Amorphous to Crystalline Phase Transformation in Metglas® Studied by Mössbauer Spectroscopy

1997 ◽  
Vol 481 ◽  
Author(s):  
V. Marquina ◽  
R. Gómez ◽  
S. Aburto ◽  
M. Jiménez ◽  
R. Ridaura ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Differential Scanning Calorimetry ◽  
Phase Transformation ◽  
Mössbauer Spectroscopy ◽  
Curie Temperature ◽  
Mossbauer Spectroscopy ◽  
Scanning Calorimetry ◽  
Mößbauer Spectroscopy ◽  
The Magnetic Field

ABSTRACTWe present differential scanning calorimetry (DSC) and in situ Mössbauer spectroscopy results for Metglas ribbons, to which different heat treatments were made. The Curie temperature of the amorphous phase is determined and the evolution of the magnetic field of this phase is studied as a function of temperature.

Mössbauer Spectroscopy of the Magnetic-Field-Induced Ferroelectric Phase of CuFeO2

2015 ◽  
Vol 84 (2) ◽  
pp. 024719 ◽  
Author(s):  
Shin Nakamura ◽  
Yasuhiro Kobayashi ◽  
Shinji Kitao ◽  
Makoto Seto ◽  
Akio Fuwa ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Mössbauer Spectroscopy ◽  
Mossbauer Spectroscopy ◽  
Ferroelectric Phase ◽  
Mößbauer Spectroscopy ◽  
The Magnetic Field

scholarly journals Studies about the design of magnetic bionanocomposite

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Robert Müller ◽  
Janna Kuchinka ◽  
Thomas Heinze
Keyword(s):  
Magnetic Field ◽  
Drug Delivery ◽  
Mössbauer Spectroscopy ◽  
Fatty Acid ◽  
Optical Microscopy ◽  
High Frequency ◽  
Mossbauer Spectroscopy ◽  
Fatty Acid Esters ◽  
Iron Oxide Particles ◽  
Mößbauer Spectroscopy

Abstract Magnetic nanocomposites are a class of smart materials that have attracted recent interest as drug delivery systems or as medical implants. A new approach toward the biocompatible nanocomposites suitable for remote melting is presented. It is shown that magnetite nanoparticles (MNPs) can be embedded into a matrix of biocompatible thermoplastic dextran esters. For that purpose, fatty acid esters of dextran with adjustable melting points in the range of 30–140 °C were synthesized. Esterification of the polysaccharide by activation of the acid as iminium chlorides guaranteed mild reaction conditions leading to high-quality products as confirmed by Fourier-transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopy as well as by gel permeation chromatography (GPC). A method for the preparation of magnetically responsive bionanocomposites (BNCs) was developed consisting of combined dissolution/suspension of the dextran ester and hydrophobized MNPs in an organic solvent followed by homogenization with ultrasonication, casting of the solution, drying and melting of the composite for a defined shaping. This process leads to a uniform distribution of MNPs in BNC as revealed by scanning electron microscope (SEM). Samples of different geometries were exposed to high-frequency alternating magnetic field (AMF). It could be shown that defined remote melting of such biocompatible nanocomposites is possible for the first time. This may lead to a new class of magnetic remote-control systems, which are suitable for controlled release applications or self-healing materials. BNCs containing biocompatible dextran fatty acid ester melting close to human body temperature were prepared and loaded with Rhodamine B (RhB) or green fluorescent protein (GFP) as model drugs to evaluate their potential use as drug delivery system. The release of the model drugs from the magnetic BNC investigated under the influence of a high-frequency AMF (20 kA/m at 400 kHz) showed that on-demand release is realized by applying the external AMF. The BNC possessed a long-term stability (28 d) of the incorporated iron oxide particles after incubation in artificial body fluids. Temperature-dependent mobility investigations of MNP in the molten BNC were carried out by optical microscopy, magnetometry, alternating current (AC) susceptibility, and Mössbauer spectroscopy measurements. Optical microscopy shows a movement of agglomerates and texturing in the micrometer scale, whereas AC susceptometry and Mössbauer spectroscopy investigations reveal that the particles perform diffusive Brownian motion in the liquid polymer melt as separated particles rather than as large agglomerates. Furthermore, a texturing of MNP in the polymer matrix by a static magnetic field gradient was investigated. First results on the preparation of cross-linkable dextran esters are shown. Cross-linking after irradiation of the BNC prevents melting that can be used to influence texturing procedures.

