Optimized methods for obtaining cellulose and cellulose sulfates from birch wood

2015 ◽  
Vol 49 (4) ◽  
pp. 825-843 ◽  
Author(s):  
Boris N. Kuznetsov ◽  
Svetlana A. Kuznetsova ◽  
Vladimir A. Levdansky ◽  
Alexandr V. Levdansky ◽  
Natalia Yu. Vasil’eva ◽  
...  
Keyword(s):  
2018 ◽  
Vol 10 (2) ◽  
pp. 142-151 ◽  
Author(s):  
B. N. Kuznetsov ◽  
N. V. Chesnokov ◽  
O. V. Yatsenkova ◽  
I. G. Sudakova ◽  
A. M. Skripnikov ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1362
Author(s):  
Boris N. Kuznetsov ◽  
Sergey V. Baryshnikov ◽  
Angelina V. Miroshnikova ◽  
Aleksandr S. Kazachenko ◽  
Yuriy N. Malyar ◽  
...  

For the first time, the fractionation of birch wood into microcrystalline cellulose, xylose and methoxyphenols is suggested based on the integration of alkali-acid pretreatments and hydrogenation in ethanol over a bifunctional Ru/C catalyst. It is established that removal of hemicelluloses during pretreatments of birch wood influences the yields of the liquid, gaseous and solid products of the non-catalytic and catalytic hydrogenation of pretreated samples in ethanol at 225 °C. The bifunctional Ru/carbon catalyst affects in different ways the conversion and yields of products of hydrogenation of the initial and acid- and alkali-pretreated birch wood. The most noticeable influence is characteristic of the hydrogenation of the acid-pretreated wood, where in contrast to the non-catalytic hydrogenation, the wood conversion and the yields of liquid products increase but the yields of the solid and gaseous products decrease. GC-MS, gel permeation chromatography and elemental analysis were used for characterization of the liquid product composition. The molecular mass distribution of the liquid products of hydrogenation of the initial and pretreated wood shifts towards the low-molecular range in the presence of the catalyst. From the GC-MS data, the contents of monomer compounds, predominantly 4-propylsyringol and 4-propanolsyringol, increase in the presence of the ruthenium catalyst. The solid products of catalytic hydrogenation of the pretreated wood contain up to 95 wt% of cellulose with the structure, similar to that of microcrystalline cellulose.


Silva Fennica ◽  
2016 ◽  
Vol 50 (3) ◽  
Author(s):  
Ludmila Novitskaya ◽  
Nadezhda Nikolaeva ◽  
Natalia Galibina ◽  
Tatiana Tarelkina ◽  
Ludmila Semenova
Keyword(s):  

1964 ◽  
Vol 18 ◽  
pp. 836-837 ◽  
Author(s):  
Bengt O. Lindgren ◽  
E. Kulonen ◽  
K. Sune Larsson ◽  
Hans Halvarson ◽  
Lennart Nilsson

10.2307/1256 ◽  
1939 ◽  
Vol 8 (1) ◽  
pp. 114 ◽  
Author(s):  
H. N. Southern ◽  
L. S. V. Venables
Keyword(s):  

2021 ◽  
Author(s):  
Remi Matrau ◽  
Yann Klinger ◽  
Jonathan Harrington ◽  
Ulas Avsar ◽  
Esther R. Gudmundsdottir ◽  
...  

