A dual underliquid superlyophobic surface in organic media for on-demand separation of immiscible organic liquid mixtures

2019 ◽  
Vol 55 (92) ◽  
pp. 13876-13879 ◽  
Author(s):  
Yihan Sun ◽  
Jinxia Huang ◽  
Zhiguang Guo
Keyword(s):  
Organic Liquid ◽  
Liquid Mixtures ◽  
Organic Liquids ◽  
Organic Media ◽  
On Demand

A facile protocol was developed for preparing a dual underliquid superlyophobic surface for the on-demand separation of immiscible organic liquids.

Polymer composites as sensing materials for liquid organic solvents – preliminary results

e-Polymers ◽  
2011 ◽  
Vol 11 (1) ◽  
Author(s):  
Stanislaw Frackowiak ◽  
Monika Maciejewska ◽  
Andrzej Szczurek ◽  
Marek Kozlowski
Keyword(s):  
Electrical Resistivity ◽  
Carbon Black ◽  
Polymer Composites ◽  
Percolation Theory ◽  
Liquid Mixtures ◽  
Organic Liquids ◽  
Volumetric Fraction ◽  
Factors Influencing ◽  
Benzene Toluene ◽  
Main Factors

AbstractCarbon black-filled polymer composites were investigated as sensing materials for organic liquids. Polypropylene and polystyrene which were selected as matrices and various amounts of carbon black were considered as the main factors influencing sensitivity of the composites in view of the percolation theory. Disposable filaments were produced of these materials. Change in their electrical resistivity was measured upon immersion in benzene, toluene, xylene, ethylbenzene and their mixtures. It has been found that studied materials were sensitive to the composition of liquid mixtures of organic solvent. Relationships between the filament response and volumetric fraction of the components were presented. The studied materials have shown promising sensing properties, which suggest their applicability for identification and quantification of multicomponent organic liquids.

Synthesis of aligned carbon nanotubes in organic liquids

2002 ◽  
Vol 17 (9) ◽  
pp. 2457-2464 ◽  
Author(s):  
Yafei Zhang ◽  
Mikka N.-Gamo ◽  
Kiyoharu Nakagawa ◽  
Toshihiro Ando
Keyword(s):  
Carbon Nanotubes ◽  
Organic Liquid ◽  
Film Surface ◽  
Normal Pressure ◽  
Organic Liquids ◽  
X Ray Diffraction ◽  
Multiwalled Carbon ◽  
Aligned Carbon Nanotubes ◽  
Novel Method ◽  
The Right

A simple and novel method was developed for efficient synthesis of aligned multiwalled carbon nanotubes (CNTs) in methanol and ethanol under normal pressure. The CNTs' alignment and structures were investigated using Raman scattering and x-ray diffraction spectroscopy. A unique kind of coupled CNT was synthesized in which one rotated to the left and one rotated to the right. Chains periodically bridged the coupled CNTs. The growth mechanism of the CNTs within organic liquid is proposed to be a catalytic process at the Fe film surface in a dynamic and thermal nonequilibrium condition in organic liquids.

Pervaporation of organic liquid mixtures through membranes of polyimides containing methyl-substituted phenylenediamine moieties

1994 ◽  
Vol 95 (2) ◽  
pp. 161-169 ◽  
Author(s):  
Nozomu Tanihara ◽  
Kazuhiro Tanaka ◽  
Hidetoshi Kita ◽  
Ken-ichi Okamoto
Keyword(s):  
Organic Liquid ◽  
Liquid Mixtures

Behavior of Volatile Organic Liquid Mixtures in the Soil Environment

1998 ◽  
pp. 37-58 ◽  
Author(s):  
B. Yaron ◽  
I. Dror ◽  
E. Graber ◽  
J. Jarsjo ◽  
P. Fine ◽  
...  
Keyword(s):  
Organic Liquid ◽  
Liquid Mixtures ◽  
Soil Environment ◽  
Volatile Organic

Coatings from Liquid and Supercritical Carbon Dioxide

2004 ◽  
Author(s):  
Yury Chernyak ◽  
Florence Henon
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Physical Properties ◽  
Organic Liquid ◽  
Spray Coating ◽  
Organic Liquids ◽  
Liquid Density ◽  
Operating Pressure ◽  
Interfacial Tensions ◽  
Supercritical Carbon

This chapter describes several aspects of the use of carbon dioxide as a solvent or cosolvent in coating applications. The primary impetus for using carbon dioxide for this purpose has been the alleviation of volatile emissions and liquid solvent wastes. However, the special physical properties of liquid and supercritical carbon dioxide may offer some processing advantages over conventional organic or aqueous solvents. Liquid carbon dioxide is quite compressible, and a reduction in temperature results not only in a reduction in the operating pressure, but also in a significant increase in the liquid density to values of approximately 0.9 g/cm3. At these high liquid densities, carbon dioxide exhibits improved solvent performance, but with much lower viscosities and interfacial tensions than aqueous or organic liquid solvents. Under supercritical conditions, carbon dioxide also exhibits high densities, low viscosities, and improved solvent power. Low viscosities and interfacial tensions tend to facilitate the transport of the solvents into any crevices or imperfections on the surface to be covered, and this might prove advantageous in the coating of patterned or etched surfaces. Since carbon dioxide dissolves and diffuses easily into many different polymers and organic liquids, it can also be used to reduce the viscosity of coating solutions. Whether in the liquid or the supercritical state, the temperature and pressure of the mixture can be used to control its physical properties in ways that are impossible to achieve with traditional solvents. These distinguishing features have raised the level of industrial interest in carbon dioxide as a solvent for coating applications, beyond those based solely on environmental concerns. In this chapter, we will discuss current applications and research on the use of CO2 as a solvent for coatings. The first section deals with spray coating from supercritical CO2. Subsequent sections deal with the use of liquid coatings, such as spin and free meniscus coatings, and impregnation coatings. Since the start of the 20th century (ca. 1907), atomization has been the basis for conventional spray coating applications (Muirhead, 1974). Typically, atomization is caused by high shear of the coating fluid in air, leading to droplet or particle formation.

Underliquid Superlyophobic Copper-Coated Meshes for the Separation of Immiscible Organic Liquid Mixtures

2019 ◽  
Vol 11 (31) ◽  
pp. 28370-28376 ◽  
Author(s):  
Zhihong Zhao ◽  
Yongqian Shen ◽  
Haidong Yang ◽  
Jian Li ◽  
Lin Guo
Keyword(s):  
Organic Liquid ◽  
Liquid Mixtures

The Determination of Water in Organic Liquid Mixtures

1939 ◽  
Vol 61 (2) ◽  
pp. 524-525 ◽  
Author(s):  
R. A. Day ◽  
Robert N. Pease
Keyword(s):  
Organic Liquid ◽  
Liquid Mixtures
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