Effect of oxygen adsorption on the kinetics of radical-recombination luminescence of phosphors

1970 ◽  
Vol 13 (9) ◽  
pp. 1224-1226
Author(s):  
Yu. A. Sivov ◽  
V. V. Styrov ◽  
L. I. Yagnova

1973 ◽  
Vol 16 (12) ◽  
pp. 1633-1635
Author(s):  
Yu. M. Naslednikov ◽  
V. V. Styrov ◽  
V. D. Khoruzhin


1969 ◽  
Vol 12 (12) ◽  
pp. 1647-1648
Author(s):  
Yu. A. Markin ◽  
Yu. A. Sivov ◽  
V. A. Sokolov ◽  
V. V. Styrov






1973 ◽  
Vol 16 (8) ◽  
pp. 1108-1112
Author(s):  
B. G. Urusov ◽  
V. V. Styrov ◽  
V. A. Sokolov


1970 ◽  
Vol 13 (8) ◽  
pp. 1010-1014
Author(s):  
V. V. Styrov ◽  
Yu. A. Sivov ◽  
Yu. A. Markin ◽  
Yu. M. Naslednikov


2020 ◽  
Vol 6 (8(77)) ◽  
pp. 21-23
Author(s):  
S.N. Sarmasov ◽  
R.Sh. Rahimov ◽  
T.Sh. Abdullayev

The effect of oxygen adsorption on the conductivity of PbTe films is studied. Pn junctions based on PbTe films are photosensitive in the IR spectral region with a maximum photosensitivity of 𝜆𝑚𝑎𝑥 microns. The tunneling mechanism of current flow through the pn junction is shown.



Isobars for the adsorption of O 2 , H 2 and CO on evaporated films of Rh, Mo, W and Fe, of Ch and CO on Ta, Pt and Pd, and of O 2 on Cu, Al and Zn have been obtained. On Rh, Mo and W the rapid adsorption of O 2 and H 2 at -183° C results in formation of monolayers with one atom per surface atom. On Ta, Pt, Pd, Cu, Al and Zn oxygen, and on Fe hydrogen form similar monolayers, but on Fe oxygen forms several layers of oxide. On Rh, Mo and possibly Ta the fast CO chemisorption corresponds to a two-site mechanism; on W and Fe it lies between that for a single and a two-site mechanism; on Pt and Pd single-site adsorption may take place. Kinetics of slow oxygen uptakes have been followed on Rh, Mo, W, Ta, Fe, Cu and Zn. With Rh, Mo, W, Ta and Zn it is believed that formation of the first oxide layer has been observed, and the rate expression is velocity ∝√{ p ) e -∝ v / RT , where v is the adsorbed volume and ∝ is a constant. The suggested mechanism is interchange of adsorbed oxygen atoms with underlying metal atoms, whereby metal atoms are exposed for further oxygen adsorption. On Cu and Fe formation of up to six and ten oxide layers respectively have been observed, and the rate expressions (u ∝ p 0.75 / v 2 and u ∝ p 0.2 e ∝'/ v ) have been interpreted in terms of the theory of Cabrera & Mott (1948).



1989 ◽  
Vol 40 (14) ◽  
pp. 9767-9771 ◽  
Author(s):  
P. J. Sebastian ◽  
V. Sivaramakrishnan


Sign in / Sign up

Export Citation Format

Share Document