Solvent effects on the hyperfine coupling constant and barrier to internal rotation for the 2-muoxyprop-2-Yl radical

1991 ◽  
Vol 65 (1-4) ◽  
pp. 927-936 ◽  
Author(s):  
D. Buttar ◽  
R. M. Macrae ◽  
B. C. Webster ◽  
E. Roduner
Keyword(s):  
Internal Rotation ◽  
Solvent Effects ◽  
Hyperfine Coupling ◽  
Hyperfine Coupling Constant ◽  
Coupling Constant

The β-phosphorus hyperfine coupling constant in nitroxides: 6. Solvent effects in non-cyclic nitroxides

2016 ◽  
Vol 14 (15) ◽  
pp. 3729-3743 ◽  
Author(s):  
Gérard Audran ◽  
Lionel Bosco ◽  
Paulin Nkolo ◽  
Raphael Bikanga ◽  
Paul Brémond ◽  
...  
Keyword(s):  
Solvent Effects ◽  
Hyperfine Coupling ◽  
Hyperfine Coupling Constant ◽  
Coupling Constant ◽  
The Impact

The impact of the solvent on aP and aN decreases strikingly upon increasing both the bulkiness and the polarity of the substituents around the nitroxyl moiety.

scholarly journals Ro-vibrational averaging of the isotropic hyperfine coupling constant for the methyl radical

2015 ◽  
Vol 143 (24) ◽  
pp. 244306 ◽  
Author(s):  
Ahmad Y. Adam ◽  
Andrey Yachmenev ◽  
Sergei N. Yurchenko ◽  
Per Jensen
Keyword(s):  
Hyperfine Coupling ◽  
Hyperfine Coupling Constant ◽  
Coupling Constant ◽  
Methyl Radical ◽  
Isotropic Hyperfine Coupling
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