Diamagnetism of some organic liquid mixtures

1939 ◽  
Vol 9 (1) ◽  
pp. 35-66 ◽  
Author(s):  
S. Ramachandra Rao ◽  
A. S. Narayanaswamy
1994 ◽  
Vol 95 (2) ◽  
pp. 161-169 ◽  
Author(s):  
Nozomu Tanihara ◽  
Kazuhiro Tanaka ◽  
Hidetoshi Kita ◽  
Ken-ichi Okamoto

1998 ◽  
pp. 37-58 ◽  
Author(s):  
B. Yaron ◽  
I. Dror ◽  
E. Graber ◽  
J. Jarsjo ◽  
P. Fine ◽  
...  

2019 ◽  
Vol 11 (31) ◽  
pp. 28370-28376 ◽  
Author(s):  
Zhihong Zhao ◽  
Yongqian Shen ◽  
Haidong Yang ◽  
Jian Li ◽  
Lin Guo

2019 ◽  
Vol 55 (92) ◽  
pp. 13876-13879 ◽  
Author(s):  
Yihan Sun ◽  
Jinxia Huang ◽  
Zhiguang Guo

A facile protocol was developed for preparing a dual underliquid superlyophobic surface for the on-demand separation of immiscible organic liquids.


1939 ◽  
Vol 61 (2) ◽  
pp. 524-525 ◽  
Author(s):  
R. A. Day ◽  
Robert N. Pease

2020 ◽  
Vol 4 (4) ◽  
pp. 44
Author(s):  
Spencer E. Taylor ◽  
Huang Zeng

The present work aims to shed light on recent literature reports suggesting that ionic species are implicated in the electrical conductivity of 1-octanol and its mixtures with hydrocarbons. Other workers have questioned this interpretation, and herein, based on new experimentation and with reference to various literature studies, we consider that molecular interactions are more likely to be responsible. To investigate this, we have studied mixtures of 1-octanol and either silicone oil (SO) or n-dodecane as nonpolar components, using dielectric (in particular electrical conductivity) and viscometric measurements. With reference to the literature, the self-association of alcohols is known to create microheterogeneity in the neat liquids and in mixtures with nonpolar, low dielectric constant liquids, and it has previously been considered to be responsible for the particular solvent properties of alcohols. The present results suggest that the electrical conductivity of alkane/alcohol systems may have similar origins, with percolating pathways formed from octanol-rich nanodomains comprising polar regions containing hydrogen-bonded hydroxyl groups and nonpolar regions dominated by alkyl chains. The percolation threshold found for dodecane/octanol mixtures, in which interactions between the component molecules are found from viscosity measurements to be repulsive, agrees well with results from experimental and theoretical studies of disordered arrangements of packed spheres, and moreover, it is consistent with other published alkane/alcohol results. On the other hand, the situation is more complex for SO/octanol mixtures, in which interactions between the two components are attractive, based on viscosity data, and in which the phase separation of SO occurs at high octanol concentrations. Overall, we have concluded that electrical conductivity in octanol (and potentially all liquid alcohols) and its mixtures with nonpolar molecules, such as alkanes, is consistent with the presence of conducting networks comprising octanol-rich nanodomains formed by self-association, and not as a result of ionic conduction.


2005 ◽  
Vol 265 (1-2) ◽  
pp. 101-107 ◽  
Author(s):  
T KAI ◽  
H GOTO ◽  
Y SHIMIZU ◽  
T YAMAGUCHI ◽  
S NAKAO ◽  
...  

2005 ◽  
Vol 73 (1) ◽  
pp. 5-15 ◽  
Author(s):  
Jean K. Platten

In the first part of the paper, we recall what the Soret effect is, together with its applications in science and industry. We emphasize the need to have a reliable data base for the Soret coefficient. Next we review the different techniques to measure the Soret coefficient (elementary Soret cell, beam deflection technique, thermal diffusion forced Rayleigh scattering technique, convective coupling and, in particular, the onset of convection in horizontal layers and the thermogravitational method). Results are provided for several systems, with both negative and positive Soret coefficients, and comparison between several laboratories are made for the same systems. We end with “benchmark” values of the Soret coefficient for some organic liquid mixtures of interest in the oil industry and to which all future new techniques should refer before gaining confidence. We conclude that correct values of the Soret coefficient can be obtained in earth conditions and we deny the need to go to microgravity.


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