scholarly journals Rice bran lipase catalyzed esterification of palm oil fatty acid distillate and glycerol in organic solvent

2007 ◽  
Vol 12 (4) ◽  
pp. 462-462
Author(s):  
Fui Chin Chong ◽  
Being Ti Tey ◽  
Zanariah Mohd Dom ◽  
Kok Hing Cheong ◽  
Budiatman Satiawihardja ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Organic Solvent ◽  
Rice Bran ◽  
Palm Oil ◽  
Rice Bran Lipase ◽  
Fatty Acid Distillate

scholarly journals Rice bran lipase catalyzed esterification of palm oil fatty acid distillate and glycerol in organic solvent

2007 ◽  
Vol 12 (3) ◽  
pp. 250-256 ◽  
Author(s):  
Fui Chin Chong ◽  
Beng Ti Tey ◽  
Zanariah Mohd Dom ◽  
Kok Hing Cheong ◽  
Budiatman Satiawihardja ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Organic Solvent ◽  
Rice Bran ◽  
Palm Oil ◽  
Rice Bran Lipase ◽  
Fatty Acid Distillate

scholarly journals An Intensified Esterification Process of Palm Oil Fatty Acid Distillate Catalyzed by Delipidated Rice Bran Lipase

2006 ◽  
Vol 6 ◽  
pp. 1124-1131 ◽  
Author(s):  
Fui Chin Chong ◽  
Beng Ti Tey ◽  
Zanariah Mohd. Dom ◽  
Nordin Ibrahim ◽  
Russly Abd. Rahman ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Rice Bran ◽  
Reaction Temperature ◽  
Palm Oil ◽  
Packed Bed ◽  
Packed Bed Reactor ◽  
Silica Gels ◽  
Water Removal ◽  
Rice Bran Lipase ◽  
Fatty Acid Distillate

An intensified esterification process was operated by circulating 10 l of reaction mixtures, consisting of palm oil fatty acid distillate (PFAD) and glycerol in hexane, through a packed-bed reactor (PBR) filled with 10 kg of delipidated rice bran lipase (RBL). The influence of the process parameters, such as reaction temperature and type of water-removal agent, on the performance of this intensified esterification process were investigated. The highest degree of esterification (61%) was achieved at a reaction temperature of 65°C, using silica gels as the water-removal agent. Thin-layer chromatography (TLC) analysis showed that the major composition of the esterified product was diacylglycerol.

scholarly journals Utilization of unsaponifiable matter from rice bran oil fatty acid distillate for preparing an antioxidant-rich oleogel and evaluation of its properties

2020 ◽  
Vol 71 (1) ◽  
pp. 336
Author(s):  
S. Sahu ◽  
M. Ghosh ◽  
D. K. Bhattacharyya
Keyword(s):  
Differential Scanning Calorimetry ◽  
Fatty Acid ◽  
Light Microscopy ◽  
Unsaponifiable Matter ◽  
Rice Bran ◽  
Rice Bran Oil ◽  
Polarized Light ◽  
Weight Basis ◽  
Scanning Calorimetry ◽  
Fatty Acid Distillate

Rice bran oil fatty acid distillate (RBOFAD) is an important by-product obtained from the physical refining process. This fatty acid distillate contains high a amount of Unsaponifiable Matter (γ-oryzanol 3.27 gm/100gm UM; total tocopherol 10.93 mg/100 g UM; total phytosterol 21.81 g/100g UM; squalene 1.15 g/100 g UM and total fatty alcohol 73.34 g/100 g UM) and free fatty acids. Antioxidant-rich Oleogels were obtained from rice bran wax (RBW), rice bran oil fatty acid distillate (RBOFAD) and refined rice bran oil. The main objective of this study was to utilize the antioxidant-rich unsaponifiable matter of RBOFAD (UMRBOFAD) as an organogelator along with rice bran wax, which also acts as a good organogelator. Antioxidant-rich oleogel was prepared using UMRBFAD, ethylcellulose (EC) and RBW at 2%, 2%, 3% on weight basis, respectively, in refined rice bran oil and this antioxidant-rich oleogel was compared with rice bran oil oleogel using RBW at 7% on weight basis of rice bran oil. These oleogels were evaluated using a combination of techniques such as differential scanning calorimetry (DSC), polarized light microscopy (PLM), Viscosity, synchrotron radiation X-ray diffraction (SR-XRD) and FTIR Spectroscopy. The differential scanning calorimetry (DSC) measured the thermal properties of rice bran oil oleogel and high antioxidant-rich oleogel. Polarized light microscopy images revealed needle-like crystals for RBW. SR-XRD measurements were used for clarification of the crystal structures of the building blocks of these oleogels. The antioxidant activities of oleogels were evaluated involving DPPH and ABTS assays.

