Emulsion Polymerization: The Mechanisms of Latex Particle Formation and Growth

1990 ◽  
pp. 159-185
Author(s):  
D. H. Napper ◽  
R. G. Gilbert
Keyword(s):  
Emulsion Polymerization ◽  
Latex Particle ◽  
Particle Formation ◽  
Particle Formation And Growth

Effect of Polymer Characteristics on Particle Formation and Growth in Batch Emulsion Polymerization

2014 ◽  
Vol 36 (9) ◽  
pp. 1320-1326 ◽  
Author(s):  
Shuang Liu ◽  
Baijun Liu ◽  
Zhongyu Fu ◽  
Tingting Zhou ◽  
Liang Ren ◽  
...  
Keyword(s):  
Emulsion Polymerization ◽  
Particle Formation ◽  
Particle Formation And Growth

Particle formation and catalyzed agglomeration in emulsion polymerization

1990 ◽  
Vol 23 (6) ◽  
pp. 1618-1625 ◽  
Author(s):  
Herbert Schlueter
Keyword(s):  
Emulsion Polymerization ◽  
Particle Formation

Connection of organics to atmospheric new particle formation and growth at an urban site of Beijing

2015 ◽  
Vol 103 ◽  
pp. 7-17 ◽  
Author(s):  
Z.B. Wang ◽  
M. Hu ◽  
X.Y. Pei ◽  
R.Y. Zhang ◽  
P. Paasonen ◽  
...  
Keyword(s):  
Particle Formation ◽  
Urban Site ◽  
New Particle Formation ◽  
Particle Formation And Growth

scholarly journals A model for particle formation and growth in the atmosphere with molecular resolution in size

2002 ◽  
Vol 2 (5) ◽  
pp. 1791-1807 ◽  
Author(s):  
K. E. J. Lehtinen ◽  
M. Kulmala
Keyword(s):  
Growth Rate ◽  
Atmospheric Aerosol ◽  
Aerosol Particles ◽  
Slight Modification ◽  
Particle Formation ◽  
Simulation Methods ◽  
Discrete Method ◽  
Condensational Growth ◽  
Particle Formation And Growth ◽  
Diffusion Problems

Abstract. The formation and growth of atmospheric aerosol particles is considered using an exact discrete method with molecular resolution in size space. The method is immune to numerical diffusion problems that are a nuisance for typical simulation methods using a sectional representation for the particle size distribution. For condensational growth, a slight modification is proposed for the Fuchs-Sutugin expression, which improves the prediction of the growth rate of nano-sized particles by as much as a factor of two. The presented method is applied to particle formation in a Finnish Boreal forest and is shown to capture the essential features of the dynamics quite nicely. Furthermore, it is shown that the growth of the particles is roughly linear, which means that the amount of condensable vapour is constant (of the order 1013 1/m3).

scholarly journals Particle formation and growth at five rural and urban sites

2010 ◽  
Vol 10 (5) ◽  
pp. 11615-11657 ◽  
Author(s):  
C.-H. Jeong ◽  
G. J. Evans ◽  
M. L. McGuire ◽  
R. Y.-W. Chang ◽  
J. P. D. Abbatt ◽  
...  
Keyword(s):  
Ultrafine Particle ◽  
Particle Formation ◽  
Nucleation And Growth ◽  
Biogenic Emissions ◽  
Traffic Density ◽  
Particle Nucleation ◽  
Size Distributions ◽  
Industrial Sources ◽  
Rural Sites ◽  
Particle Formation And Growth

Abstract. Ultrafine particle (UFP) number and size distributions were simultaneously measured at five urban and rural sites in Southern Ontario, Canada as part of the Border Air Quality and Meteorology Study (BAQS-Met 2007). Particle formation and growth events at these five sites were classified based on their strength and persistence as well as the variation in geometric mean diameter. Regional nucleation and growth events and local short-lived strong nucleation events were frequently observed at the near-border rural sites, upwind of industrial sources. Surprisingly, the particle number concentrations at one of these sites were higher than the concentrations at a downtown site in a major city, despite its high traffic density. Regional nucleation and growth events were favored at intense solar irradiance and less polluted cooler drier air. The most distinctive regional particle nucleation and growth event during the campaign was observed simultaneously at all five sites, which were up to 350 km apart. Although the ultrafine particle concentrations and size distributions generally were spatially heterogeneous across the region, a more uniform spatial distribution of UFP across the five areas was observed during this regional nucleation event. Thus, nucleation events can cover large regions, contributing to the burden of UFP in cities and potentially to the associated health impacts on urban populations. In addition, particle formation in southwestern Ontario appears to more often be related to anthropogenic gaseous emissions, although biogenic emissions may at times contribute. Local short-lived nucleation events at the near-border sites during this three-week campaign were associated with high SO2, which likely originated from US and Canadian industrial sources. These particle formation events may contribute to the production of cloud condensation nuclei, thus potentially influencing regional climate. Longer-term studies are needed to help resolve the relative contributions of anthropogenic and biogenic emissions to nucleation and growth in this region.

scholarly journals New particle formation, growth and apparent shrinkage at a rural background site in western Saudi Arabia

2019 ◽  
Vol 19 (16) ◽  
pp. 10537-10555 ◽  
Author(s):  
Simo Hakala ◽  
Mansour A. Alghamdi ◽  
Pauli Paasonen ◽  
Ville Vakkari ◽  
Mamdouh I. Khoder ◽  
...  
Keyword(s):  
Saudi Arabia ◽  
Growth Rates ◽  
Particle Formation ◽  
Anthropogenic Sources ◽  
New Particle Formation ◽  
Rural Background ◽  
Background Site ◽  
High Solar Radiation ◽  
Particle Formation And Growth ◽  
Condensation Sink

Abstract. Atmospheric aerosols have significant effects on human health and the climate. A large fraction of these aerosols originates from secondary new particle formation (NPF), where atmospheric vapors form small particles that subsequently grow into larger sizes. In this study, we characterize NPF events observed at a rural background site of Hada Al Sham (21.802∘ N, 39.729∘ E), located in western Saudi Arabia, during the years 2013–2015. Our analysis shows that NPF events occur very frequently at the site, as 73 % of all the 454 classified days were NPF days. The high NPF frequency is likely explained by the typically prevailing conditions of clear skies and high solar radiation, in combination with sufficient amounts of precursor vapors for particle formation and growth. Several factors suggest that in Hada Al Sham these precursor vapors are related to the transport of anthropogenic emissions from the coastal urban and industrial areas. The median particle formation and growth rates for the NPF days were 8.7 cm−3 s−1 (J7 nm) and 7.4 nm h−1 (GR7−12 nm), respectively, both showing highest values during late summer. Interestingly, the formation and growth rates increase as a function of the condensation sink, likely reflecting the common anthropogenic sources of NPF precursor vapors and primary particles affecting the condensation sink. A total of 76 % of the NPF days showed an unusual progression, where the observed diameter of the newly formed particle mode started to decrease after the growth phase. In comparison to most long-term measurements, the NPF events in Hada Al Sham are exceptionally frequent and strong both in terms of formation and growth rates. In addition, the frequency of the decreasing mode diameter events is higher than anywhere else in the world.

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