The Soret Effect: A Review of Recent Experimental Results

2005 ◽  
Vol 73 (1) ◽  
pp. 5-15 ◽  
Author(s):  
Jean K. Platten

In the first part of the paper, we recall what the Soret effect is, together with its applications in science and industry. We emphasize the need to have a reliable data base for the Soret coefficient. Next we review the different techniques to measure the Soret coefficient (elementary Soret cell, beam deflection technique, thermal diffusion forced Rayleigh scattering technique, convective coupling and, in particular, the onset of convection in horizontal layers and the thermogravitational method). Results are provided for several systems, with both negative and positive Soret coefficients, and comparison between several laboratories are made for the same systems. We end with “benchmark” values of the Soret coefficient for some organic liquid mixtures of interest in the oil industry and to which all future new techniques should refer before gaining confidence. We conclude that correct values of the Soret coefficient can be obtained in earth conditions and we deny the need to go to microgravity.

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 376 ◽  
Author(s):  
Doreen Niether ◽  
Mona Sarter ◽  
Bernd W. Koenig ◽  
Jörg Fitter ◽  
Andreas M. Stadler ◽  
...  

Thermophoretic behavior of a free protein changes upon ligand binding and gives access to information on the binding constants. The Soret effect has also been proven to be a promising tool to gain information on the hydration layer, as the temperature dependence of the thermodiffusion behavior is sensitive to solute–solvent interactions. In this work, we perform systematic thermophoretic measurements of the protein streptavidin (STV) and of the complex STV with biotin (B) using thermal diffusion forced Rayleigh scattering (TDFRS). Our experiments show that the temperature sensitivity of the Soret coefficient is reduced for the complex compared to the free protein. We discuss our data in comparison with recent quasi-elastic neutron scattering (QENS) measurements. As the QENS measurement has been performed in heavy water, we perform additional measurements in water/heavy water mixtures. Finally, we also elucidate the challenges arising from the quantiative thermophoretic study of complex multicomponent systems such as protein solutions.


1994 ◽  
Vol 95 (2) ◽  
pp. 161-169 ◽  
Author(s):  
Nozomu Tanihara ◽  
Kazuhiro Tanaka ◽  
Hidetoshi Kita ◽  
Ken-ichi Okamoto

Polymer ◽  
1986 ◽  
Vol 27 (11) ◽  
pp. 1705-1708 ◽  
Author(s):  
Qui Tran-Cong ◽  
Taihyun Chang ◽  
Charles C. Han ◽  
Yasunori Nishijima

2005 ◽  
Vol 73 (1) ◽  
pp. 21-25 ◽  
Author(s):  
Charles-Guobing Jiang ◽  
M. Ziad Saghir ◽  
M. Kawaji

Thermal diffusion, or Soret effect, in porous media is mathematically modeled with the Firoozabadi model based on non-equilibrium thermodynamics. The Soret effect in a binary mixture is investigated in a vertical cavity with heterogeneous permeability, where natural convection can occur. The thermo solutal convection with heterogeneous permeability was studied in terms of flow pattern, concentration distribution, component separation ratio, and Soret coefficient distribution. A consistent analysis was conducted and it is concluded that the Soret coefficient of thermal diffusion in porous media strongly depends on the heterogeneity of permeability.


1998 ◽  
pp. 37-58 ◽  
Author(s):  
B. Yaron ◽  
I. Dror ◽  
E. Graber ◽  
J. Jarsjo ◽  
P. Fine ◽  
...  

2019 ◽  
Vol 11 (31) ◽  
pp. 28370-28376 ◽  
Author(s):  
Zhihong Zhao ◽  
Yongqian Shen ◽  
Haidong Yang ◽  
Jian Li ◽  
Lin Guo

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