Pressure and density dependence of capacity ratios in supercritical fluid chromatography (SFC) with carbon dioxide as mobile phase

1975 ◽  
Vol 8 (6) ◽  
pp. 274-276 ◽  
Author(s):  
U. van Wasen ◽  
G. M. Schneider
Keyword(s):  
Carbon Dioxide ◽  
Density Dependence ◽  
Supercritical Fluid ◽  
Supercritical Fluid Chromatography ◽  
Mobile Phase

Supercritical argon as a mobile phase for the flame photometric detection of sulfur

2003 ◽  
Vol 81 (10) ◽  
pp. 1051-1056 ◽  
Author(s):  
Kevin B Thurbide ◽  
Brad W Cooke
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Supercritical Fluid ◽  
Supercritical Fluid Chromatography ◽  
Mobile Phase ◽  
Packed Column ◽  
Flow Rates ◽  
Photometric Detection ◽  
Flame Photometric Detection ◽  
Background Emission

The background emission properties of supercritical argon and supercritical carbon dioxide mobile phases in packed column supercritical fluid chromatography (pSFC) with flame photometric detection (FPD) were compared. As column flow rates were increased toward common values used in pSFC, the carbon dioxide background emission grew enormously. The resulting emission spectrum displayed dominant features at wavelengths between 325 and 525 nm, consisting of a complex series of overlapping molecular emission band systems partly attributed to CO* and CH*. By comparison, when using the same flow rates with a supercritical argon mobile phase, the background emission was identical to that of the FPD flame without column effluent. In terms of intensity, when using a column flow rate of 2 mL/min, supercritical carbon dioxide contributes a background emission in the FPD that is about 3 × 105 times larger than that produced by supercritical argon. This difference leads to an improvement of two orders of magnitude in the pSFC-FPD signal-to-noise ratio for sulfur when a supercritical argon mobile phase is used. Results indicate that supercritical argon could also be advantageous for the pSFC-FPD analysis of other elements.Key words: supercritical fluid chromatography, packed column, flame photometric detection, supercritical argon.

Pressure, temperature and density drops along supercritical fluid chromatography columns in different thermal environments. III. Mixtures of carbon dioxide and methanol as the mobile phase

2014 ◽  
Vol 1323 ◽  
pp. 143-156 ◽  
Author(s):  
Donald P. Poe ◽  
Devon Veit ◽  
Megan Ranger ◽  
Krzysztof Kaczmarski ◽  
Abhijit Tarafder ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Fluid ◽  
Supercritical Fluid Chromatography ◽  
Mobile Phase ◽  
Thermal Environments ◽  
Chromatography Columns
Sign in / Sign up

Export Citation Format

Share Document