Investigation of phase transformation in an Al-0.58 wt% Fe alloy by Mössbauer spectroscopy

1988 ◽  
Vol 41 (1) ◽  
pp. 595-598 ◽  
Author(s):  
L. Murgas ◽  
Z. Homonnay ◽  
S. Nagy ◽  
A. Vértes
Keyword(s):  
Phase Transformation ◽  
Mössbauer Spectroscopy ◽  
Mossbauer Spectroscopy ◽  
Mößbauer Spectroscopy

In-situ studies of catalysts by XAFS and Mössbauer spectroscopy

1989 ◽  
Vol 47-48 (1-4) ◽  
pp. 203-217 ◽  
Author(s):  
Bjerne S. Clausen ◽  
Henrik TopsØe
Keyword(s):  
Mössbauer Spectroscopy ◽  
Mossbauer Spectroscopy ◽  
In Situ Studies ◽  
Mößbauer Spectroscopy

Microstructure Evolution and Mossbauer Spectroscopy Research of Nanostructured Ni3 Fe Intermetallic

2021 ◽  
Vol 32 ◽  
pp. 1-13
Author(s):  
Amel Kaibi ◽  
Abderrahim Guittoum ◽  
Nassim Souami ◽  
Mohamed Kechouane
Keyword(s):  
Magnetic Field ◽  
Mössbauer Spectroscopy ◽  
Mössbauer Spectra ◽  
Milling Time ◽  
Mossbauer Spectroscopy ◽  
Hyperfine Magnetic Field ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mossbauer Spectra ◽  
Mößbauer Spectroscopy

Nanocrystalline Ni75Fe25 (Ni3Fe) powders were prepared by mechanical alloying process using a vario-planetary high-energy ball mill. The intermetallic Ni3Fe formation and different physical properties were investigated, as a function of milling time, t, (in the range 6 to 96 h range), using X-Ray Diffraction (XRD) and Mössbauer Spectroscopy techniques. X-ray diffraction were performed on the samples to understand the structural characteristics and get information about elements and phases present in the powder after different time of milling. The refinement of XRD spectra revealed the complete formation of fcc Ni (Fe) disordered solid solution after 24 h of milling time, the Fe and Ni elemental distributions are closely correlated. With increasing the milling time, the lattice parameter increases and the grains size decreases. The Mössbauer experiments were performed on the powders in order to follow the formation of Ni3Fe compound as a function of milling time. From the adjustment of Mössbauer spectra, we extracted the hyperfine parameters. The evolution of hyperfine magnetic field shows that the magnetic disordered Ni3Fe phase starts to form from 6 h of milling time and grow in intensity with milling time. For the milling time more than 24 h, only the Ni3Fe disordered phase is present with a mean hyperfine magnetic field of about 29.5 T. The interpretation of the Mossbauer spectra confirmed the results obtained by XRD.

In situ 119Sn Mössbauer spectroscopy study of Sn-based electrode materials

2006 ◽  
Vol 167 (1-3) ◽  
pp. 733-738 ◽  
Author(s):  
Abdelmaula Aboulaich ◽  
Florent Robert ◽  
Pierre Emmanuel Lippens ◽  
Laurent Aldon ◽  
Josette Olivier-Fourcade ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Electrode Materials ◽  
Mossbauer Spectroscopy ◽  
Spectroscopy Study ◽  
119Sn Mössbauer Spectroscopy ◽  
Mößbauer Spectroscopy
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