PVT properties of concentrated aqueous electrolytes. II. Compressibilities and apparent molar compressibilities of aqueous NaCl, Na2SO4, MgCl2, and MgSO4 from dilute solution to saturation and from 0 to 50�C

1982 ◽  
Vol 11 (10) ◽  
pp. 671-686 ◽  
Author(s):  
Frank J. Millero ◽  
J. Ricco ◽  
Donald R. Schreiber

1985 ◽  
Vol 14 (12) ◽  
pp. 837-851 ◽  
Author(s):  
Frank J. Millero ◽  
Leslie M. Connaughton ◽  
Faina Vinokurova ◽  
Peter V. Chetirkin




1990 ◽  
Vol 19 (4) ◽  
pp. 353-374 ◽  
Author(s):  
Eugene A. Dedick ◽  
J. Peter Hershey ◽  
Sara Sotolongo ◽  
David J. Stade ◽  
Frank J. Millero


Author(s):  
P. Pradère ◽  
J.F. Revol ◽  
R. St. John Manley

Although radiation damage is the limiting factor in HREM of polymers, new techniques based on low dose imaging at low magnification have permitted lattice images to be obtained from very radiation sensitive polymers such as polyethylene (PE). This paper describes the computer averaging of P4MP1 lattice images. P4MP1 is even more sensitive than PE (total end point dose of 27 C m-2 as compared to 100 C m-2 for PE at 120 kV). It does, however, have the advantage of forming flat crystals from dilute solution and no change in d-spacings is observed during irradiation.Crystals of P4MP1 were grown at 60°C in xylene (polymer concentration 0.05%). Electron microscopy was performed with a Philips EM 400 T microscope equipped with a Low Dose Unit and operated at 120 kV. Imaging conditions were the same as already described elsewhere. Enlarged micrographs were digitized and processed with the Spider image processing system.



Author(s):  
Sengshiu Chung ◽  
Peggy Cebe

We are studying the crystallization and annealing behavior of high performance polymers, like poly(p-pheny1ene sulfide) PPS, and poly-(etheretherketone), PEEK. Our purpose is to determine whether PPS, which is similar in many ways to PEEK, undergoes reorganization during annealing. In an effort to address the issue of reorganization, we are studying solution grown single crystals of PPS as model materials.Observation of solution grown PPS crystals has been reported. Even from dilute solution, embrionic spherulites and aggregates were formed. We observe that these morphologies result when solutions containing uncrystallized polymer are cooled. To obtain samples of uniform single crystals, we have used two-stage self seeding and solution replacement techniques.



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