Cross-coupling reaction of phenyltriethoxytitanium with allyl halides catalyzed by palladium complexes

1984 ◽  
Vol 33 (12) ◽  
pp. 2599-2599 ◽  
Author(s):  
G. A. Tolstikov ◽  
A. N. Kasatkin
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Cross Coupling Reaction ◽  
Allyl Halides

scholarly journals A Quantum-Chemical DFT Approach to Elucidation of the Chirality Transfer Mechanism of the Enantioselective Suzuki–Miyaura Cross-Coupling Reaction

2017 ◽  
Vol 2017 ◽  
pp. 1-12 ◽  
Author(s):  
Radomir Jasiński ◽  
Oleg M. Demchuk ◽  
Dmytro Babyuk
Keyword(s):  
Quantum Chemical ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Initial Reaction ◽  
Chiral Ligand ◽  
Chirality Transfer ◽  
Cross Coupling Reaction ◽  
Enantioselective Reactions ◽  
Selection Of

The DFT calculations of the simplified model of the asymmetric Suzuki–Miyaura coupling reaction were performed at the M062x/LANL2DZ theory level at first. It was found that enantioselective reactions mediated by the palladium complexes of chiral C,P-ligands follow a four-stage mechanism similar to that proposed previously as one of the most credible mechanisms. It should be underlined that the presence of substituents in the substrates and the chiral ligand at ortho positions determines the energies of possible diastereoisomeric transition states and intermediates in initial reaction steps. This suggests that, in practice, a sharp selection of theoretically possible paths of chirality transfer from the catalyst to the product should have a place and, therefore, the absolute configuration of the formed atropisomeric product is defined and can be predicted.

Highly Efficient Bulkyα-Diimine Palladium Complexes for Suzuki-Miyaura Cross-Coupling Reaction

2017 ◽  
Vol 35 (3) ◽  
pp. 363-367 ◽  
Author(s):  
Ping Huo ◽  
Jingbo Li ◽  
Wanyun Liu ◽  
Guangquan Mei
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Highly Efficient ◽  
Cross Coupling Reaction

ChemInform Abstract: α-Hydroxyimine Palladium Complexes: Synthesis, Molecular Structure, and Their Activities Towards the Suzuki-Miyaura Cross-Coupling Reaction.

ChemInform ◽  
2013 ◽  
Vol 44 (34) ◽  
pp. no-no
Author(s):  
Xiao Tang ◽  
Ying-Tang Huang ◽  
Huan Liu ◽  
Rui-Zhi Liu ◽  
Dong-Sheng Shen ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Cross Coupling Reaction

Nickel-catalyzed cross-coupling reaction of allyl halides with alkynyltins

1995 ◽  
Vol 60 (18) ◽  
pp. 5752-5756 ◽  
Author(s):  
Dong-Mei Cui ◽  
Naoko Hashimoto ◽  
Shin-ichi Ikeda ◽  
Yoshiro Sato
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Cross Coupling Reaction ◽  
Allyl Halides

Synthesis of Allyl Allenes through Three-Component Cross-Coupling Reaction ofN-Tosylhydrazones, Terminal Alkynes, and Allyl Halides

2013 ◽  
Vol 8 (7) ◽  
pp. 1404-1407 ◽  
Author(s):  
Fei Ye ◽  
Mohammad Lokman Hossain ◽  
Yan Xu ◽  
Xiaoshen Ma ◽  
Qing Xiao ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Terminal Alkynes ◽  
Cross Coupling Reaction ◽  
Allyl Halides

Suzuki—Miyaura Cross-Coupling Reaction of Aryl Bromides and Chlorides with Phenylboronic Acid under Aerobic Conditions Catalyzed by Palladium Complexes with Thiosemicarbazone Ligands.

ChemInform ◽  
2005 ◽  
Vol 36 (28) ◽  
Author(s):  
Ioannis D. Kostas ◽  
Fotini J. Andreadaki ◽  
Dimitra Kovala-Demertzi ◽  
Christos Prentjas ◽  
Mavroudis A. Demertzis
Keyword(s):  
Phenylboronic Acid ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Aerobic Conditions ◽  
Aryl Bromides ◽  
Cross Coupling Reaction
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