Kinetics of Overall Crystallization: Kinetic Criteria for Glass-Formation

2013 ◽  
pp. 395-415
Author(s):  
Ivan S. Gutzow ◽  
Jürn W. P. Schmelzer
2016 ◽  
Vol 73 (7-8) ◽  
pp. 237-239 ◽  
Author(s):  
V. V. Samoilenko ◽  
T. K. Uglova

2006 ◽  
Vol 23 (3) ◽  
pp. 672-674 ◽  
Author(s):  
Jo Chol-Lyong ◽  
Xia Lei ◽  
Ding Ding ◽  
Dong Yuan-Da

1999 ◽  
Vol 581 ◽  
Author(s):  
R. I. Wu ◽  
G. Wilde ◽  
J. H. Perepezko

ABSTRACTAl-Sm and Al-Y-Fe alloys with a high number density of nanocrystalline fcc-Al homogeneously dispersed within the amorphous matrix have been synthesized by devitrifying the precursor metallic glasses produced by rapid solidification. The kinetics of metallic glass formation and the development of the nanostructure during devitrification are discussed in terms of the rate limiting mechanism. The glass transition temperature of the two metallic glasses has been successfully assessed with the application of the modulated-temperature differential scanning calorimetry (DDSC). In addition, the formation of quenched-in nuclei was investigated by a comparison study on the cold-rolled and melt-spun Al92Sm8 amorphous samples. Furthermore, the enhancement of the particle density of the fcc-Al nanocrystals in the amorphous matrix after devitrification has been demonstrated by the incorporation of nanosize Pb particles.


2017 ◽  
Vol 727 ◽  
pp. 233-238 ◽  
Author(s):  
Qian Gao ◽  
Zeng Yun Jian ◽  
Jun Feng Xu ◽  
Man Zhu

The crystallization kinetics of melt-spun Cu64.5Zr35.5 amorphous alloy ribbons was investigated using differential scanning calorimetry (DSC) at different heating rates. Besides, the Kissinger and isoconversional approaches were used to obtain the crystallization kinetic parameters. As shown in the results, the activation energies for glass transition and crystallization process at the onset, peak and end crystallization temperatures were obtained by means of Kissinger equation to be 577.65 ± 34, 539.86 ± 54, 518.25 ± 20 and 224.84 ± 2 kJ/mol, respectively. The nucleation activation energy Enucleation is greater than grain growth activation energy Egrowth, indicating that the nucleation process is harder than grain growth. The local activation energy Eα decreases in the whole crystallization process, which suggests that crystallization process is increasingly easy.


1982 ◽  
Vol 48 (1) ◽  
pp. 65-77 ◽  
Author(s):  
H Schmidt ◽  
H Scholze ◽  
A Kaiser
Keyword(s):  

2020 ◽  
Vol 12 (1) ◽  
pp. 65-69
Author(s):  
Vandita Rao ◽  
H. P. Pathak ◽  
Pooja Lohia ◽  
D. K. Dwivedi

Structural and thermal measurements have been performed in glassy Se78Te18M4 (M = Sb and Ge) alloys to study the effect of Sb and Ge additives on the kinetics of glass transition and crystallization. Kinetic parameters of glass transition and crystallization such as the activation energy of glass transition (Eg), the activation energy of crystallization (Ec) have been determined using different non-isothermal methods. It was found that Ge was more suitable dopant for phase change memory (PCM) devices due to its low activation energies as compared to Sb dopant.


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