Gasoline Yield Enhancement in Fluid Catalytic Cracking by Coprocessing of Petroleum Gasoil with Refined Bleached Deodorized Palm Oil and Palm Fatty Acid Distillate

2020 ◽  
Vol 17 (2) ◽  
pp. 1079-1084
Author(s):  
Zarkoni Azis ◽  
Bambang Heru Susanto ◽  
Mohammad Nasikin
Keyword(s):  
Gas Chromatography ◽  
Fatty Acid ◽  
Palm Oil ◽  
Catalytic Cracking ◽  
Spark Ignition Engine ◽  
Fluid Catalytic Cracking ◽  
Light Cycle ◽  
Palm Fatty Acid Distillate ◽  
Cracking Reaction ◽  
Fatty Acid Distillate

Gasoline is liquid hydrocarbon fuel used for spark-ignition engine. Most of gasoline production is carried out in the petroleum oil refinery through several stages of process and fluid catalytic cracking (FCC) is an important process that can convert some of heavy oil fractions like vacuum gasoil (VGO) and residue to be cracked into gasoline and lighter products. Consumption of gasoline for transportation fuel in Indonesia is higher than its production capability, so this gap has compelled to search the alternative process route using renewable feedstock. Coprocessing of petroleum gasoil with crude palm oil in fluid catalytic cracking had been investigated previously resulting in lower value of conversion as well as gasoline yield when applying co-feeds at higher level of vegetable oils. Cracking feedstock containing triglyceride and fatty acid from vegetable oil is supposed to be the other possibility as a reason of conversion and yield changes. The research work is aimed to find out another way for gasoline yield upgrading in fluid catalytic cracking process using available catalyst by coprocessing of VGO with refined bleached deodorized palm oil (RBDPO) and small amount of palm fatty acid distillate (PFAD). The experimental work of cracking reaction was performed on fluid-bed reactor of ACE unit at temperature of 530 °C, nearly atmospheric pressure and catalyst-oil ratio of 5.5 g/g. Three kind of oil feeds were tested namely VGO, VGO mixed with 5% RBDPO and VGO added with 5% RBDPO-PFAD of mixing ratio 9:1. The cracking reaction results in gaseous and liquid products. The gaseous phase product was analyzed using online gas chromatography to detect light hydrocarbon components of C1, C2 and H2 as dry gas and hydrocarbon components of C3 and C4 as LPG. The liquid item was investigated through gas chromatography of simulated distillation to separate fluid components including gasoline, light cycle oil (LCO) and slurry oil. Carbon material placed on catalyst through cracking reaction was analyzed at regeneration step of spent catalyst passed through catalytic converter by online Infrared method. Coprocessing of VGO with 5% RBDPO and VGO with 5% RBDPO-PFAD can alter conversion and product yields. The presence of triglyceride and fatty acid in oil feeds during cracking reaction influence signifi- cantly to gasoline enhancement. Although this coprocessing work has shown initial phenomenon in accordance with hypothesis, further investigation is necessary to explore deeper in order to obtain an optimized process condition by various levels of coprocessing feed.

scholarly journals Biodiesel Synthesis from Palm Fatty Acid Distillate (PFAD) by Palm Oil Industry Product using Metal-Hydroxyapatite Catalyst

2020 ◽  
Vol 1655 ◽  
pp. 012030
Author(s):  
Sri Rezeki Muria ◽  
Yelmida Azis ◽  
Khairat ◽  
Desy Erika Putri ◽  
Zultiniar ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Palm Oil ◽  
Oil Industry ◽  
Palm Fatty Acid Distillate ◽  
Biodiesel Synthesis ◽  
Fatty Acid Distillate

scholarly journals NON-Catalytic and glycerol-free biodiesel production from rice bran oil fatty acid distillate in a microreactor

2021 ◽  
pp. 100096
Author(s):  
Nattee Akkarawatkhoosith ◽  
Tiprawee Tongtummachat ◽  
Amaraporn Kaewchada ◽  
Attasak Jaree
Keyword(s):  
Fatty Acid ◽  
Rice Bran ◽  
Rice Bran Oil ◽  
Biodiesel Production ◽  
Fatty Acid Distillate

scholarly journals Low-rank coal and poly fatty acid distillate characterization as a preparation of coal upgrading palm oil technology

2021 ◽  
Vol 882 (1) ◽  
pp. 012038
Author(s):  
Sihyun Lee ◽  
Jiho Yoo ◽  
Datin Fatia Umar
Keyword(s):  
Fatty Acid ◽  
Moisture Content ◽  
Palm Oil ◽  
Calorific Value ◽  
Low Rank ◽  
Low Rank Coal ◽  
Temperature Oxidation ◽  
Technology Application ◽  
Palm Fatty Acid Distillate ◽  
Fatty Acid Distillate

Abstract The utilization of low-rank coal is restricted by such factors as high moisture content, low heating value, high propensity to low-temperature oxidation, spontaneous combustion, etc. Some coal upgrading technologies to reduce the moisture content have been developed, one of them is coal upgrading palm oil technology using palm fatty acid distillate as an additive to keep the stability of moisture content in the coal after the process. To study the possibility of the upgrading technology application in Indonesia, some studies have been conducted. The study covered coal characterization such as proximate, ultimate and calorific value, palm fatty acid distillate for stabilization of upgraded low-rank coal and coal upgrading by coal upgrading palm oil technology in laboratory scale. By using 7 Indonesian low-rank coals and 4 palm fatty acid distillates, it is confirmed that the coal upgrading palm oil technology is effective to reduce the moisture content and increase the calorific value of low rank coal.

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