Zero-waste technology for the preparation and application of aluminum chloride solutions in petroleum refineries

1995 ◽  
Vol 31 (5) ◽  
pp. 201-205
Author(s):  
V. F. Sorochenko
Keyword(s):  
Aluminum Chloride ◽  
Chloride Solutions ◽  
Zero Waste ◽  
Petroleum Refineries

Hydrophobization of coarse calico by wet treatment in aluminum chloride solutions

Cellulose ◽  
2022 ◽  
Author(s):  
E. V. Endiiarova ◽  
A. A. Osipov ◽  
S. E. Alexandrov
Keyword(s):  
Aluminum Chloride ◽  
Chloride Solutions

Precipitation-redissolution phenomena in sulfonate-aluminum chloride solutions

Langmuir ◽  
1988 ◽  
Vol 4 (4) ◽  
pp. 1061-1063 ◽  
Author(s):  
P. Somasundaran ◽  
K. P. Ananthapadmanabhan ◽  
M. S. Celik
Keyword(s):  
Aluminum Chloride ◽  
Chloride Solutions

Solubility Products of Aluminum Hydroxide in Various Ionic Solutions

1973 ◽  
Vol 51 (21) ◽  
pp. 3528-3533 ◽  
Author(s):  
David T. Y. Chen
Keyword(s):  
Aluminum Hydroxide ◽  
Aluminum Chloride ◽  
Solubility Product ◽  
Ionic Solutions ◽  
Chloride Solutions ◽  
Ion Concentrations ◽  
Ph Values ◽  
Solubility Products ◽  
Low Solubility

Solubility products of Al(OH)3 were determined in various solutions of NH4+, Li+, Na+, K+, and Ca2+ ions. Increasing amounts of these hydroxides were added to the respective chloride solutions containing aluminum chloride. The solutions were aged for 3 months. Activities of the OH− ions were calculated from the pH values of the solutions. The total Al concentrations remaining in solutions were determined by Hsu's modified aluminon method. The Al3+ ion concentrations were computed using the hydrolysis equilibria of Aveston. The ion product, aAl3+(aOH−)3, was found to vary linearly with the [OH]/[Al] ratio. The solubility product of Al(OH)3 was obtained by extrapolating this ratio to 3. The pKsp values thus obtained were 30.55, 33.15, 30.75, 30.36, and 31.00 in NH4+, Li+, Na+, K+, and Ca2+ systems respectively. The anomalously low solubility product of Al(OH)3 in the Li+ system was attributed to the specific "lithium effect".

Thermodynamic properties of aluminum chloride solutions in the molten LiClKCl system

1988 ◽  
Vol 33 (6) ◽  
pp. 761-767 ◽  
Author(s):  
F. Lantelme ◽  
H. Alexopoulos ◽  
M. Chemla ◽  
O. Haas
Keyword(s):  
Thermodynamic Properties ◽  
Aluminum Chloride ◽  
Chloride Solutions

CONDITIONS IN SOLUTION DURING THE FORMATION OF GIBBSITE IN DILUTE ALUMINUM SALT SOLUTIONS: III. HYDROXYALUMINUM PRODUCTS OF REACTIONS DURING THE NEUTRALIZATION OF ALUMINUM CHLORIDE SOLUTIONS WITH SODIUM HYDROXIDE

1969 ◽  
Vol 49 (3) ◽  
pp. 389-396 ◽  
Author(s):  
R. C. Turner ◽  
G. J. Ross
Keyword(s):  
Sodium Hydroxide ◽  
Aluminum Chloride ◽  
Solid Phase ◽  
Major Product ◽  
Aluminum Salt ◽  
Molar Ratio ◽  
Salt Solutions ◽  
Chloride Solutions

Experiments were made to determine the relative amounts of solid phase hydroxyaluminum to polynuclear ionic hydroxyaluminum formed, according to methods developed by one of the authors, during titrations of dilute AlCl3 solutions with a base. With both 10−3 and 10−2 M AlCl3 solutions, and with both fast (less than 5 minutes) and slow (12 hours) titrations, the solid phase and the polynuclear ions were present at each degree of neutralization at which measurements were made. During the greater part of the titrations the solid phase was the major product with the fast titrations, and the polynuclear ions were the major product with the slow titrations. Beyond about 80% neutralization the polynuclear ions began to decrease in concentration until at 100% the solid phase approached 100% of the products regardless of the rate of titration. There was a considerable amount of Cl associated with the solid phase during most of each titration, but the Cl/Al molar ratio of the solid approached zero as neutralization approached 100%.

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