Fabrication of Solid State Amorphized Metallic Powders by Mechanical Alloying

1988 ◽  
pp. 635-640
Author(s):  
Hiroshi Kiraura
Metals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 301
Author(s):  
Kirill Lyashkov ◽  
Valery Shabashov ◽  
Andrey Zamatovskii ◽  
Kirill Kozlov ◽  
Natalya Kataeva ◽  
...  

The solid-state mechanical alloying (MA) of high-nitrogen chromium-manganese austenite steel—MA in a planetary ball mill, —was studied by methods of Mössbauer spectroscopy and transmission electron microscopy (TEM). In the capacity of a material for the alloying we used mixtures of the binary Fe–Mn and Fe–Cr alloys with the nitrides CrN (Cr2N) and Mn2N. It is shown that ball milling of the mixtures has led to the occurrence of the α → γ transitions being accompanied by the (i) formation of the solid solutions supersaturated with nitrogen and by (ii) their decomposition with the formation of secondary nitrides. The austenite formed by the ball milling and subsequent annealing at 700–800 °C, was a submicrocrystalline one that contained secondary nano-sized crystalline CrN (Cr2N) nitrides. It has been established that using the nitride Mn2N as nitrogen-containing addition is more preferable for the formation and stabilization of austenite—in the course of the MA and subsequent annealing—because of the formation of the concentration-inhomogeneous regions of γ phase enriched with austenite-forming low-mobile manganese.


1997 ◽  
Vol 12 (12) ◽  
pp. 3254-3259 ◽  
Author(s):  
J. Font ◽  
J. Muntasell ◽  
E. Cesari ◽  
J. Pons

Ball milling has been used as a solid-state mechanical alloying technique in two binary systems of plastic crystals: neopentylglycol/pentaglycerin (NPG/PG), showing a partial solubility in the ordered phase, and 2-amino-2-methyl-1,3-propanediol/tris(hydroxymethyl) (AMP/TRIS) whose immiscibility in this ordered solid phase is almost total. For the AMP/TRIS system the stable state at room temperature was reached by milling. Contrarily, for NPG/PG, DSC measurements reveal that an annealing period is required after milling. These results have been compared with those of the pentaglycerin/pentaerythritol (PG/PE) binary system, previously studied, whose miscibility is total at room temperature.


2006 ◽  
Vol 980 ◽  
Author(s):  
Tatsuhiko Aizawa ◽  
Renbo Song

AbstractMagnesium binary and ternary alloy systems have been popular as a thermoelectric light-weight alloy to be working in the medium temperature range. The solid-state reactivity via the bulk mechanical alloying is applied to yield these types of alloys. The diffusion-controlled solid-state synthesis is first stated as a process to yield a binary compound, Mg2X (X = Ge, Sn and Pb). This processing is further applied to directly synthesize several ternary thermoelectric alloys Mg2Si1-xGex, Mg2Si1-ySny and Mg2Sn1-zPbz for 0.0 < x, y, z < 1.0 and to evaluate their thermoelectric properties. Hot pressing is used to make full-dense billets and samples for thermoelectric measurement. The effect of germanium and tin contents on their Seebeck coefficient and band-gap is investigated to describe the p-n transition behavior and to understand the change of electric structure with solid solution formation.


1997 ◽  
Vol 226-228 ◽  
pp. 383-387 ◽  
Author(s):  
M. Seidel ◽  
M. Reibold ◽  
I. Bächer ◽  
H.-D. Bauer ◽  
J. Eckert ◽  
...  

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