<p>Paleoseismology is key to study earthquake recurrence and fault slip rates during the Late Pleistocene-Holocene. The Húsavík-Flatey Fault (HFF) in northern Iceland is a 100 km-long right-lateral transform fault connecting the onshore Northern Volcanic Zone to the offshore Kolbeinsey Ridge and accommodating, together with the Grímsey Oblique Rift (GOR), ~18 mm/yr of relative motion between the Eurasian and North American plates. Significant earthquakes occurred on the HFF in 1755, 1838 and 1872 with estimated magnitudes of 6.5-7. However, historical information on past earthquakes prior to 1755 is very limited in both timing and size.</p><p>We excavated five trenches in a small basin (Vestari Krubbsskál) located 5.5 km southeast of the town of Húsavík and at 300 m.a.s.l. and one trench in an alluvial fan (Traðargerði) located 0.5 km north of Húsavík and at 50 m.a.s.l. In a cold and wet environment, such as in coastal parts of Iceland, one has to take into account periglacial processes affecting the topsoil to discriminate tectonic from non-tectonic deformation. We used tephra layers in the Vestari Krubbsskál and Traðargerði trenches as well as birch wood samples in Traðargerði to constrain the timing of past earthquakes. Tephra layers Hekla-3 (2971 BP) and Hekla-4 (4331±20 BP) are visible in the top half of all the trenches. In addition, a few younger tephra layers are visible in the top part of the trenches. In Traðargerði several dark layers rich in organic matter are found, including birch wood-rich layers from the Earlier Birch Period (9000-7000 BP) and the Later Birch Period (5000-2500 BP). In Vestari Krubbsskál the lower halves of the trenches display mostly lacustrine deposits whereas in Traðargerði the lower half of the trench shows alluvial deposits overlaying coarser deposits (gravels/pebbles) most likely of late-glacial or early post-glacial origins. In addition, early Holocene tephra layers are observed in some of the trenches at both sites and may correspond to Askja-S (10800 BP), Saksunarvatn (10300 BP) and Vedde (12100 BP). These observations provide good age constraints and suggest that both the Vestari Krubbsskál and Traðargerði trenches cover the entire Holocene.</p><p>Trenches at both sites show significant normal deformation in addition to strike-slip, well correlated with their larger scale topographies (pull-apart basin in Vestari Krubbsskál and 45 m-high fault scarp in Traðargerði). We mapped layers, cracks and faults on all trench walls to build a catalogue of Holocene earthquakes. We identified events based on the upward terminations of the cracks and retrodeformation. Our results yield fewer major earthquakes than expected, suggesting that large earthquakes (around magnitude 7) are probably rare and the more typical HFF earthquakes of magnitude 6-6.5 likely produce limited topsoil deformation.[yk1]  Our interpretation also suggests that the Holocene slip rate [yk2] for the fault section we are studying may be slower than the estimated geodetic slip rate (6 to 9 mm/yr)[yk3]  for the entire onshore HFF, although secondary onshore sub-parallel fault strands could accommodate part of the deformation.</p>


2020 ◽  
Vol 78 (5) ◽  
pp. 849-857
Author(s):  
Dace Cirule ◽  
Anrijs Verovkins ◽  
Ingeborga Andersone ◽  
Edgars Kuka ◽  
Bruno Andersons
Keyword(s):  

Holzforschung ◽  
2002 ◽  
Vol 56 (4) ◽  
pp. 348-354 ◽  
Author(s):  
K. Luostarinen ◽  
V. Möttönen ◽  
A. Asikainen ◽  
J. Luostarinen

Summary Birch wood discolours during artificial drying, which is a considerable problem for the use of birch as raw material in the mechanical wood industry. In this investigation sample boards of Betula pendula were sawn to the dimensions used as raw material for parquet billets. The variables studied were those that may affect wood discolouration: growing site, felling date, length of the storage period for logs and location of the wood in the trunk. Discoloration of birch wood was studied in conventional and vacuum drying processes. The wood layer of about 2–5 mm under the yellow surface of conventionally dried boards remained light-coloured, while the inner wood of the boards became discoloured. During vacuum drying, however, the inner wood of sample boards clearly became discoloured. The radial location of the wood in the trunk affected the colour of dried wood more than the longitudinal location did. To keep the colour of dry wood as light as possible, it may be best to fell birch in winter and store the wood for several weeks before conventional drying. On the other hand, the lightest coloured wood obtained during vacuum drying was from autumnfelled five weeks stored birches, which may indicate differences in the process of discoloration in these two drying methods.


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