. It is anticipated that this review may be used to aid in the selection of solid-state NMR experiments for the analysis of these systems.


1999 ◽  
Vol 103 (47) ◽  
pp. 10356-10364 ◽  
Author(s):  
F. Angeli ◽  
T. Charpentier ◽  
P. Faucon ◽  
J.-C. Petit

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