The effect of a magnetic field on the electrical conductivity of water and aqueous solutions of electrolytes

1968 ◽  
Vol 9 (3) ◽  
pp. 316-320
Author(s):  
L. A. Blyumenfel'd ◽  
M. G. Gol'dfeld
Keyword(s):  
Magnetic Field ◽  
Electrical Conductivity ◽  
Aqueous Solutions ◽  
Solutions Of Electrolytes

scholarly journals The conductivity of uni-univalent salts in methyl alcohol at 25°C

1925 ◽  
Vol 109 (750) ◽  
pp. 351-368 ◽  
Keyword(s):  
Electrical Conductivity ◽  
Aqueous Solutions ◽  
Physical Properties ◽  
Methyl Alcohol ◽  
Experimental Work ◽  
Complete Understanding ◽  
Systematic Data ◽  
The Past ◽  
Aqueous Solvent ◽  
Solutions Of Electrolytes

The physical properties of solutions of electrolytes in non-aqueous solvents have been investigated in the past by a number of workers, but until recently the work in this field has been characterised to some extent by lack of accuracy and of co-ordination. The need for accurate experimental work in this direction is clear when it is realised that modern theories of the behaviour of electrolytes in solution are based almost entirely on data obtained for solutions in water. It is probable that a more complete understanding of the nature of solutions can come only through experimental work extending over a range of solvents: the peculiar properties of water as a solvent have tended hitherto to obscure many of the fundamental difficulties of the problem by cloaking them in the garb of simplicity. The work which forms the substance of this paper was undertaken with a view to obtaining some systematic data for the electrical conductivity of dilute solutions of uni-univalent salts in a non-aqueous solvent, of an accuracy comparable with that of Kohlrausch and his co-workers in the case of aqueous solutions. The choice of methyl alcohol as a solvent was governed by the fact that it is most closely allied to water in type, and is experimentally well suited for such an investigation.

scholarly journals Investigation of temperature effect on the electrical conductivity of alcohol solutionssodium and potassium alcoholates

2020 ◽  
Vol 61 (1) ◽  
pp. 81-85
Author(s):  
Vera A. Petrukhina ◽  
◽  
Pavel I. Fedorov ◽  
Ksenia A. Konnova ◽  
Maria V. Yakimova ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Aqueous Solutions ◽  
Temperature Dependence ◽  
Isopropyl Alcohol ◽  
Effect Of Temperature ◽  
Inorganic Salts ◽  
Equivalent Conductivity ◽  
Solutions Of Electrolytes ◽  
Weak Electrolytes ◽  
Sodium And Potassium

Earlier, we studied the electrical conductivity of inorganic salts in a number of alcohols (ethanol, propanol-2, and butanol-1) at room temperature and found that alcoholic solutions of inorganic salts are weak electrolytes. It is known that an increase in the temperature of salt solutions leads to an increase in electrical conductivity due to an increase in the mobility of their ions in the solvent medium. To study the temperature dependence of the electrical conductivity of aqueous solutions of electrolytes, we proposed an approach based on the study of the effect of temperature on the equivalent electrical conductivity of solutions at infinite dilution λ∞. Using this approach, we studied the electrical conductivity of aqueous solutions of a number inorganic salts (nitrates, acetates, and phosphates), carboxylic acids, and amino acids as a function of temperature. It was found that for these solutions the dependence λ∞(Т) is described by the exponential Arrhenius equation λ∞ = Аexp(-E/(RT)). This equation was used to describe the temperature dependence of the ultimate equivalent conductivity for solutions of a number of inorganic salts (calcium and nitrate calcium, cadmium, lithium and potassium iodides, chloride, iodide and ammonium nitrate, silver nitrate and sodium bromide) in ethanol. This article investigated and demonstrated the possibility of describing the experimental data λ∞(Т) for solutions of ethylates, propylates and isopropylates of sodium and potassium in the corresponding alcohols (ethylates in ethanol, propylates in propanol, isopropylates in isopropyl alcohol) using the same equation.

scholarly journals Preliminary Note on the Conductivity of Concentrated Aqueous Solutions of Electrolytes

