Theoretical Studies of Carbon Dioxide Organometallic Reactivity

1990 ◽  
pp. 23-42 ◽  
Author(s):  
A. Dedieu ◽  
C. Bo ◽  
F. Ingold
Keyword(s):  
Carbon Dioxide ◽  
Theoretical Studies

Experimental and Theoretical Studies on the Reduction of CO2 to CO with Chloro(methyl)disilane Components from the Direct Process

Synlett ◽  
2017 ◽  
Vol 28 (18) ◽  
pp. 2439-2444 ◽  
Author(s):  
Frank Jensen ◽  
Troels Skrydstrup ◽  
Mathias Flinker ◽  
Sara Lopez ◽  
Dennis Nielsen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Dft Calculations ◽  
Theoretical Studies ◽  
Direct Process ◽  
Industrial Synthesis ◽  
Reduce Carbon Dioxide ◽  
Reduction Of Co2 ◽  
Fluoride Salts ◽  
Experimental And Theoretical Studies

Three disilanes, (CH3)3SiSi(CH3)3, Cl(CH3)2SiSi(CH3)2Cl, and Cl2(CH3)SiSi(CH3)Cl2, all representing components of the Direct Process residue for the industrial synthesis of chloromethylsilanes, were evaluated for their abilities to reduce carbon dioxide to carbon monoxide upon treatment with fluoride salts. In particular, Cl(CH3)2SiSi(CH3)2Cl proved to be highly efficient upon the use of stoichiometric amounts of potassium bifluoride. DFT calculations performed on the reduction steps with (CH3)3SiSi(CH3)3 and fluorinated analogues of this disilane suggest that the previously proposed pathway involving an intermediate silacarboxylic acid is plausible.

Seasonal carbon dioxide exchange between the regolith and atmosphere of Mars: Experimental and theoretical studies

1982 ◽  
Vol 87 (B12) ◽  
pp. 10215 ◽  
Author(s):  
Fraser P. Fanale ◽  
W. Bruce Banerdt ◽  
R. Steven Saunders ◽  
L. A. Johansen ◽  
James R. Salvail
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Exchange ◽  
Theoretical Studies ◽  
Experimental And Theoretical Studies

Theoretical studies of the collision-induced Raman spectrum of carbon dioxide

1980 ◽  
Vol 39 (6) ◽  
pp. 1519-1526 ◽  
Author(s):  
R.D. Amos ◽  
A.D. Buckingham ◽  
J.H. Williams
Keyword(s):  
Carbon Dioxide ◽  
Raman Spectrum ◽  
Theoretical Studies

Experimental and theoretical studies on hydrogen bond-promoted fixation of carbon dioxide and epoxides in cyclic carbonates

2012 ◽  
Vol 14 (31) ◽  
pp. 11021 ◽  
Author(s):  
Jin-Quan Wang ◽  
Jian Sun ◽  
Wei-Guo Cheng ◽  
Kun Dong ◽  
Xiang-Ping Zhang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Bond ◽  
Theoretical Studies ◽  
Cyclic Carbonates ◽  
Experimental And Theoretical Studies ◽  
Fixation Of Carbon Dioxide

ChemInform Abstract: Theoretical Studies of Carbon Dioxide Organometallic Reactivity

ChemInform ◽  
2010 ◽  
Vol 22 (19) ◽  
pp. no-no
Author(s):  
A. DEDIEU ◽  
C. BO ◽  
F. INGOLD
Keyword(s):  
Carbon Dioxide ◽  
Theoretical Studies

Theoretical Studies on Coupling Reactions of Carbon Dioxide with Alkynes Mediated by Nickel(0) Complexes

2008 ◽  
Vol 27 (15) ◽  
pp. 3892-3900 ◽  
Author(s):  
Juan Li ◽  
Guochen Jia ◽  
Zhenyang Lin
Keyword(s):  
Carbon Dioxide ◽  
Theoretical Studies ◽  
Coupling Reactions
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