Premartensitic phase transformation in a TiNiFe shape memory alloy studied by Mössbauer spectroscopy

1991 ◽  
Vol 66 (1-4) ◽  
pp. 345-349 ◽  
Author(s):  
M. Jiménez ◽  
S. Aburto ◽  
S. Gómez ◽  
V. Marquina ◽  
M. L. Marquina ◽  
...  
1988 ◽  
Vol 41 (1) ◽  
pp. 595-598 ◽  
Author(s):  
L. Murgas ◽  
Z. Homonnay ◽  
S. Nagy ◽  
A. Vértes

1991 ◽  
Vol 246 ◽  
Author(s):  
M. Jimenez ◽  
V. Marquina ◽  
S. Aburto ◽  
M.L. Marquina ◽  
R. Gomez ◽  
...  

AbstractMÖssbauer spectroscopy is very sensitive to structural transitions that may occur during a phase change of the type known to arise in the shape memory TiNiFe alloy. In this work we present the results of resistance vs temperature, differential scanning calorimetry (DSC) and Mössbauer spectroscopy (MS) measurements in Ti50Ni47Fe3 sample. The resistance vs temperature curve shows the usual sharp increase associated to the B2 → R transition at Tp = 245 K and then raises until a maximum is attained at ∼ 150 K. The DSC curve shows a peak maximum at the same temperature where the resistivity starts to increase. The room temperature Mössbauer spectrum consists of a single line, indicating that the iron atoms have cubic surroundings. As temperature is lowered, a small asymmetric quadrupole doublet begins to develop. The isomer shift (I.S.) and quadrupole splitting (ΔQ) values of this doublet increase with decreasing temperature until almost constant values are achieved at temperatures ∼ 100 K. We relate the changes in the Mössbauer spectra with previously proposed charge density wave induced premartensitic transition.


Metals ◽  
2013 ◽  
Vol 3 (2) ◽  
pp. 225-236 ◽  
Author(s):  
Rie Umetsu ◽  
Kenji Sano ◽  
Kouji Fukushima ◽  
Takeshi Kanomata ◽  
Yusuke Taniguchi ◽  
...  

2018 ◽  
Vol 239 (1) ◽  
Author(s):  
I. Unzueta ◽  
J. López-García ◽  
V. Sánchez-Alarcos ◽  
V. Recarte ◽  
J. I. Pérez-Landazábal ◽  
...  

1993 ◽  
Vol 15 (3-4) ◽  
pp. 211-224 ◽  
Author(s):  
E. Kuzmann ◽  
Z. Homonnay ◽  
S. Nagy ◽  
M. Gál ◽  
A. Vértes

57Fe,119Sn, and151Eu Mössbauer spectroscopy was used to study the chemical structure, phonon mode changes, and low-temperature phase transformation around the Tcas well as suppression of superconductivity in high-temperature superconductors and related compounds. Anomalous temperature-dependent changes in the total57Fe spectral area fraction and in the Mössbauer line shift were simultaneously found around the Tcin a EuBa2(Cu0.9957Fe0.01)3O7-dsuperconductor. These anomalous changes were attributed to phonon softening and low-temperature phase transformation occurring around the superconducting transition. Significant differences were observed between the57Fe Mössbauer spectra of superconducting EuBa2(Cu0.9957Fe0.01)3O7-dand the isostructural non-superconducting PrBa2(Cu0.9957Fe0.01)3O7-d. The differences were interpreted in connection with the suppression of superconductivity (by hole filling or hybridization of Pr, Cu and O states) in the Pr-containing compound. The unusually high isomer shift value observed in the Pr-containing material can give evidence for the charge transfer mechanism between the Cu(1) chains and the Cu(2) planes and for its role in the suppression of superconductivity.


1997 ◽  
Vol 481 ◽  
Author(s):  
V. Marquina ◽  
R. Gómez ◽  
S. Aburto ◽  
M. Jiménez ◽  
R. Ridaura ◽  
...  

ABSTRACTWe present differential scanning calorimetry (DSC) and in situ Mössbauer spectroscopy results for Metglas ribbons, to which different heat treatments were made. The Curie temperature of the amorphous phase is determined and the evolution of the magnetic field of this phase is studied as a function of temperature.


2005 ◽  
Vol 161 (1-4) ◽  
pp. 221-227 ◽  
Author(s):  
J. Martínez ◽  
G. Aurelio ◽  
G. Cuello ◽  
S. M. Cotes ◽  
A. Fernández Guillermet ◽  
...  

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