1906 ◽  
Vol 26 (1) ◽  
pp. 234-237
Author(s):  
J. Gibson
Keyword(s):  
Electrical Conductivity ◽  
Aqueous Solutions ◽  
Electrolytic Conductivity ◽  
Preliminary Note ◽  
Chemical Action ◽  
Concentrated Aqueous Solutions ◽  
Solutions Of Electrolytes ◽  
Chemical Behaviour

In a paper communicated to the Society in 1897, the author drew attention to increase in electrical conductivity as a characteristic of photo-chemical action, and in a second communication in December of the same year, made the following statement—“It would appear that the chemical behaviour of the acids just mentioned (HNO3, HCl, H2SO4) depends in many of their reactions on whether their concentration is above or below that corresponding to their maximum electrolytic conductivity.”

Concerning the mechanism of the influence of a magnetic field of aqueous solutions of salts

1969 ◽  
Vol 98 (5) ◽  
pp. 195-199 ◽  
Author(s):  
O.I. Martynova ◽  
B.T. Gusev ◽  
E.A. Leont'ev
Keyword(s):  
Magnetic Field ◽  
Aqueous Solutions

Gas holdup in bubbled beds of aqueous solutions of electrolytes

1977 ◽  
Vol 42 (9) ◽  
pp. 2642-2650
Author(s):  
F. Kaštánek ◽  
J. Kratochvíl ◽  
J. Pata ◽  
M. Rylek
Keyword(s):  
Aqueous Solutions ◽  
Gas Holdup ◽  
Solutions Of Electrolytes

Viscosity, electrical conductivity and density of the system ammonium nitrate-dimethyl sulphoxide

1984 ◽  
Vol 49 (5) ◽  
pp. 1109-1115
Author(s):  
Jindřich Novák ◽  
Zdeněk Kodejš ◽  
Ivo Sláma
Keyword(s):  
Electrical Conductivity ◽  
Aqueous Solutions ◽  
Ammonium Nitrate ◽  
Transport Properties ◽  
Calcium Nitrate ◽  
Dimethyl Sulphoxide ◽  
Present System ◽  
Empirical Equations ◽  
Concentrated Solutions ◽  
Nitrate Solutions

The density, viscosity, and electrical conductivity of highly concentrated solutions of ammonium nitrate in dimethyl sulphoxide have been determined over the temperature range 10-60 °C and the concentration range 7-50 mol% of the salt. The variations in the quantities as a function of temperature and concentration have been correlated by empirical equations. A comparison is made between the transport properties for the present system, aqueous solutions of ammonium nitrate, and calcium nitrate solutions in dimethyl sulphoxide.

The metachor as a characteristic of the association of electrolytes in aqueous solutions

1984 ◽  
Vol 49 (5) ◽  
pp. 1061-1078 ◽  
Author(s):  
Jiří Čeleda ◽  
Stanislav Škramovský
Keyword(s):  
Aqueous Solutions ◽  
Apparent Volume ◽  
Solutions Of Electrolytes ◽  
Molal Volumes ◽  
The Difference ◽  
High Concentrations ◽  
Experimental Values ◽  
Suitable Characteristic ◽  
Association Of Ions ◽  
Very High

Based on the earlier paper introducing a concept of the apparent parachor of a solute in the solution, we have eliminated in the present work algebraically the effect which is introduced into this quantity by the additivity of the apparent molal volumes. The difference remaining from the apparent parachor after substracting the contribution corresponding to the apparent volume ( for which the present authors suggest the name metachor) was evaluated from the experimental values of the surface tension of aqueous solutions for a set of 1,1-, 1,2- and 2,1-valent electrolytes. This difference showed to be independent of concentration up to the very high values of the order of units mol dm-3 but it was directly proportional to the number of the free charges (with a proportionality factor 5 ± 1 cm3 mol-1 identical for all studied electrolytes). The metachor can be, for this reason, a suitable characteristic for detection of the association of ions and formation of complexes in the solutions of electrolytes, up to high concentrations where other methods are failing.

Sign in / Sign up

Export Citation Format

Share Document