Development of a cathode layer (La0.8Sr0.2MnO3) in a solid Oxide fuel cell using a reactive plasma spray

2004 ◽  
Vol 10 (5) ◽  
pp. 479-483 ◽  
Author(s):  
Hyun-Ki Kang
Author(s):  
W.T. Ju ◽  
S.H. Hong

Abstract The atmospheric pressure plasma spray processes for functional layers of the tubular solid oxide fuel cell are developed to build a fuel cell structure consisting of air electrode, ceramic electrolyte, and fuel electrode. Further more the characteristics of each film are also investigated. The layers of LSM (La0.65Sr0.35MnO3) air electrode and Ni/8YSZ fuel electrode have porosities of 23 ~32 % sufficient for supplying fuel and oxidant gases efficiently to electrochemical reaction interfaces. The measured electrical conductivities of the electrodes are higher than 90 S/cm at 1000 °C, which satisfy the requirement as the current collecting electrodes. The YSZ electrolyte film has a high ionic conductivity of 0.07 S/cm at 1000 °C, but shows a bit too porous to block the oxygen molecule penetration through it. A unit tubular SOFC is fabricated by the optimized plasma spray processes for depositing each functional film and forming a porous cylindrical supporting tube of the cell, and turns out to have a promising capability of electricity generation.


2014 ◽  
Vol 783-786 ◽  
pp. 1698-1703
Author(s):  
Hironori Nakajima

An anode-supported honeycomb solid oxide fuel cell can work with high power density and improve thermo-mechanical durability at high temperatures. We have thus fabricated the honeycomb cell with an electrolyte layer of 8YSZ on an anode honeycomb substrate of Ni/8YSZ. The cathode layer is LSM-YSZ composite. Current-voltage and current-power density characteristics of the cells having different anode and cathode flow channel configurations are measured under different hydrogen flow rates. We also evaluate the hydrogen mole fraction distributions in the honeycomb cell using finite element method, and discuss appropriate anode and cathode flow channel configurations. The present study is a starting point of developing an anode-supported honeycomb cell for cell stacks assembled with multiple and large scale honeycomb cells which can achieve high efficiency flow channel and current collecting configurations, and enhanced thermo-mechanical durability.


2018 ◽  
Vol 44 (10) ◽  
pp. 11576-11581 ◽  
Author(s):  
Nurhadi S. Waluyo ◽  
Seong-Sik Park ◽  
Rak-Hyun Song ◽  
Seung-Bok Lee ◽  
Tak-Hyoung Lim ◽  
...  

2007 ◽  
Vol 539-543 ◽  
pp. 1385-1390 ◽  
Author(s):  
Olivera Kesler

Plasma spray processing is a low-cost, rapid manufacturing technique that is widely used industrially for fabrication of thermal barrier and wear- and corrosion-resistant coatings. Because the technique can be used to rapidly deposit coatings of high melting temperature materials with good substrate adhesion, it has also been applied to the production of individual component layers in tubular solid oxide fuel cells (SOFCs), and more recently, in planar SOFCs. The use of plasma spray processing for the fabrication of fuel cell components presents unique challenges, due to the high porosities required for the electrode layers and fully dense coatings required for electrolytes. Application of plasma spray processing for the manufacture of solid oxide fuel cells is discussed, with consideration of potential advantages of the technique compared to standard SOFC wet ceramic processing routes. Major challenges faced in the adaptation of the processing method to solid oxide fuel cell manufacture are discussed, along with current research approaches being used to overcome these challenges. Recent developments in the use of the technique for the rapid onestep manufacturing of direct oxidation SOFC anodes are discussed, for composite material combinations that cannot be co-sintered due to widely divergent melting points. The impacts of plasma sprayed coating properties on solid oxide fuel cell performance are considered, and implications of the use of the technique on overall stack and system manufacturing costs are discussed.


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